• Title/Summary/Keyword: Slight asymmetry

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Crystal Structure and Physical Property of Tetragonal-like Epitaxial Bismuth Ferrites Film

  • Nam, Joong-Hee;Biegalski, Michael;Christen, Hans M.;Kim, Byung-Ik
    • Proceedings of the Korean Magnestics Society Conference
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    • 2011.06a
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    • pp.7-8
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    • 2011
  • Basically, the lattice mismatch between film and substrate can make those BiFeO3(BFO) films distorted with strain structure. BFO phase can be stabilized on LaAlO3(LAO) represents the example of a multiferroic with giant axial ratio. Its crystal structure is not strictly tetragonal, but tetragonal with a slight monoclinic distortion and related to the rotation of the oxygen octahedra. In this study, we show that phases with a tetragonal-like epitaxial BFO films can indeed be ferroelectric and also can be stabilized via epitaxial growth onto LAO. Recent reports on epitaxial BFO films show that the crystal structure changes from nearly rhombohedral ("R-like") to nearly tetragonal("T-like") at strains exceeding approximately -4.5%, with the "T-like" structure being characterized by a highly enhanced c/a ratio. While both the "R-like" and the "T-like" phases are monoclinic, our detailed x-ray diffraction results reveal asymmetry change from MA and MC type, respectively. By applying additional strain or by modifying the unit cell volume of the film by substituting Ba for Bi, the monoclinic distortion in the "T-like" MC phase is reduced, i.e. the system approaches a true tetragonal symmetry. There are two different M-H loops for $Bi_{1-x}Ba_xFeO_{3-{\delta}}$(BBFO) and BFO films on SrTiO3(STO) & LAO substrates. Along with the ferroelectric characterization, these magnetic data indicate that the BFO phase stabilized on LAO represents the first example of a multiferroic with giant axial ratio. However, there is a significant difference between this phase and other predicted ferroelectrics with a giant axial ratio: its crystal structure is not strictly tetragonal, but tetragonal with a slight monoclinic distortion. Therefore, in going from bulk to highly-strained films, a phase sequence of rhombohedral(R)-to-monoclinic ["R-like" MA-to-monoclinic, "T-like" MC-to-tetragonal (T)] is observed. This sequence is otherwise seen only near morphotropic phase boundaries in lead-based solid-solution perovskites (i.e. near a compositionally induced phase instability), where it can be controlled by electric field, temperature, or composition. Our results show that this evolution can occur in a lead-free, stoichiometric material and can be induced by stress alone. Those major results are summarized as follows ; 1) Ba-doping increases the unit cell volume, 2) BBFO on LAO can be fully strained up to x=0.08 as a strain limit (Fig. 1), 3) P(E) & M(H) properties can be tuned by the variation of composition, strain, and film thickness.

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The BV Photometry of the RR Lyrae Star, BH Ursae Majoris: Light Curves and Period Study

  • Kim, Chun-Hwey;Jeong, Jang-Hae
    • Journal of Astronomy and Space Sciences
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    • v.28 no.2
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    • pp.109-116
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    • 2011
  • The first presented BV light curves of BH UMa confirmed Krajci's (2005) result that BH UMa is an RR Lyr star that belongs to the RRc subgroup. The light curves showed a slight asymmetry of D = 0.453 with an amplitude of about $0.^m58$ in B, $0.^m47$ in V, and $0.^m11$ in B-V and with a small hump between $0.^p82$ and $0.^p86$. We determined nine new times of minimum light and eight times of maximum light. We also analyzed all of the available unanalyzed minimum timings and found for the first time that the period of BH UMa has varied dramatically in at least three independent sinusoidal ways superposed on a secularly downward parabola over 66 years. The secular period decreasing rate was obtained as $6.^d684{\times}10^{-8}y^{-1}$, corresponding to -0.58 s/century. The semi-amplitude and period for each of the three sinusoidal variations were ($0.^d058$, $14.^y44$), ($0.^d044$, $9.^y98$), and ($0.^d005$, $0.^y97$), respectively. It is uncertain whether the periodicity for the shortest period of $0.^y97$ is real or spurious. The secular period decrease, well consistent with those of the other RRc stars, could be considered as a natural result of the evolution of the BH UMa system. The two possible sinusoidal terms were interpreted as both two light-time effects due to two additional bodies orbiting BH UMa and combinations of random fluctuations in the pulsation period of BH UMa. Two interpretations were shortly discussed with related parameters.

Growth observation and orthodontic treatment of a hemifacial microsomia patient treated with distraction osteogenesis

  • Chung, Nam Hyung;Yang, So Jin;Kang, Jae Yoen;Jeon, Young-Mi;Kim, Jong Ghee
    • The korean journal of orthodontics
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    • v.50 no.2
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    • pp.136-144
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    • 2020
  • Hemifacial microsomia (HFM) patients may experience emotional withdrawal during their growth period due to their abnormal facial appearance. Distraction osteogenesis at an early age to improve their appearance can encourage these patients. Some abnormalities of the affected side can be overcome by distraction osteogenesis at an early age. However, differences in the growth rate between the affected and unaffected sides during the rest of the growth period are inevitable due to the characteristics of HFM. Therefore, re-evaluation should be performed after completion of growth in order to achieve stable occlusion through either orthognathic surgery or camouflage orthodontic treatment. An eight-year-old patient visited the clinic exhibiting features of HFM with slight mandibular involvement. He received phase I treatment with distraction osteogenesis and a functional appliance. Distraction osteogenesis was performed at the right ramus, which resulted in an open bite at the right posterior dentition. After distraction osteogenesis, a functional appliance and partial fixed appliance were used to achieve extrusion of the affected posterior dentition and settlement of the occlusion adjustment on the unaffected posterior dentition. The patient visited the clinic regularly for follow-up assessments, and at the age of 20 years, he showed facial asymmetry of the mandible, which had deviated to the right side. He received orthodontic treatment to improve the occlusion of his posterior dentition after the growth period. Without orthognathic surgery, stable occlusion and a satisfactory facial appearance were obtained through camouflage orthodontic treatment.

Thermal Denaturation of the Apo-cyclic AMP Receptor Protein and Noncovalent Interactions between Its Domains

  • Won, Hyung-Sik;Seo, Min-Duk;Ko, Hyun-Suk;Choi, Wahn Soo;Lee, Bong-Jin
    • Molecules and Cells
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    • v.26 no.1
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    • pp.61-66
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    • 2008
  • Cyclic AMP receptor protein (CRP) is allosterically activated by cAMP and functions as a global transcription regulator in enteric bacteria. Structural information on CRP in the absence of cAMP (apo-CRP) is essential to fully understand its allosteric behavior. In this study we demonstrated interdomain interactions in apo-CRP, using a comparative thermodynamic approach to the intact protein and its isolated domains, which were prepared either by limited proteolysis or using recombinant DNA. Thermal denaturation of the intact apo-CRP, monitored by differential scanning calorimetry, revealed an apparently single cooperative transition with a slight asymmetry. Combined with circular dichroism and fluorescence analysis, the thermal denaturation of apo-CRP could be interpreted as a coupled process involving two individual transitions, each attributable to a structural domain. When isolated individually, both of the domains exhibited significantly altered thermal behavior, thus pointing to the existence of non-covalent interdomain interactions in the intact apo-CRP. These observations suggest that the allosteric conformational change of CRP upon binding to cAMP is achieved by perturbing or modifying pre-existing interdomain interactions. They also underline the effectiveness of a comparative approach using calorimetric and structural probes for studying the thermodynamics of a protein.

Intraosseous Hemangioma of the Zygoma: A Case Report (광대뼈에 발생한 뼈내혈관종의 증례 보고)

  • Jeong, Minkyoung;Kwon, Yongseok;Jun, Dongkeun;Lee, Myungchul;Kim, Jeenam;Shin, Donghyeok;Kim, Wan-seop;Choi, Hyungon
    • Korean Journal of Head & Neck Oncology
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    • v.37 no.1
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    • pp.33-37
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    • 2021
  • Intraosseous hemangioma is a rare, benign vascular tumor of endothelial origin. It accounts for fewer than 1% of all hemangiomas, and very rarely occurs in the face. Intraosseous hemangioma usually presents as an asymptomatic lesion, but symptoms can occur due to the mass effect. The authors describe a case of intraosseous hemangioma of the zygoma with a review of the relevant literature. A 44-year-old man presented with a chief complaint of painless swelling on the left zygomatic region that had been slowly growing for the past year. On physical examination, a hard, non-movable mass in a deep layer was palpated. On computed tomography performed to evaluate its layers and extent, trabeculation was found inside the mass, but the lack of destruction of the surrounding bone suggested that the mass was benign. Complete surgical excision was performed under local anesthesia. After complete excision of the mass, slight erosions remained on the cortical bone of the zygoma, but because it was small enough not to cause a facial deformity such as depression or asymmetry, no additional reconstructive procedure was performed. There were no symptoms or recurrence during a 8-month follow-up period.

A Study on Three-phase Imbalance of a Power Transmission Line due to Installation of a Passive Loop Conductor (수동루프에 의한 송전선로 상불평형 발생에 관한 연구)

  • 김종형;신명철;최상열
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.17 no.6
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    • pp.31-38
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    • 2003
  • Among mitigation techniques for electric and magnetic field (EMF) from an overhead transmission line a passive loop is a way that can be cheap and easily installed on the existing towers and have a satisfactory effect as well. However current induced in the passive loop causes transmission power loss and the phase imbalance increases since geometrical asymmetry of the transmission lines becomes larger. So in order to evaluate the power loss and the phase imbalance due to a passive loop, this paper represent a 345[kV] 1-circuit flat type transmission line as asymmetrical 3-phase distributed parameter line model where the effect of a passive loop is embedded in the line parameters, and then formulates differential equations. By solving these equations voltages and currents of each phase at receiving end become known. We find out that power losses occur differently at each phase and positive sequence component decreases at receiving end while negative sequence component increase. In general phase imbalance due to a passive loop is slight, but it increases in proportional to the induced current and length of section where the passive loop is installed. Thus the phase imbalance should be included in terms of cost for introducing a passive loop.

Characterization and Conversion Electron Mössbauer Spectroscopy of HoMn1-x-FexO3 Thin Films by Pulsed Laser Deposition (PLD를 이용한 HoMn1-x-FexO3 박막 제조 및 후방 산란형 뫼스바우어 분광 연구)

  • Choi, Dong-Hyeok;Shim, In-Bo;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.17 no.1
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    • pp.18-21
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    • 2007
  • The hexagonal $HoMn_{1-x}-Fe_xO_3$(x=0.00, 0.05) thin films were prepared using pulsed laser deposition(PLD) method on $Pt/Ti/SiO_2/Si$ substrate. The microstructure and magnetic properties have been studied by x-ray diffraction(XRD), atomic force microscopy (AFH), scanning electron microscope(SEM:), x-ray photoelectron spectroscopy(XPS), and conversion electron $M\"{o}ssbauer$ spectroscopy(CEMS). From the analysis of the x-ray diffraction patterns, the crystal structure for all films was found to be a hexagonal($P6_3cm$), which was preferentially grown along(110) direction. The lattice constant $c_0$ of the film with x=0.05 was close to that of single crystal, whereas lattice constant $a_0$ with respect to single crystal shows a slight decrease. This difference of lattice parameters between film and single crystal was caused by the lattice mismatch between the film and $Pt/Ti/SiO_2/Si$ substrate. Conversion electron $M\"{o}ssbauer$ spectrum of $HoMn_{0.95}Fe_{0.05}O_3$ thin film shows an asymmetry doublet absorption ratio at room temperature, which is due to the oriented direction of crystallographic domains. This is corresponding with analysis of x-ray diffraction. The quadrupole splitting(${\Delta}E_Q$) at room temperature is found to be $1.62{\pm}0.01mm/s$. This large ${\Delta}E_Q$ was caused by asymmetry environment surrounding Fe ion.