• Title/Summary/Keyword: Size separation

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Pore Size Control of Silica-Coated Alumina Membrane for $CO_2$ Separation ($CO_2$ 선택투과 분리를 위한 Silica 코팅 Alumina 막의 세공 제어)

  • 서봉국;김성수;김태옥
    • Journal of Environmental Science International
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    • v.8 no.2
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    • pp.263-269
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    • 1999
  • For effective $CO_2$ separation using pore size controlled membrane, silica was deposited in the mesopores of a $\gamma$-alumina film by chemical vapor deposition of tetraethoxysilane (TEOS) and phenyl-substituted ethoxysilanes at 773-873K. The membranes prepared with phenyl-substituted ethoxysilanes were calcined to remove the phenyl group and control the pore size. The gas permaselectivity of prepared membranes was evaluated by using $H_2$, $CO_2$ $N_2$, $CH_2$ and $C_3H_8$ single component and a mixture of $CO_2$ and $N_2$. The membranes produced using TEOS contained micropores having permselectivity only to hydrogen, but the phenyl-subsitituted ethoxysilane derived membranes possessed micorpores which are recognizable molecules of $CO_2$, $N_2$ and $CH_4$. In the diphenyl-diethoxysilane-derived membrane, the $CO_2$ permeance and selectivity of $CO_2$/$CH_4$ were $10^{-6} m^3(STP) \cdot m^{-2} \cdot s^{-1} \cdot kPa^{-1}$ and 11, respectively. Therefore, the use of phenyl-substituted ethoxysilane was effective in controlling micropore size for $CO_2$ separation.

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Pervaporation separation of polyion complex composite membranes for the separation of water/alcohol mixtures: characterization of permeation behavior by using molecular modeling techniques

  • Kim, Sang-Gyun;Lee, Yoon-Gyu;Jonggeon Jegal;Lee, Kew-Ho
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.91-94
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    • 2003
  • In this work, the physicochemical properties for permeant molecules and polyion complex membrane prepared by complexation between SA and chitosan were determined by using molecular modeling methods, and the permeation behaviors of water and alcohol molecules through the PIC membrane have been investigated. In the case of penetrant molecule, the experimental results showed that the prepared membrane was excellent pervaporation performance result in most solution, and the selectivity and permeability of the membrane were dependent on the molecular size, the polarity and the hydrophilic surface of permeant organics. However, the separation behavior of methanol aqueous solution exhibited other permeation tendency with other feed solutions and contradictory result. That is, the membrane were preferentially permeable to methanol over water despite water molecule has stronger polarity and small molecular size than methanol molecule. In this study, the results were discussed from the viewpoint of chemical and physical properties between permeant molecules and membrane in the diffusion state.

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Carbon Molecular Sieve Membranes Dispersed with Nano Particles

  • H.Suda;Ha, K.raya
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.183-186
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    • 2004
  • Nano particles-containing CMS membranes were prepared by pyrolysis of polyimides dispersed uniformly with precursors and their gas separation performances were examined, to elucidate the permeation mechanism and to further improve the gas separation performance. Consequently, it was suggested that the separation performance could be controlled by doping nano-particles in the CMS membranes, and that optimization of various factors, such as the size, content, and dispersion state of the nano particles would contribute for further improvement of the gas separation performance.

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Separation Performance of a Low-pressure Hydrocyclone for Suspended Solids in a Recirculating Aquaculture System

  • Lee, Jin-Hwan
    • Fisheries and Aquatic Sciences
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    • v.13 no.2
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    • pp.150-156
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    • 2010
  • The separation performance of a low-pressure hydrocyclone (LPH) was evaluated for suspended-solids removal in a recirculating aquaculture system (RAS). The dimensions of the LPH were 335 mm cylinder diameter, 575 mm cylinder height, 60 mm overflow diameter, 50 mm underflow diameter, and $68^{\circ}$ cone angle. The inflow rate varied (400, 600, 800, and 1,000 mL $s^{-1}$) with 25%, 25%, 20%, and 10% of bypass ($R_f$), respectively. The maximum total separation efficiency (Et) and reduced separation efficiency (E't) for suspended solids from the effluent of the second settlement tank (before biofiltration) were 58.9% and 45.2%, respectively, at an inflow rate of 600 mL $s^{-1}$ and 25% of $R_f$. The maximum Et and E't for suspended solids from the water supply channel (after biofiltration) were 24.4% and 16%, respectively, at an inflow rate of 1,000 mL $s^{-1}$ and 10% of $R_f$. The maximum grade efficiency (Ei) was 51.6% for a 300 ${\mu}m$ particle size at an inflow rate of 600 mL $s^{-1}$ with 23% of $R_f$. The maximum reduced grade efficiency (E'i) was 37.6% for a 300 ${\mu}m$ particle size at an inflow rate of 1,000 mL $s^{-1}$ with 11% of $R_f$. The results indicate that the separation performance of the LPH for suspended solids removal was size selective and that maximum removal occurred at particle sizes ranging from 300 to 500 ${\mu}m$.

An Estimation on the Stability of W/O Type Emulsified Fuel Using by Capacitance Sensor (정전용량센서를 이용한 W/O형 유화연료의 안정성 평가)

  • Cho, Seong-Cheol;Oh, Yang-Hwan;Im, Seok-Yeon
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.1
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    • pp.95-101
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    • 2011
  • We estimated on the stability of W/O type emulsified fuel using by capacitance sensor, so it concluded the following conclusions. For the first 24 hours, prepared emulsified fuel reveals phase separation ratio of 5%, maintains stable status which verifies the stability of emulsified fuel. Adding more water increases the phase separation ratio rapidly, and adding more surfactant displays stable emulsification. Adding water causes larger size of water droplet diameter, and adding surfactant mixture causes smaller size of water droplet diameter. In conclusion, the size of W/O type emulsified fuel water droplet diameter is directly related to the volume of surfactant, and density of water droplet diameter changes thedistribution according to water contents.

Preparation of Porous Glasses by the Phase-separation of the Silicate Glass Containing $TiO_2$ ($TiO_2$를 함유한 규산염 유리의 상분리를 이용한 다공질 유리의 제조)

  • 김병훈;최석진;박태철
    • Journal of the Korean Ceramic Society
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    • v.28 no.1
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    • pp.29-36
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    • 1991
  • Microporous glasses in the system TiO2-SiO2-Al2O3-B2O3-CaO-Na2O were prepared by the phase-separation technique. Morphology and distribution of pore and specific surface area of glasses heated and leached out at various conditions were investigated by SEM and Porosimeter. Crystallization of glasses heated above transition temperature was also inspected by X-ray diffraction method. When the heating temperature and time increased, the pore size and volume increased, but the specific surface area decreased above the critical temperature. The phase-separation, specific surface area and pore size showed more sensitive change on the variation of heating temperature than of heating time. The specific surface area and micropore volume of porous glasses prepared in this study were about 120-330$m^2$/g and 0.001-0.01cc/g, respectively. Mean pore size of porous glasses were about 20-90$\AA$. Anatase phases was deposited when the parent glass was heat-treated at 75$0^{\circ}C$ for 6hrs.

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Analysis on the Effects of the Induced Noise with Change of the Separation Distance between Grounding Equipment at End of Telecommunication Line and the Inducting Facilities in Power Inducting Situation (전력 유도 장애 시 통신 선로 케이블의 접지체와 유도원간의 이격거리에 의한 유도 잡음 영향 분석)

  • Choi, Mun-Hwan;Lee, Sang-Mu;Cho, Pyoung-Dong
    • 한국정보통신설비학회:학술대회논문집
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    • 2007.08a
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    • pp.215-218
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    • 2007
  • In this paper, we have analyzed the effects from the change of separation distance between grounding equipment at end of telecommunication line and the inducting facilities in power inducting situation. In the result of measurement, we can see that as the separation distance between grounding equipment ant end of telecommunication line and the inducting facility become longer, the induced noise level and PIF level is decreased. From the another experiment results about the effect of changing the impedance size in both ends of telecommunication line, however, we already knew that as the ground impedance at either end of the telecommunication line become grower, the noise level is increased, and as the ground impedance at either end of the telecommunication line become smaller, the noise level is decreased. Hence we can not define the relationship exactly between separation distance from inducting facility to inducted facility and the induced noise level because when the grounding equipment is moved, its impedance size is changed too. In conclusion, changing the separation distance between grounding equipment at end of telecommunication line and the inducting facilities have not influence on the induced noise level.

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A Study on the Crystallization of Low Density Polyethylene Microparticles in $n$-Dodecanol Solution ($n$-Dodecanol 용액에서 저밀도폴리에틸렌 마이크로 입자 결정화에 관한 연구)

  • Park, Keun-Ho;Jang, Young-Min
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.3
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    • pp.306-312
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    • 2011
  • In this study, we are crystallized to the low density polyethylene (LDPE) micro-particles in $n$-dodecanol solution by thermally induced phase separation(TIPS) method. The Low density polyethylene micro-particles is used in a wide variety of polymer coatings and industrial application. The utility of that for a particular application depends on a number of factors such as the particle size and distribution, and chemical composition of the materials. However, there are still needs for new methods of preparation which will provide the structure with unique sizes. The widely used processes for micro-size particles are crystallization method and thermally induced phase separation. TIPS process based on the phase separation mechanism was performed for the LDPE system which undergoes liquid-solid phase separation. Effects of various operating parameters were examined on the structure variation of the particles. Professionality, take-up speed and crystallization rate depended on temperature and concentration of polymer in solution.

Non-Destructive Evaluation of Separation and Void Defect of a Pneumatic Tire by Speckle Shearing Interferometry

  • Kim, Koung-Suk;Kang, Ki-Soo;Jung, Hyun-Chul;Ko, Na-Kyong
    • Journal of Mechanical Science and Technology
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    • v.18 no.9
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    • pp.1493-1499
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    • 2004
  • This paper describes the speckle shearing interferometry, a non-destructive optical method, for quantitative estimation of void defect and monitoring separation defect inside of a pneumatic tire. Previous shearing interferometry has not supplied quantitative result of inside defect, due to effective factors. In the study, factors related to the details of an inside defect are classified and optimized with pipeline simulator. The size and the shape of defect can be estimated accurately to find a critical point and also is closely related with shearing direction. The technique is applied for quantitative estimation of defects inside of a pneumatic tire. The actual traveling tire is monitored to reveal the cause of separation and the starting points. And also unknown void defects on tread are inspected and the size and shape of defects are estimated which has good agreement with the result of visual inspection.

DNA Separation Chips Using Asymmetrically-Switched Nonuniform Electric Fields (비대칭 교차전기장의 불균일 분포를 이용한 DNA 분리 소자)

  • Yi, So-Yeon;Cho, Young-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.33 no.3
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    • pp.265-268
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    • 2009
  • We present the experimental study to realize a DNA separation chip using asymmetrically-switched nonuniform electric fields. The DNA separation chip redistributes DNA molecules within a specific area based on the size- and field-dependent nonlinearity of DNA drift velocity. The present chip is composed of a width variable channel to distribute nonuniform electric field, a DNA loading slit and a pair of electrodes to apply electric field. We focus on the design of DNA separation chips with identifying the nonlinearity of DNA drift velocity using three different DNA molecules (11.1kbp, 15.6kbp, and 48.5kbp) in the chips. It is demonstrated that different size of DNA shows different net migration in different direction under the asymmetrically-switched nonuniform electric field.