• Proceedings of the Korean Institute of Resources Recycling Conference
• /
• 2003.10a
• /
• pp.22-34
• /
• 2003

Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and Dore furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyre-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

• Resources Recycling
• /
• v.12 no.2
• /
• pp.21-27
• /
• 2003

Smelting reduction technique in arc furnace was applied for the recovery of valuable metal such as V from LD slag. In the present study, the parameters for increasing the reduction rate and the reduction efficiency were selected by changing the oxide additives, melting temperature and basicity. The optimum condition for LD-slag reduction was achieved by $Al_2$$O_3$ addition. The reduction ratio of V was increased in increasing the basicity.

• Resources Recycling
• /
• v.8 no.1
• /
• pp.44-51
• /
• 1999

Converter slag was reduced and modified by the simultaneous addition of carbon and waste foundry sand as a $SiO_2$ source. The basic properties such as phase distribution, composition, specific density, hardness. absorption of water and compressive strength of modified slags were measured. The Iron recovery was significantly affected by the basicity of slag. The properties of slow cooled-modified slags of basicity 1.34 arc very similar to the natural aggregates.

• Resources Recycling
• /
• v.10 no.3
• /
• pp.37-42
• /
• 2001

Current iron and steelmaking operation was re-evaluated on the basis of slag engineering technology to optimize slag operations. In blast furnace process, increase in the basicity of slags (C/S) could obtain progressed fluidity and hot metal quality. COREX process would be stabilized in view of slag fluidity and hot metal quality by reducing input content of $SiO_2$and $A1_2$$O_3$In STS-AOD process, addition of small amount of lime could improve refining capacity of the slag; also calcium aluminate flux could be taken into account as a potential substitute for fluorspar, without degradation of operation efficiency and steel quality.

• Journal of Soil and Groundwater Environment
• /
• v.29 no.1
• /
• pp.72-83
• /
• 2024

Most of the slags generated from steel-making industry in Korea are recycled into media-contact aggregates such as fill and cover materials. For their use as media-contact aggregates, the slags must meet not only the waste quality criteria, but also the Daphnia magna acute toxicity test criteria. In this study, Korean Leaching Test ES 06150.e (Korea), Japanese Leaching Test JIS K 0058-1(Japan), Detuch Leaching Test DIN 19529 (Germany), Toxicity Characteristic Leaching Procedure (USA) were conducted for batch leaching test of slags from 6 Korean steel-making companies. In addition, Korean Standard up-flow percolation test (ES 06151.1) mimicking field conditions was conducted to assess the impact of the slag leachate on the surrounding environment indirectly. Heavy metals such as Cr⁶⁺ and Zn²⁺ were detected from both extractant and leachate samples, but all of them did not exceed waste quality criteria of each country. However, Daphnia magna acute toxicity tests using the leachate samples from up-flow percolation test with slag alone and slag/natural soil conditions exceeded ecotoxicity standard (TU=2) due to their high pH (11.3-12.5). After neutralizing the pH of the slag leachate to 6.5~8.5, the Daphnia magna mortality and immobilization were reduced to satisfy ecotoxicity standard. As the reducing pH of slag leachate would be extremely difficult, appropriate recycling management considering the physicochemical characteristics of he slags should be stuided further.

• Resources Recycling
• /
• v.25 no.2
• /
• pp.49-59
• /
• 2016

Steel slag is being recycled into industrial by-products for civil generated inevitably in the seasonal course, road and cement raw materials. However, the field of recycling most of the bottom portion is concentrated in the areas that are required to take advantage of the situation in various fields taking advantage of the steel slag. But various studies to take advantage of the steel slag as aggregate for concrete made for limiting slag was a situation that most of the studies are incomplete research on the suitability of as aggregate for concrete practical relates to an expandable suppressed. In this study, the separation of the slag aggregate according to the production methods to assess the feasibility aggregate for concrete aggregates, including through Steel making slag, a total of seven kinds of steel slag aggregate. Studies show that ordinary concrete, steel slag aggregate for aggregate and on the equally to take advantage of grading, chloride content standards such as to what is lacking, although appropriate aggregate of concrete include the deployment of only in special sectors through the combination was assessed to have a very high.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2020.06a
• /
• pp.136-137
• /
• 2020

This study compared and analyzed the fluidity and strength characteristics of mortar using the recycling water, indicates strong alkali properties, as pre-wetting water of artificial light aggregate to increase usage ratio of recycling.

• Resources Recycling
• /
• v.25 no.4
• /
• pp.54-59
• /
• 2016

EAF processed slag which contains about 20 ~ 35 weight percent FetO is poured to slag pot and cooled. If we recover Fe from molten slag by the reduction, we will improve steel yield rate and reduce slag quantity poured from the furnace. Usually, carbon is used as a reductant and slag foaming agent in the EAF process. In this experiment, after melt the metal in induction furnace and then add slag with carbon and Al dross powder as a reductant, we investigated the reduction of FetO from slag and change of Phophorus content. As the result, when we use Al dross as a reductant, recovery rate is two times more than carbon. Phosphorus pick up is less than 50ppm with reduction of EAF slag.

• Resources Recycling
• /
• v.17 no.5
• /
• pp.11-18
• /
• 2008

The purpose of this study was to evaluate the effects of blast-furnace slag on chemical attack and carbonation of latex-modified concrete (LMC) and ordinary portland cement concrete as slag contents. Main experimental variables were performed latex contents (0%, 15%) and slag contents (0%, 30%, 50%). The compressive strengths, chemical attacks resistance and carbonation depth were measured to analyze the characteristic of the developed LMC and BS-LMC(latex-modified concrete added blast-furnace slag) on hardened concrete. The test results showed that compressive strength of BS-LMC with blast-furnace slag content 30% was quite similar to it of OPC without slag content. The structural quality deterioration was concerned when blast slag content was up to 50%. However, carbonation restraint of BS-LMC with blast-furnace slag 30% was bigger then that of opc. Also, the effects of added latex on OPC and BS-LMC were increased on the carbonation restraint and chemical attacks resistance.

• Resources Recycling
• /
• v.27 no.2
• /
• pp.38-47
• /
• 2018

Integrated gasification combined cycle (IGCC) is a next generation energy production technology that converts coal into syngas with enhanced power generation efficiency and environmental performance. IGCC produces almost coal gasification slag as the solid by-product. IGCC slag is generated about 140,000 tons for a year although recycling of it is still in the early stages. We evaluated the potential of IGCC slag which is generated from a pilot plant in South Korea as an alkali-activated cement. Samples which were activated with the combined activator of sodium silicate solution and caustic soda had an average compressive strength of 4.5 MPa, showing expansion. Expansion of the alkali-activated slag was presumed to be caused by free CaO in the slag, although it was not detected by the ethylene glycol method. Samples that were activated with the combined activator of sodium aluminate and caustic soda had an average compressive strength of 10 MPa. Hydroxy sodalite and $C_3AH_6$ were found to be the new crystalline phases. IGCC slag can be used as an alkali-activated material, but the strength performance should be improved with proper mix design approach to calculate optimum proportions which can alleviate the expansion issue at the same time.