• 한국대기환경학회지
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• 제18권2호
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• pp.95-112
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• 2002

A precision analysis was conducted for the quantification of trace metal levels in airborne particulates using ICP-MS. According to our study the quantitative analysis using Whatman grade 41 filters produces more precise and representative values of metal concentrations than that using EPM 2000 filters. The mean concentration of PM 10 analyzed during 1998 ~ 2000 was 82 $\mu$g/m$^3$. The concentrations of human carcinogens such as As and Cr were 8.65 and 25.87 ng/m$^3$, respectively, while those of probable human carcinogens such as Cd and Pb were 3.13 and 219.46 ng/m$^3$, respectively. Time-weighted mean concentration, calculated using surface wind speed and direction, indicated that there were differences between metals of crustal origin and metals of anthropogenic origin. The rectorial concentrations of anthropogenic metals and PM 10 were higher for north -west sector with calm or low wind speed conditions than for any other sector with high wind speed conditions. On the contrary, the rectorial concentrations of crustal metals were high with high wind speed. In addition, the sectorial concentrations of crustal metals were more affected by south-west wind directions, which were compared with those of anthropogenic metals. The enrichment factor (EF) values of many anthropogenic metals were higher than 50, while those of crustal metals were lower than 3, respectively. The concentrations of Cr and Ni in Daejeon industrial complex area were 11 times higher than those in the background site of Kuopio in Finland, while that of Pb in the complex area was 22 times higher, respectively.

• 한국환경복원기술학회지
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• 제13권5호
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• pp.172-179
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• 2010

This study was conducted to establish a management plan for the Songrim woodland restoration by analyzing the site characteristics of the Songrim Woodland Natural Monument (Natural Monument 445) in Hadong-Gun, Gyeongsangnam-Do, Korea. The Songrim woodland was a pure pine forest. To stimulate the growth of sub-trees or mid- story vegetation in both a non-rest year forest and a rest year forest, it is recommended to take a silvicultural practices such as pruning because canopy of over-story trees was closely covered. The Songrim woodland in the non-rest year forest severely competed among individual trees of DBH classes of 60 cm and height of 18 m, while the woodland in the rest-year forest competed with DBH classes of 62 cm and height of 10 m, respectively. Soil physical property such as soil hardness, soil pore space rates, and pF 2.7 was restored following the rest-year forest designation. Mean salt concentration in the Songrim woodland soils was 0.006%. The result suggests that it is needed to take a study to prevent the salt inputs to conserve the Songrim woodland.

• 한국대기환경학회지
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• 제12권5호
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• pp.541-554
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• 1996

A set of 1994 data was analyzed to investigate the characteristics of background surface SO$_{2}$ concentrations at Kosan, Cheju Island, Korea. The SO$_{2}$ concentrations at Kosan site show a seasonal variation with a minimum(0.46 ppb) in summer, maximum(1.02 ppb) in spring and an annual mean of 0.83 ppb. These values were 4-7 times higher than those measured in other remote areas, such as Bermuda and Oki Island, but they were similar to the baseline concentrations of other sites in the world. The diurnal variation of SO$_{2}$ concentrations was very small and it shows a peak at 10 am in spring and fall, 2 pm in summer, and 1 pm in winter, respectively. Correlations between local meteorological parameters and SO$_{2}$ concentrations were mot significant. This suggests that the variations of the Kosan's SO$_{2}$ comcentrations were relatively independent on local meteorological variables. Backward trajectory analysis results showed that the seasonal variation of the OS$_{2}$ concentration was mainly due to the inflow of air masses from the continent in spring and from the Pacific Ocean im summer. The results also revealed that the air masses with the highest SO$_{2}$ concentration came through China or the Korea peninsula in spring and through Japan during summer. It was found that the SO$_{2}$ concentrations at Kosan were under the influence of passage of air masses arriving at this site.

• 한국환경과학회지
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• 제22권7호
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• pp.787-799
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• 2013

The aim of this study was to investigate the accumulation of metallic elements and the control effect of marine pollution caused by ocean dumping in the sediments at a waste disposal area in the Yellow Sea. In July 2009, concentrations of organic matter and metallic elements (Al, Fe, As, Cd, Cr, Co, Hg, Ni, Mn, Pb, and Zn) were measured in surface sediments at the site. The ignition loss (IL) in the surface sediments showed a mean value of 15.4%, about 1.5 times higher than the mean value of the sediments in the coastal areas of Korea. The chemical oxygen demand (COD) at some disposal sites exceeded 20 mg $O_2/g{\cdot}dry$, which signifies the initial concentration of marine sediment pollutants in Japan. The disposal sites contain higher concentrations of Cr, Cu and Zn than the sediments of bays and estuaries that might be contaminated. The magnitude of both metal enrichment factors (EF) and adverse biological effects suggest that pollution with Cr and Ni occurred due to the dumping of waste in the study area. In addition, the geoaccumulation index (Igeo) showed that the surface sediments were moderately contaminated. By the mid-2000s, when the amount of waste dumped at this site was the highest, the concentration of metallic elements was higher than ever recorded. On the other hand, in 2008-09, the need for environmental management was relatively low compare with the peak. As a result, the quality of marine sediment has been enhanced, considering the effect of waste reduction and natural dilution in the disposal area.

• 한국대기환경학회지
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• 제17권4호
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• pp.299-312
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• 2001

The analysis of vent -emitted Hg concentrations and relevant environmental parameters was made from the inlet of 42 ventpipes in Nan-Ji-Do area of Seoul during September/october of 2000. Using these data, the fluxes of Hg from the ventpipes were also derived. The mean concentration of Hg, computed using the data sets collected from 42 ventpipes, was 420$\pm$619ng m$^{-3}$ with the range of 3.45~2,952ng m$^{-3}$ . Because of large differences in concentration levels between two sectors 1 and 2 and between plain and slope areas. evaluation of the data was made by dividing them into four different categories such as plain areas of sectors 1 and 2 (and/or slope areas of sectors 1 and 2). When this classification was applied, the computed fluxes were highly different among each group with the generally enhanced fluxes in plain area relative to slope area. The computed fluxes were then used to make comparative analysis of different source processes in the study area.

• 대한환경공학회지
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• 제32권11호
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• pp.995-1000
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• 2010

하천 퇴적물 중 PCBs 농도수준 파악과 발생원 추정을 위해 낙동강 수계를 대상으로 21개 지점을 선정하고 지점당 3개씩 총 63개의 샘플을 분석한 결과 퇴적물 표층에서 검출된 DL-PCBs 농도분포는 3.0~6,600(평균440) pg/g-dry의 범위였고 TEQ값은

• 한국대기환경학회지
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• 제14권1호
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• pp.1-10
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• 1998

Relationships between TSP and PM10 concentrations were evaluated using their respective data sets collected from Taegu and Kyeungsan areas during the period of December 1993 to November 1994. The collection of data was made using the gravimetric and $\beta$-ray absorption ($\beta$-MPM) methods for 7 days of every month from three urban sites in Taegu and one suburban site in Kyeungsan. Correlation coefficients between TSP and PM10 concentrations for these four sampling sites were found in the range of 0.85 $\sim$ 0.96. Correlation analysis was also conducted for $\beta$-PM concentration data that were measured only from the residential and commercial sites. The correlation coefficients between TSP and $\beta$-PM concentrations were 0.9 in the residential site and 0.8 in the commercial site. By contrast, the correlation coefficients between PM10 $\beta$-PM concentrations were almost identical for both the residential and commercial sites with a value of 0.88. The mean ratio for PM10 to TSP concentrations for all sites was appeared to be 0.68. The analysis of seasonal trends in PM10/TSP ratios showed that the contribution of PM10 to TSP concentrations was more significant during winter (0.70 $\sim$ 0.75) than during summer (0.61 $\sim$ 0.68). The results of this study may provide empirical informations on the compatability of aerosol data measured by different sampling methods.

• 한국대기환경학회지
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• 제24권3호
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• pp.367-375
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• 2008

To characterize atmospheric particles in Cheonan area, 5 monitoring sites representing highway area, commercial area, residential area, and industrial areas were selected, and the mass concentrations of PM10 and PM2.5 were monitored for 14 days at each site during 2007. The daily average PM10 and PM2.5 concentrations were in the range from 18.5 to $140.9{\mu}g/m^3$ and 8.2 to $116.6{\mu}g/m^3$, respectively, showing the highest mean concentrations at the commercial area site and the lowest concentration at the residential area site. The daily average PM 10 concentrations at Shinan (Commercial area) and Bakseok (Industrial area) sites were exceeded the current National Standard for 1 and 2 days during the monitoring periods. The fractions of PM2.5 in PM10 were above 70% for all sites, indicating fine particles are the major constituent of atmospheric particles in Cheonan. The results indicate that PM10 concentrations in Cheonan are at the concerning level, and the control strategy for fine particles is necessary to address this issue.

• Bulletin of the Korean Chemical Society
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• 제16권9호
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• pp.873-885
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• 1995

The local structural and thermodynamical properties of blends A-B/H of a diblock copolymer A-B and a homopolymer H are studied using the polymer reference interaction site model (RISM) integral equation theory with the mean-spherical approximation closure. The random phase approximation (RPA)-like static scattering function is derived and the interaction parameter is obtained to investigate the phase transition behaviors in A-B/H blends effectively. The dependences of the microscopic interaction parameter and the macrophase-microphase separation on temperature, molecular weight, block composition and segment size ratio of the diblock copolymer, density, and concentration of the added homopolymer, are investigated numerically within the framework of Gaussian chain statistics. The numerical calculations of site-site interchain pair correlation functions are performed to see the local structures for the model blends. The calculated phase diagrams for A-B/H blends from the polymer RISM theory are compared with results by the RPA model and transmission electron microscopy (TEM). Our extended formal version shows the different feature from RPA in the microscopic phase separation behavior, but shows the consistency with TEM qualitatively. Scaling relationships of scattering peak, interaction parameter, and temperature at the microphase separation are obtained for the molecular weight of diblock copolymer. They are compared with the recent data by small-angle neutron scattering measurements.

• 환경위생공학
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• 제10권3호
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• pp.85-98
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• 1995

In order to ensure that all major cations and anions were accurately measured, the quality assurance checks of chemical analysis data by considering ion and conductivity balance of each precipitation sample were performed. To check the quality assurance of chemical analysis data, precipitation samples were collected by wet- only precipitation sampler at Seoul site and their chemical components were analyzed. By checking the problems for the screening methods of chemical analysis data used until recently, the f value expressed as the ratio of the sum of cations and anions equivalent concentration( $\Sigma $C/$\Sigma $A ) was found to be not ap priorate for data screening. Also, the scattering plot between cation and anion equivalent concentrations in each sample was found to show the general tendency of ion balance but was proved to not quantitate the standard of data screening at a set of samples of various concentration levels.4 more appropriate value was therefore required, h value is defined as (A-C)/C for C≥A and ( A-C)/A for C<4. This value was showed to check the ion balance in a viewpoint of quantitative as well as qualitative and to be useful in applying this expression to a measurement data set. However, the standard o( data screening must vary in response to the ion concentration of sample. In this study, the quality assurance of chemical analysis data was checked by considering both the ion balance evaluating by h value and the electrical conductivity. As these quality assurance checks were applied to Seoul data serf 67 valid samples were obtained. The result of statistical summary in the analytical parameter of precipitation samples collected for a certain period was found to be computed in the precipitation volume- weighted mean( VWM) rather than the arithmetic mean( AM), but PH In the VWM of hydrogen ion concentration. The annual VWM of pH values was 5.0(4.9 ∼ 5.1).