• Title/Summary/Keyword: Size and shape effect

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Effect of Crystal Shape on the Grain Growth during Liquid Phase Sintering of Ceramics

  • Jo, Wook;Hwang, Nong-Moon;Kim, Doh-Yeon
    • Journal of the Korean Ceramic Society
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    • v.43 no.11 s.294
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    • pp.728-733
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    • 2006
  • The equilibrium or growth shape of ceramic materials is classified largely into two categories according to the thermodynamic conditions imposed. One is a polyhedral shape where the surface free energy is anisotropic, and the other a spherical shape where the surface free energy is isotropic. In the case of grains with a polyhedral shape of anisotropic surface free energy, socalled abnormal grain growth usually takes place due to a significant energy barrier for a growth unit to be attached to the crystal surface. In the case of grains with a spherical shape of isotropic surface free energy, however, normal grain growth with a uniform size distribution takes place. In this contribution, the state-of-the-art of our current understanding of the relationship between the crystal shape and the microstructure evolution during the sintering of ceramic materials in the presence of a liquid phase was discussed.

Quantitative Analysis of Wear Debris for Surface Modification Layer by Ferrography (Ferrography에 의한 표면개질층의 마모분 정량분석)

  • 오성모;이봉구
    • Tribology and Lubricants
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    • v.15 no.3
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    • pp.265-271
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    • 1999
  • Wherever there are rotating equipment and contact between surface, there is wear and the generation of wear particles. The particles contained in the lubricating oil carry detailed and important information about the condition monitoring of the machine. This information may be deduced from particle shape, composition, size distribution, and concentration. Therefore, This paper was undertaken to Ferrography system of wear debris generated from lubricated moving machine surface. The lubricating wear test was performed under different experimental conditions using the Falex wear test of Pin and V-Block type by Ti(C, N) coated. It was shown from the test results that wear particle concentration (WPC) and wear severity Index( $I_{S}$), size distribution in normal and abnormal wear have come out all the higher value by increases sliding friction time. Wear shape is observed on the Ferrogram it was discovered a thin leaf wear debris as well as ball and plate type wear particles. This kind of large wear shape have an important effect not only metals damage, but also seizure phenomenon.

Effects of cutter runout on end milling forces I -Up and milling- (엔드밀링 절삭력에 미치는 공구형상오차 I -상향 엔드밀링-)

  • 이영문;최원식;송태성;권오진;백승기
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.985-988
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    • 1997
  • In end milling process, the undeformed chip section area and cutting forces vary periodically with phase change of the tool. However the real undeformed chip section area deviates from the geometrically ideal one owing to cutter runout and tool shape error. In this study ,a method of estimating the real undeformed chip section area which reflects cutter runout and tool shape error was presented in up end milling process using measured cutting forces. Size effect was identified from the analysis of specific cutting resistance obtained by using the modified undeformed chip section area.

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A Finite Element Analysis for the Characteristics of Temperature and Stress in Micro-machining Considering the Size Effect (크기효과가 고려된 미소절삭시의 온도 및 응력특성에 관한 유한요소해석)

  • 김국원;이우영
    • Journal of the Korean Society for Precision Engineering
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    • v.15 no.10
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    • pp.128-139
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    • 1998
  • In this paper, a finite element method for predicting the temperature and stress distributions in micro-machining is presented. The work material is oxygen-free-high-conductivity copper(OFHC copper) and its flow stress is taken as a function of strain, strain rate and temperature in order to reflect realistic behavior in machining process. From the simulation, a lot of information on the micro-machining process can be obtained; cutting force, cutting temperature, chip shape, distributions of temperature and stress, etc. The calculated cutting force was found to agree with the experiment result with the consideration of friction characteristics on chip-tool contact region. Because of considering the tool edge radius, this cutting model using the finite element method can analyze the micro-machining with the very small depth of cut, almost the same size of tool edge radius, and can observe the 'size effect' characteristic. Also the effects of temperature and friction on micro-machining were investigated.

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Effect of Heat Flux on the Melting Efficiency and Penetration Shape in TIG Welding (TIG 용접에서 열유속이 용융효율과 용입형상에 미치는 영향)

  • Oh, Dong-Soo;Cho, Sang-Myung
    • Journal of Welding and Joining
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    • v.27 no.2
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    • pp.44-50
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    • 2009
  • The characteristics of arc pressure, current density and heat flux distribution are important factors in understanding physical arc phenomena, which will have a marked effect on the penetration, size and shape of a weld in TIG welding. The purpose of this study is to find out the effect of the heat flux on the melting efficiency and penetration shape in TIG welding using the results of the previous investigators. The conclusions obtained permit to draw a proper method which derived the heat flux distributions by arc pressure distribution measurements, but previous researchers calculated heat flux and current distribution with the heat intensity measurements by the calorimetry. Heat flux of Ar gas arc was concentrated at the central part and distributed low from the arc axis to the radial direction, that of He mixing arc was lower than that of Ar gas, and it was wide distributed to radial direction. That showed a similar characteristic with the Nestor's by calorimetry calculated values. Throughout heat flux drawn in this study was discussed melting efficiency and penetration shape on Ar gas and He mixing gas arc.

The First-principles View of Nanometal Alloy Catalysts

  • Ham, Hyung Chul;Hwang, Gyeong S.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.129-129
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    • 2013
  • Nanometal alloy catalysts have been found to significantly increase catalytic efficiency, compared to the monometallic counterparts. This enhancement can be attributed to various alloying effects: i) the existence of uniquemixed-metal surface sites [the so called ensemble (geometric) effect]; ii) electronic state changes due to metal-metal interactions [the so called ligand (electronic) effect]; and iii) strain caused by lattice mismatch between the alloy components [the socalled strain effect]. In addition, the presence of low-coordination surface atoms and preferential exposure of specific facets [(111), (100), (110)] in association with the size and shape of nanoparticle catalysts [the so called shape-size-facet effect] can be another important factor for modifying the catalytic activity. However, mechanisms underlying the alloying effect still remain unclear owing to the difficulty of direct characterization. Computational approaches, particularly the prediction using first-principles density functional theory (DFT), can be a powerful and flexible alternative for unraveling the role of alloying effects in catalysis since those can give us quantitative insights into the catalytic systems. In this talk, I will present the underlying principles (such as atomic arrangement, facet, local strain, ligand interaction, and effective atomic coordination number at the surface) that govern catalytic reactions occurring on Pd-based alloys using the first-principles calculations. This work highlights the importance of knowing how to properly tailor the surface reactivity of alloy catalysts for achieving high catalytic performance.

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Bumper Stay Design for RCAR Front Low Speed Impact Test (RCAR 전방 저속 충돌시험 대응 범퍼 스테이 설계)

  • Kang, Sungjong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.24 no.2
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    • pp.191-197
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    • 2016
  • RCAR low speed impact test estimates repair cost of the impacted vehicle. In this study, for a mid-size vehicle front body model, structural performance for RCAR low speed impact were analyzed with changing the bumper stay shape and size. First, for improving the impact load transfer mechanism to side member the stay rear section shape at connecting area with side member was modified and the stay outer was redesigned to be normal to the barrier. Next, the investigation on stay thickness effect was carried out and the performances of several models with different forming shape were compared. The final design showed 13mm decrease in the maximum barrier intrusion distance and greatly reduced side member deformation. Additional analyses explained the validity of the final design.

Study of the Influence of Mandrels on the Smear Zone and the Variation of Permeability (스미어존 형성과 투수성 변화에 미치는 멘드럴의 영향에 관한 연구)

  • Kim, Su-Sam;Jang, Yeon-Su;Go, Gyeong-Hwan
    • Geotechnical Engineering
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    • v.13 no.5
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    • pp.45-58
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    • 1997
  • In this paper the factors developing ground disturbance with the penetration of PDB mandrels are analysed by using field reconnaissance and laboratory test. In the laboratory tests, the amount of smear zones around the PDB mandrels is compared with respect to the shape and the size of mandrels by penetrating model mandrels of various shapes into the reconstituted clay. The shapes of mandrels selected are circular, oval and rectangular. It was recognized from the field reconnaissance that the size and shape, driving techniques of mandrels, as well as the size and shape of anchor shoe could develop ground disturbance. The mandrels that would reduce the smear effect of clay is oval and rectangular shapes rat her than circular one. It was found that the smear effect becomes smaller as the ratio of the long and short edge of the rectangular shape mandrel becomes larger.

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Effect of Surfactant on Synthesis of Colloidal Ag Nanoparticles (콜로이드 Ag 나노입자 합성시 계면활성제의 영향)

  • Lee Jong-Kook;Choi Nam-Kyu;Seo Dong-Seok
    • Korean Journal of Materials Research
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    • v.15 no.5
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    • pp.340-347
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    • 2005
  • Silver nanoparticles were synthesized by chemical reduction method from aqueous silver nitrate solution ana hydrazine as a reduction agent. The morphology, particle size and shape were dependent on the mixing method, reaction temperature and time, molar ratio of hydrazine and silver nitrate, the kind of surfactant, and the addition of surfactant. The stability of the colloidal silver was achieved by the adsorption of surfactant molecules onto the particle. Silver nanoparticles have a characteristic absorption maximum at 430 nm under UV irradiation. It was found that the colloid was nanometer m size and formed very stable dispersion of silver. The Ag nanoparticles obtained showed the spherical shape with the size range of 10-30 nm.

A Study on the Drapability of Flare Skirts in the Different Materials -between polyester and rayon fabrics- (소재에 따른 플레어스커트의 입체성능에 관한 연구 -레이온과 폴리에스테르소재 플레이스커트를 중심으로-)

  • 김혜경;이영숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.19 no.4
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    • pp.628-636
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    • 1995
  • The purpose of this study was to investigate the general distribution trend of drapery according to the material of flare skirt and the body size. 100% polyester and 100% rayon fabrics were chosen to compare the effect on the material type. The results from this study were as follows. (1) Both materials generally had similar trend of drapery (2) The difference of material influenced the shape and the amount of drapery. The amount of drapery in polyester was more than the one in rayon. (3) Rody size didn't significantly influence the shape of grapery. So it is concluded that material type is more important variable than the body size for the drapery.

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