• Resources Recycling
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• v.31 no.4
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• pp.19-25
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• 2022

In this study, tungsten carbide (WC) powder was prepared using a novel recycling process for hard metal sludge that does not use ammonium paratungstate. Instead of ammonia, acid was used to remove the sodium and crystallized tungstate, resulting in the formation of tungstic acid (H₂WO₄). The WC powder was successfully synthesized by the carbothermal reduction of tungstic acid through H₂O decomposition, reduction of WO₃ to W, and formation of WC. The carbon content and holding time at the carbothermal reduction temperature were optimized to remove free carbon from the WC powder. As a result, most of the free carbon in the WC powder prepared from sludge was removed, and the content of free carbon in the synthesized WC powder was lower than that in commercial WC powder. Moreover, the crystallite size of WC prepared from H₂WO₄ was much smaller than that of commercial micron-sized WC powder produced from APT. The small crystallite size of WC induces grain growth during the sintering of the WC-Co composite; thus, a WC-Co composite with large WC grains was fabricated using the WC powder prepared from H₂WO₄. The large WC grains affected the mechanical properties of the WC-Co composite. Further, due to the large grain size, the WC-Co composite fabricated from H₂WO₄ exhibited a higher toughness than that of the WC-Co composite prepared from commercial WC powder.

• Journal of the Korea Organic Resources Recycling Association
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• v.17 no.2
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• pp.51-58
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• 2009

In this paper checked up biomass which occurs in the Jeju as are classified as organic waste for integrated management system for review and circulation of resources. Biomass which occurs in the Jeju was the 10,818 tons of sludge, 61,284 tons of food-waste, 1,519,000 tons of livestock. Sludge is treated marine discharge, food-waste is treated regeneration and livestock is treated in the form of recycling. How to establish "System used by mechanism of recycling management on biomass resources" to introduce biomass town created by Hita-city, Oita-ken in Japan. Also there established a model system to building for recycling management of biomass and then checked up the economics. According to the report, it has the difference in facilities, but it will switch to a surplus in 4 years, therefore it was confirmed that the economy. To be considered priority most livestock in "System used by mechanism of recycling management on biomass resources" in Jeju. So it is introduced the urgent problem and the problem awaiting solution on treating livestock in this study.

• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.2
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• pp.53-63
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• 2018

The hydrolysis of organic solid waste, such as sludge, is the rate-limiting step of the anaerobic digestion. The longer rate-limiting step lead to decrease of treatment efficiency and increase hydraulic retention time and anaerobic digester. Therefore, the pre-treatment has been applied for accelerating the hydrolysis step. This study was investigated the effects of pre-treatment of waste activated sludge using ultrasonic and alkaline integrated treatment simultaneously. The results showed the cumulative methane production and the methane production rate increased while the lag phase decreased. Therefore ultrasonic and alkaline integrated pre-treatment of waste activated sludge resulted in acceleration of hydrolysis step in anaerobic digestion.

• Resources Recycling
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• v.21 no.4
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• pp.35-43
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• 2012

This study was carried out for the purpose of obtaining basic data to utilize the AMD sludge as sorbent for heavy metal ions. The sludge from the treatment process of Acid Mine Drainage mainly consists of fine iron hydroxide or iron oxide hydrate and calcite, and the fine iron hydroxide or iron oxide hydrate has a property of adsorbing heavy metal ions. In this study, we investigated the physical property of the AMD sludge like as mineral composition, particle size and shape and chemical composition and also investigated the influence of dosage of sludge, adsorbing time, pH, initial concentration and sintering temperature on the adsorption of heavy metal ions.

• Journal of the Korea Organic Resources Recycling Association
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• v.23 no.3
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• pp.51-59
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• 2015

Livestock sludge contains high concentration of organic matter and some heavy metals. In case of discharging into the sea, it might have negative effects in the environment. In this study thermal hydrolysis reaction was applied for livestock sludge to determine the fuelization possibility and obtain the best operation conditions. Livestock sludges were thermally hydrolyzed at temperature range $170{\sim}210^{\circ}C$ in sealed high-temperature reactors. Liquid products and dewatered cakes were analyzed. The operation at $190^{\circ}C$ was found to be best effective condition. High heating value and low heating value were 5,050 kcal/kg and 4,740 kcal/kg, respectively. Therefore, fuelization of livestock sludge using thermal hydrolysis reactor is found to be highly effective.

• Journal of the Korea Organic Resources Recycling Association
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• v.11 no.3
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• pp.42-50
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• 2003

Pyrolysis of maize is experimentally investigated in bench-scale rotary kiln in semi-continuous operation. The operational parameters varied are the temperature($450{\sim}800^{\circ}C$), the solids residence time(7~20 min). Important parameters studied include the running time, water content of sewage sludge, solids amount of sewage sludge(TS%) by the varied temperature. Also, with the increasing of temperature, how the yield of oil and char product change was observed, and the distribution of gas production components was observed. The gas of $C_1{\sim}C_3$ yield increased and oil of $C4{\sim}C6$ yield decreased along with pyrolysis temperature of $670^{\circ}C$ by the run time of 9 min. The results showed the expected strong influence of pyrolysis temperature and a noticeable influence of running time.

• Journal of the Korea Organic Resources Recycling Association
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• v.24 no.2
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• pp.3-13
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• 2016

This study investigated the environmental and economical assessment for sewage sludge treatment options including biogasification, incineration, carbonization, drying, and solidification. Additionally it is also investigated the economical feasibility of the current guidelines (Digestion efficiency for organic waste = 45 %, Moisture content of sludge = 95 and 93 %) and it aimed to suggest the scientific informations for a policy-making. For the economical feasibility the 30 plants with anaerobic digestion treatment and the 17 plants without anaerobic digestion treatment were investigated. The result of the comparison of sewage sludge treatment options showed that anaerobic digestion+incineration was the most economically feasible considering incineration and drying. For smaller treatment capacity, solidification was the most economically feasible considering carbonization and solidification and anaerobic digestion+carbonization was the most economically feasible considering carbonization and solidification.

• Journal of the Korea Organic Resources Recycling Association
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• v.3 no.2
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• pp.37-45
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• 1995

The performance and the operational problems of UASB(Upflow Anaerobic Sludge Blanket) reactor for treatment of dairy wastewaters were investigated. Synthetic milk wastewater was successfully treated up to the loading rate of 3.9kg $COD/m^3.day$, with a specific gas production rate of 1. 23 I/I. day and a COD removal efficiency of over 90%. However, the sludge rising was observed at the loading rate of 2.1kg $COD/m^3.day$, due probably to the formation of scum layer at the surface of settling compartment. The BMP(biochemical methane potential) of raw milk wastewater and ice cream wastewater, measured by using SBT(serum bottle test), were 0.135 and 0.66ml $CH_4/mg\;COD_{added}$, respectively. The sludge activity increased more than 8 times from 0.159g $COD-CH_4/g$ VSS. d during 90 days of operation.

• Journal of the Korea Organic Resources Recycling Association
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• v.12 no.4
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• pp.130-138
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• 2004

Food wastes with different regional origins were mixed with bulking agent such as paper mill sludge or night soil, and aged for 21 days or 28 days. And aged food wastes were fed to the earthworm(tiger worm, Eisenia fetida) for 60 days. There were no significant physico-chemical differences among the food wastes with different regional origins. EC values and NaCl concentrations in food wastes were too high for earthworms to survive. Food wastes mixed with paper mill sludge were vermicomposted more efficiently than food wastes mixed with night soil, but the over-all vermicomposting rates on the food wastes were much lower than that on paper mill sludge because EC values and NaCl concentrations were still high for earthworm to compost the feeds. Earthworm population did not increase its biomass on the food wastes mixed with paper mill sludge or night soil, whereas earthworm population fed with paper mill sludge increased its biomass by 20% for 60 days. It could be concluded that a solution for reducing NaCl concentrations in food waste should be developed to vermicompost food waste.

• Journal of the Korean Recycled Construction Resources Institute
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• v.3 no.1
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• pp.34-42
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• 2015

The paper investigates environmental hazards and characteristics of the artificial lightweight aggregate manufactured by using dyestuff sludge from dyeing industrial complex. The dyestuff sludge used in this study is chemically treated with Ti and Fe salt for the purpose of recycling. The artificial lightweight aggregate is manufactured through 3 step; 1) Selecting the optimum moisture content by evaluating plasticity from the mixing ratio of the clay and sludge, 2) shaping round type based on the optimum mixing ratio, 3) drying and Sintering process. Based on KS F 2534 "Lightweight Aggregate for Structural concrete", the particle size, fineness modulus, the density, absorption, unit volume weight, stability and environmental hazards of the manufactured lightweight aggregate are evaluated. Experimental results show that the particle size and fineness modulus is out of the range. However, it is observed that other physical properties are within criteria. In addition, it is confirmed that the problem of the particle size and fineness modulus could be solved in the manufacturing process.