• 제목/요약/키워드: Sintering aids

검색결과 104건 처리시간 0.027초

소결조제 첨가에 따른 PMW-PMN-PZT 세라믹의 저온소결 특성 (Low temperature sintering properties of the $Pb(Mg_{1/2}W_{1/2})O_3-Pb(Mn_{1/3}Nb_{2/3})O_3-Pb(Zi,Ti)O_3$ ceramics with the addition of sintering aids)

  • 이현석;류주현;이창배;정영호;백동수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.350-351
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    • 2005
  • In this study, in order to develop the low temperature sintering multilayer piezoelectric transformer, PMW-PMN-PZT system ceramics were manufactured with the addition of sintering aids, and their dielectric and piezoelectric characteristics were investigated. At the composition ceramics sintered at $900^{\circ}C$, dielectric constant(${\varepsilon}r$), electromechanical coupling factor(kp) and mechanical quality factor(Qm) showed the optimal value of 1043, 0.44 and 793, respectively, for multilayer piezoelectric transformer application.

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소결조제 변화에 따른 PZW-PMN-PZT 압전 세라믹의 압전 및 유전 특성 (Piezoelectric and dielectric properties of PZW-PMN-PZT piezoelectric ceramic according to variation of sintering aids.)

  • 이갑수;이일하;류주현;류성림
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.290-291
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    • 2007
  • In this study, in order to develop the low temperature sintering multilayer piezoelectric actuator, PZW-PMN-PZT system ceramics were manufactured according to variation of sintering aids. At the sintering temperature of $900^{\circ}C$, $0.3wt%Li_2CO_3$, $0.2wt%Bi_2O_3$ and 0.2wt%CuO added specimen showed a maximum value of kp = 0.552, $d_{33}\;=\;344pC/N$ and Qm = 1320, respectively.

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저온소결 압전변압기용 PMW-PMN-PZT 의 압전특성 (Piezoelectric Characteristics of Low temperature sintering PMW-PMN-PZT Ceramics for Piezoelecric Transformer)

  • 이현석;정광현;류주현;박창엽;류성림;정영호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.214-215
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    • 2005
  • In this paper, in order to develop low temperature sintering piezoelectric ceramics for piezoelectric transformer, PMW-PMN-PZT ceramics using 0.25wt%$CaCO_3$ and 0.2wt%$Li_2CO_3$ as sintering aids were fabricated according to the variation of amount of PMW and Zr/Ti ratio. Specimens could be sintered at 900$^{\circ}C$ by adding sintering aids. As Zr/Ti ratio was increased, kp was increased and Qm was decreased by approaching MPB region, and kp showed the largest value of 0.58 at Zr/Ti:50/50. The variation of amount of PMN substitution affected the liquid phase sintering of the ceramics using sintering aids, and decreased piezoelectric properties.

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소결조제를 달리해 상압 반응소결로 제조된 AlON의 투명도 (Transparency of AlON Fabricated by Pressureless Reaction Sintering Using Various Sintering Aids)

  • 구본경;구교헌;김지혜;정인철;이재형
    • 한국세라믹학회지
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    • 제46권4호
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    • pp.392-396
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    • 2009
  • AlON was fabricated by the pressureless reaction sintering of $Al_2O_3$-AlN powder mixtures. The ratio of AlN to $Al_2O_3$ as well as various sintering aids were the main variables for this study. The optimum ratio of AlN in the $Al_2O_3$-AlN mixture was approximately 35.0 mol%. For the sintering aids, only when a small amount of MgO was added together with $Y_2O_3$ and BN, AlON specimens could be sintered to a full density with negligible pores and high transparency. Other combinations of $Y_2O_3$, BN, CaO and MgO resulted in enough pores in the sintered specimens to have in-line transmittance only between 0% and 30%. The in-line transmittance reached over 80% after sintering at $1975^{\circ}C$ for 10 h for the specimen containing 0.15 wt% MgO, 0.08 wt% $Y_2O_3$ and 0.02 wt% BN.

$MnO_2$ 첨가방법에 따른 PMN-PNN-PZT 세라믹스의 유전 및 압전특성 (Dielectric and Piezoelectric Characteristics of PMN-PNN-PZT Ceramics with the methods of $MnO_2$ additon)

  • 김도형;김국진;류주현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.255-256
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    • 2007
  • In the study, in order to develop low temperature sintering ceramics for multilayer piezoelectric actuator, PMN-PNN-PZT ceramics were fabricated using $Na_2CO_3,\;Li_2CO_3$ as sintering aids and their dielectric and piezoelectric properties were investigated according to the variations of $MnO_2$ as additives and sintering aids. At the sintering temperature of $900^{\circ}C$ and 0.1wt% $MnO_2$ as sintering aids, density, electromechanical coupling factor$(k_p)$, mechanical quality factor$(Q_m)$, piezoelectric constant$(d_{33})$, and dielectric constant $({\varepsilon}_r)$ showed the optimum value of $7.87[g/cm^3]$, 0.61, 1131, 1127 and 376, respectively, for multilayer piezoelectric actuator application.

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소결 조제를 이용한 고체산화물 연료전지용 세리아 전해질의 저온소결 특성 연구 (A Study of Ceria on Low-temperature Sintering Using Sintering Aids for Solid Oxide Fuel Cells)

  • 오창훈;송광호;한종희;윤성필
    • 한국수소및신에너지학회논문집
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    • 제25권3호
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    • pp.280-288
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    • 2014
  • SDC (Samarium doped Ceria) electrolyte was developed for Intermediate temperature SOFC ($500^{\circ}C-800^{\circ}C$) which showed a good electrical conductivity. In this study, we used sintering aids to reduce the SDC sintering temperature down to $1000^{\circ}C$, especially which can help the SOFC scale-up. In order to reduce the SDC sintering temperature, $Li_2CO_3$ and $TiO_2$ were used as a sinering aids for decreasing sintering temperature. $Li_2CO_3$ and $TiO_2$ doped SDC sintered at $1000^{\circ}C$ showed 99% of the theoretical density and higher electrical conductivity than the pure SDC sintered at $1500^{\circ}C$. When measuring the OCV (Open circuit voltage) with the $Li_2CO_3$ and $TiO_2$ doped SDC electrolyte, however, the OCV values were lower than the theoretical OCV values which means that the modified SDC still had electronic conductivity.

$MnO_2$ 첨가에 따른 저온소결 PCW-PMN-PZT 세라믹스의 유전 및 압전특성에 관한 연구 (A Study on the Dielectric and Piezoelectric properties of Low temperature sintering CW-PMN-PZT Ceramics according to the amount of $MnO_2$ addition)

  • 정광현;이덕출;류주현;박창엽;정영호
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.82-85
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    • 2004
  • In this study, in order to increase piezoelectric properties of the low temperature sintering ceramics for multilayer piezoelectric transformer, PCW-PMN-PZT ceramics added with $Li_2CO_3$, $Bi_2O_3$ and CuO as sintering aids were manufactured according to the amount of $MnO_2$ addition, and their microstructural, dielectric and piezoelectric properties were investigated. When the sintering aids was added, specimens could be sintered at $950^{\circ}C$. However, sintering aids added specimens showed lower piezoelectric properties than those of non-added specimens. $0.1wt%MnO_2$ added specimen at $950^{\circ}C$ showed ${\varepsilon}_r$, of 1503, $k_p$ of 0.57 and $Q_m$ of 1502 were shown, respectively, and showed optimum properties for multilayer piezoelectric transformer.

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알루미나와 이트리아가 질화규소의 가공성에 미치는 영향 (Effect of $Al_2O_3$ and $Y_2O_3$ on Machining of Silicon itride)

  • 이수완;장태석;엄호성
    • 한국세라믹학회지
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    • 제33권3호
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    • pp.269-276
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    • 1996
  • The effect of sintering aids on the sinterability for silcion nitride has been studied by hundreds workers. However the effect of sintering aids on the machinability as the own trobles which is the major barrier for the field applications of the ceramic components has not been fully studied. in this study the contents of Al2O3 and Y2O3 in silicon nitride were varied from 0 to 8 wt% respectively. The physical and mechanical properties of the silcion nitride were measured. The optimal microstructure of silicon nitride balls with the excellent machinability by adding with various contents of sintering aids was studied by MGF(magnetic-fluid grinding)technique. An attempt to figure out how the mechanical properties influence the machinability of silicon-nitride ball was made.

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저온소결 PMN-PNN-PZT세라믹스의 $WO_3$첨가에 따른 압전 및 유전특성 (Piezoelectric and Dielectric Characteristics of Low Temperature Sintering PMN-PNN-PZT ceramics with the amount of $WO_3$ addition)

  • 김국진;류주현;정영호
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.61-62
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    • 2006
  • In this study, in order to develop the low temperature sintering ceramics for multilayer piezoelectric actuator, PMN-PNN-PZT ceramics using ${Fe_2}{O_3}$ and $WO_3$ as sintering aids were manufactured with the amount of $WO_3$ addition, and the specimens were sintered at 900, 930, $960^{\circ}C$, respectively. Thereafter, their dielectric and piezoelectric properties were investigated. The sintering aids were proved to lower the sintering temperature of piezoelectric ceramics due to the effects of ${Fe_2}{O_3}$ and $WO_3$ liquid phase. At 0.3wt% $WO_3$ added specimen sintered at $930^{\circ}C$, kp, Qm, dielectric constant and $d_{33}$ showed the optimum values of 0.60, 1402, 1440 and 360[pC/N], respectively, for multilayer piezoelectric actuator application.

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소결조제 Li2CO3 첨가에 따른 저온소결(K0.5Na0.5)NbO3 세라믹스의 압전 및 유전 특성 (Piezoelectric and Dielectric Properties of Low Temperature Sintering (K0.5Na0.5)NbO3 Ceramics according to Sintering Aid Li2CO3)

  • 이일하;류주현
    • 한국전기전자재료학회논문지
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    • 제21권10호
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    • pp.906-910
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    • 2008
  • $(K_{0.5}Na_{0.5})NbO_3$ (NKN) ceramics doped with $Li_{2}CO_3$ as sintering aids were manufactured in order to develop the low temperature sintering ceramics for piezoelectric device. The sintering aids were proved to lower the sintering temperature of doped NKN ceramics due to the effect of $Na_{2}CO_{3}-Li_{2}CO_3$ liquid phase. All the specimens showed the orthorhombic phase without secondary phase. And also, the piezoelectric properties of specimens were improved with increasing $Li_{2}CO_3$ contents. At sintering temperature of $930^{\circ}C$, the density, electromechanical coupling factor (kp), mechanical quality factor (Qm) and dielectric constant(${\epsilon}_{\gamma}$), piezoelectric constant of 0.3 wt.% $Li_{2}CO_3$ added specimen showed the optimum values of $4.255 g/cm^3$, 0.37, 234, 309, 136 pC/N, respectively.