• Title/Summary/Keyword: Size and Number Concentration

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The Chemical Nature of Individual Size-resolved Raindrops and Their Residual Particles Collected during High Atmospheric Loading for PM2.5

  • Ma, Chang-Jin;Sera, Koichiro
    • Asian Journal of Atmospheric Environment
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    • v.11 no.3
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    • pp.176-183
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    • 2017
  • Although it is well known that rain plays an important role in capturing air pollutants, its quantitative evaluation has not been done enough. In this study, the effect of raindrop size on pollutant scavenging was investigated by clarifying the chemical nature of individual size-resolved raindrops and their residual particles. Raindrops as a function of their size were collected using the raindrop collector devised by our oneself in previous study (Ma et al., 2000) during high atmospheric loading for $PM_{2.5}$. Elemental analyses of solid residues and individual residual particles in raindrops were subsequently analyzed by Particle Induced X-ray Emission (PIXE) and Scanning Electron Microscopy (SEM) with Energy Dispersive X-Ray Analysis (EDX), respectively. The raindrop number concentration ($m^{-2}h^{-1}$) tended to drastically decrease as the drop size goes up. Particle scavenging rate, $R_{sca.}$ (%), based on the actual measurement values were 38.7, 69.5, and 80.8% for the particles with 0.3-0.5, 0.5-1.0, and $1.0-2.0{\mu}m$ diameter, respectively. S, Ca, Si, and Al ranked relatively high concentration in raindrops, especially small ones. Most of the element showed a continuous decrease in concentration with increasing raindrop diameter. The source profile by factor analysis for the components of residual particles indicated that the rainfall plays a valuable role in scavenging natural as well as artificial particles from the dirty atmosphere.

Anodic Oxide Films Formed on AZ31 Magnesium Alloy by Plasma Electrolytic Oxidation Method in Electrolytes Containing Various NaF Concentrations

  • Moon, Sungmo;Kwon, Duyoung
    • Journal of the Korean institute of surface engineering
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    • v.49 no.3
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    • pp.225-230
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    • 2016
  • The present work was conducted to investigate the effects of NaF concentration in phosphate and silicate-containing alkaline electrolyte on the morphology, thickness, surface roughness and hardness of anodic oxide films formed on AZ31 Mg alloy by plasma electrolytic oxidation (PEO) method. The PEO films showed flat surface morphology with pores in the absence of NaF in the electrolyte, but nodular features appeared on the PEO film surface prepared in NaF-containing electrolyte. Numerous pores ranging from 1 to $20{\mu}m$ in size were observed in the PEO films and the size of pores decreased with increasing NaF concentration in the electrolyte. Surface roughness and thickness of PEO films showed increases with increasing NaF concentration. Hardness of the PEO films also increased with increasing NaF concentration. It was noticed that hardness of inner part of the PEO films is lower than that of outer part of them, irrespective of the concentration of NaF. The low hardness of PEO films was explained by the presence of a number of small size pores less than $2{\mu}m$ near the PEO film/substrate interface.

Relationships between a Calculated Mass Concentration and a Measured Concentration of PM2.5 and Respirable Particle Matter Sampling Direct-Reading Instruments in Taconite Mines (타코나이트 광산 공정에서의 실시간 질량측정기기와 실시간 수농도의 환산에 의한 질량농도와의 연관성)

  • Chung, Eun-Kyo;Jang, Jae-Kil;Song, Se-Wook;Kim, Jeongho
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.1
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    • pp.65-73
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    • 2014
  • Objectives: The purposes of this study are to investigate workers' exposures to respirable particles generated in taconite mines and to compare two metric methods for mass concentrations using direct-reading instruments. Methods: Air monitorings were conducted at six mines where subjects have been exposed primarily to particulate matters in crushing, concentrating, and pelletizing processes. Air samples were collected during 4 hours of the entire work shift for similarly exposure groups(SEGs) of nine jobs(N=37). Following instruments were employed to evaluate the workplace: a nanoparticle aerosol monitor(particle size range; 10-1000 nm, unit: ${\mu}m^2/cc$, Model 9000, TSI Inc.); DustTrak air monitors($PM_{10}$, $PM_{2.5}$, unit: $mg/m^3$, Model 8520, TSI Inc.); a condensation particle counter(size range; 20-1000 nm, unit: #/cc, P-Trak 8525, TSI Inc.); and an optical particle counter(particle number by size range $0.3-25{\mu}m$, unit: #/cc, Aerotrak 9306, TSI Inc.). Results: The highest airborne concentration among SEGs was for furnace operator followed by pelletizing maintenance workers in number of particle and surface area, but not in mass concentrations. The geometric means of $PM_{2.5}$ by the DustTrak and the Ptrak/Aerotrak were $0.04{\mu}m$(GSD 2.52) and $0.07{\mu}m$(GSD 2.60), respectively. Also, the geometric means of RPM by the DustTrak and the Ptrak/Aerotrak were $0.16{\mu}m$(GSD 2.24) and $0.32{\mu}m$(GSD 3.24), respectively. The Pearson correlation coefficient for DustTrak $PM_{2.5}$ and Ptrak/Aerotrak $PM_{2.5}$ was 0.56, and that of DustTrak RPM and Ptrak/Aerotrak RPM was 0.65, indicating a moderate positive association between the two sampling methods. Surface area and number concentration were highly correlated($R^2$ = 0.80), while $PM_{2.5}$ and RPM were also statistically correlated each other($R^2$ = 0.79). Conclusions: The results suggest that it is possible to measure airborne particulates by mass concentrations or particle number concentrations using real-time instruments instead of using the DustTrak Aerosol monitor that monitor mass concentrations only.

Physical Characteristics of Aerosol Concentrations Observed in an Urban Area, Busan (부산 도심지에서 측정된 에어로졸 농도의 물리적 특성)

  • Kim, Yun-Jong;Kim, Cheol-Hee
    • Journal of Environmental Science International
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    • v.19 no.3
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    • pp.331-342
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    • 2010
  • Aerosol physical properties have been measured at Pusan National University by using the 16-channel LPC(Laser Particle Counter), and particle characteristics have been examined for the period from Aug. 4 2007 to Dec. 30, 2008. Annual total average, seasonal average, and other averages of the meteorologically classified four categories such as Asian dust, precipitation, foggy, and clear days are respectively described here. Both annually and seasonally averaged number concentration show three peaks at the particle diameter of 0.3, 1.3, and $4{\mu}m$, respectively. However, the first peak for summer season tends to be shifted toward smaller size than other seasons, implying the strong fine particle generation. Meteorological condition shows strong contrast in aerosol concentrations. In Asian dust case, relatively lower number concentrations of fine particles (i.e., smaller than $0.5{\mu}m$) were predominant, while higher concentrations of coarse particles were found particularly for the size bigger than $0.5{\mu}m$. In precipitation day, number concentrations were decreased by approximately 30% due to the removal process of precipitation. Foggy day shows significantly higher concentrations for fine particles, implying the importance of the aerosol condensation process of micro-fine-particle growing to fine-particle. Finally the regressed particle size distribution function was fitted optimally with two log-normal distribution, and discussed the similarities and differences among four categorized cases of the Asian dust, precipitation, foggy, and clear days.

Analysis of High Volume Slit Type Two-Stage Virtual Impactor for Particle Size Classification (특정크기 입자농축을 위한 대유량 슬릿형 2단 가상충돌기의 성능분석)

  • 박성호;김상수;오명도
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.1
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    • pp.285-291
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    • 1991
  • A two-stage slit type virtual impactor based on the concept of the single stage virtual impactor has been designed, fabricated, and evaluated for the purpose of concentrating the suspended particles in the air with the size range of 1.8-4.5 .mu.m and handling large flow volume. Monodisperse methylene blue particles have been generated with vibrating orifice aerosol generator (VOAG). The separation efficiency and concentration efficiency have been measured by the UV-visible absorption spectrometry. Previous study for a single stage virtual impactor were used to determine the design parameters such as 50% cut-off sizes and dimensions of the two stage virtual impactor. The separation efficiency curve and 50% cut-off Stokes number(cut-off sizes) are not sensitive to the nozzle Reynolds number, but sensitive to the ratio between the minor flow rate and the total flow rate, The measured concentration efficiency was compared with the maximum concentration efficiency determined by the separation efficiencies of the first and the second stages. The differences between the measured and the maximum concentration efficiencies result from the wall loss due to the deposited particles on the internal walls inside the impactor.

Effect of Sperm Concentration on Fertility and Litter Size in Deep Frozen Boar Semen (돼지 동결정액 중의 정자농도가 수태율 및 산자수에 미치는 영향)

  • 김학규;정행기;이수헌;이광원;김인철;최진성;지병천;김경남;박창식
    • Journal of Embryo Transfer
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    • v.11 no.1
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    • pp.81-83
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    • 1996
  • This study was carried out to investigate the effect of sperm concentration of 5ml maxi-straw on farrowing rate and number of pigs born alive per litter in deep frozen boar semen. We did not find out the effect of sperm concentration on post-thaw sperm motility and NAR acrosome. However, farrowing rate and number of pigs born alive per litter of 7. 5 x 10˚ /5ml and 10.0 x 10˚ /5m1 sperm concentrations were higher than those of 5. 0 /10˚ /5ml sperm concentration.

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Analysis of Fog using the FSSP-100 and Microwave Radiometer at Daegwallyoung in the 2003 winter case (전방산란스펙트로미터 (FSSP-100)와 마이크로 레디오메타를 이용한 2003년도 대관령 동계 안개 사례 분석)

  • Cha, Joo-Wan;Chang, Ki-Ho;Jeong, Jin-Yim;Park, Gyun-Myeong;Yang, Ha-Young
    • Atmosphere
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    • v.15 no.3
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    • pp.167-178
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    • 2005
  • Using the FSSP-100(FSSP) and Microwave Radiometer (MWR), the fog and clear day characteristics (the size and number concentration of fog particles and the liquid water content) have been measured and analyzed at Daegwallyoung observation site ($37^{\circ}41^{\prime}N$, $128^{\circ}45^{\prime}E$) during 27 - 30 November 2003 (fog day) and 19 January 2004 (clear day). During the fog days, the measured fog-particle size by using FSSP is 0.8~8.4 ${\mu}m$, which is similar to the WMO typical value, the fog number concentration varies from 121 to 200 count ($No./cm^2$) and the fog liquid water content from $0.018g/m^3-0.1g/m^3$ in the site. The precipitable water vapor obtained by the MWR, showing the correlation coefficient $R^2$=0.83 between the total precipitable water vapor obtained from the radio sonde and MWR, shows the larger amount (0.75-8.3 cm) during the fog days than the clear-sky data (0.2 cm).

Effects of Particle Measuring Conditions on Diesel Nanoparticles Distribution (입자측정조건이 디젤 나노입자의 입경분포에 미치는 영향)

  • Lee, Jin-Wook;Kim, Hong-Suk;Jeong, Young-Il
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.5
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    • pp.653-660
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    • 2006
  • Due to the stronger exhaust emission regulations and the introduction of advanced technology in Diesel engine, the specific Diesel particulate matters have decreased by about one order of magnitude since the 1980's. In recent years, particle number emissions rather than particulate mass emissions have become the subject of controversial discussions. Recent results from health studies imply that it is possible that particulate mass does not properly correlated with the variety of health effects attributed to Diesel exhaust. Concern is instead now focusing on nano-sized particles. This study has been performed for the better understanding about the Diesel nano-particle measurement and size distribution characteristics in the exhaust system of a turbo charged Diesel engine. A scanning mobility particle sizer(SMPS) system was applied to measure the particle number and size concentration of Diesel exhaust particles. As the experimental results, the number concentrations in the particle size (Dp<200 nm) were very sensitive to dilution conditions. Specially the changes in nano-particle number concentrations(Dp<50 nm) increased along the downstream of exhaust flow. Also we found the dilution conditions were influencing the condensation of SOF and $H_2O$ during dilution and cooling of hot exhaust.

Long-term Environmental Changes: Interpretations from a Marine Benthic Ecologist's Perspective (II) -Eutrophication and Substratum Properties

  • Yoo Jae-Won;Hong Jae-Sang;Lee Jae June
    • Fisheries and Aquatic Sciences
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    • v.2 no.2
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    • pp.210-217
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    • 1999
  • Chemical oxygen demand (COD), phytoplankton cell number and chlorophyll-a concentration (Chl-a), sediment mean grain size and ignition loss were studied to determine their temporal trends in the study area. Historical data of COD, cell number and Chl-a were gathered from the late 1960s or early 1980s to 1997, and trends in temporal domain were obtained from a simple regression. Sediments for grain size and ignition loss (as organic contents in sediments) were sampled from the Chokchon macrotidal flat bimonthly from September 1990 to November 1996, and were analyzed using the decomposition method of time series analysis. In general, the first three data showed increasing trends based on regression analysis. The trends of sediment grain size fluctuated in a neutral pathway while those of ignition loss yielded no increasing pattern. In contrast with the suggestions from Ahn and Choi (1998) who reported a coarsening variation in sediment grain size to be a cause of the directional and remarkable changes of macrofaunal communities in this area, we could not find such a corresponding variation pattern from our samples. In diagnosing eutrophication, a paradoxical phenomenon was encountered between the trends in water column (COD, cell number and Chl-a) and sediment (ignition loss) data. In this paper, we inferred the possible processes that produce the discrepancy. Some explanations and biological responses to eutrophication were predicted and discussed.

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The Dispersion Stability of $\alpha-Fe_2O_3$ Particulate Soil in the Anionic/Nonionic Mixed Surfactant Solution (음/비이온계 혼합계면활성제 용액에서 $\alpha-Fe_2O_3$ 입자의 분산안정성)

  • 정선영;강인숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.28 no.6
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    • pp.854-861
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    • 2004
  • To estimate dispersion stability of particles in anionic and nonionic surfactant mixed solution, suspending power was examined as functions of duration time of suspension, ionic and nonionic surfactant mixed ratio, surfactant concentration, kinds of electrolyte, ionic strength and mole numbers of oxyethylene additions to nonionic surfactant using $\alpha$-Fe$_2$O$_3$ particle as the model of particulate soil. The suspending power of anionic and nonionic surfactant mixed solution was relatively higher than that of anionic and nonionic surfactant single solution regardless of solution concentration. The suspending power was gradually decreased with increasing duration time of suspension. In the absence of electrolyte, the effect of surfactant concentration on suspending power was small but in solution with electrolyte, suspending power was lowest at 1 % surfactant concentration. With 1${\times}$10$^{-3}$ ionic strength and polyanionic electrolyte in solution, the suspending power was high but effects of oxyethylene mole number to nonionic surfactant on suspending power was small. Generally the suspending power was gradually increased with decreasing the particle size. Hence the suspending power was inversely related to the particle size.