• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.161-165
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• 2007

Recently by the development of the electronic engineering technology various mobile devices are developed. But their operation time need to be extended although capacity of the batteries are limited. We focused our attention to the portable SOFC system. Because SOFC has the high efficiency and a lot of strongness in comparison with other kinds of fuel cells. In addition they can be built as a self/non-reformable system and single/dual chamber system. So We evaluated some types of SOFC theoretically, and compared the results from the fuel and performance efficiency point of view.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.29 no.8
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• pp.510-515
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• 2016

Single-chamber solid oxide fuel cells (SC-SOFCs) consist of only one gas chamber, in which both the anode and the cathode are exposed to the same fuel-oxidant mixture. Thus, this configuration shows good thermal and mechanical resistance and allows rapid start-up and -down. In this study, the unit cell consisting of $La_{0.8}Sr_{0.2}MnO_3$ (cathode) / $Zr_{0.84}Y_{0.16}O_{2-x}$ (electrolyte) / $Ni-Zr_{0.84}Y_{0.16}O_{2-x}$ (anode) was fabricated and its electrochemical property was investigated as a function of temperature and the volume ratio of fuel and oxidant for SC-SOFCs. Impedance spectra were also investigated in order to figure out the electrical characteristics of the cell. As a result, the cell performance was governed by the polarization resistances of the electrodes. The cell exhibited an acceptable cell-performance of $86mW/cm^2$ at $800^{\circ}C$ and stable performance for 3 hs under 0.7 V.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.306-309
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• 2005

One of the most critical issues in sol id oxide fuel cell (SOFC)running on hydrocarbon fuels is the risk of carbon formation from the fuel gas. The simple method to reduce the risk of carbon formation from the reactions is to add steam to the fuel stream, leading to the carbon gasification react ion. However, the addition of steam to fuel is not appropriate for the auxiliary power unit (APU) and potable power generation (PPG) systems due to an increase of complexity and bulkiness. In this regard, many researchers have focused on so-called 'direct methane' operation of SOFC, which works with dry methane without coking. However, coking can be suppressed only by the operation with a high current density, which may be a drawback especially for the APU and PPG systems. The single chamber fuel cell (SC-SOFC) is a novel simplification of the conventional SOFC into which a premixed fuel/air mixture is introduced. It relies on the selectivity of the anode and cathode catalysts to generate a chemical potential gradient across the cell. Moreover it allows compact and seal-free stack design. In this study, we fabricated honeycomb type mixed-gas fuel cell (MGFC) which has advantages of stacking to the axial direction and increasing volume power density. Honeycomb-structured SOFC with four channels was prepared by dry pressing method. Two alternative channels were coated with electrolyte and cathode slurry in order to make cathodic reaction sites. We will discuss that the anode supported honeycomb type cell running on mixed gas condition.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.45-48
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• 2008

This paper presents a passive air-breathing direct methanol fuel cell (DMFC) which has been designed and tested. The single cell is fuelled by methanol vapor that is supplied through flow channel from a methanol reservoir at the anode, and the oxygen is supplied via natural air-breathing at the cathode. The methods for supplying the methanol vapor to the single cell were parallel channel and chamber. This research investigates various methods to identify the effects of using flow channels for providing the methanol vapor at the anode, and the opening ratio between the inlet and outlet ports for the methanol flow at the anode. The best flow channel condition for passive DMFC was a chamber, and the opening ratio was 0.8. Under these conditions, the peak power was 10.2mW/$cm^2$ at room temperature and ambient pressure. The key issues for the Passive DMFCs for using methanol vapor are that sufficient methanol needs to be supplied using a large as possible opening ratio. However, it is shown that the performance of the passive DMFC, which has a channel at the anode,is low due to the low differential pressure and insufficient methanol supply rate.

• Proceedings of the Korean Ceranic Society Conference
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• 2004.04b
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• pp.31.3-31.3
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• 2004

• Transactions of the Korean Society of Mechanical Engineers A
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• v.31 no.10
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• pp.981-985
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• 2007

We present a MEMS-based portable Direct Methanol Fuel Cell (micro-DFMC), featured by a platinum sputtered microcolumn electrode and a built-in fuel chamber containing a limited amount of methanol fuel. Also presented is a micro-DMFC stack structure having a common electrolyte sandwiched by the microcolumn electrodes. The single cells with ME16 and PE16 electrodes show the maximum power densities of $31.04{\pm}0.29{\mu}W/cm^2$ and $9.75{\pm}0.29{\mu}W/cm^2$, respectively; thus indicating the microcolumn electrode (ME16) generates the power density (3.2 times) higher than the planar electrode (PE16). The single cell tests of ME16 and ME4 electrodes (Fig.8) show the maximum power of $31.04{\pm}0.29{\mu}W/cm^2$, and $25.23{\pm}2.7{\mu}W/cm^2$, respectively; thus demonstrating the increased window frame reduces the normalized standard power deviation (standard deviation over the average power). The normalized deviation of 0.11 in ME4 cell has been reduced to 0.01 in ME16 cell due to the increased window frames. The maximum power density of 4-cell stack is 15.7 times higher than that of the single cell. 4-cell stack produces the power capacity of 20.3mWh/g during 980min operation at the voltage of 450mV with the load resistance of $800{\Omega}$.

• KEPCO Journal on Electric Power and Energy
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• v.2 no.4
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• pp.589-593
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• 2016

Microbial fuel cell (MFC) can produce electricity from oxidation-reduction of organic and inorganic matters by electrochemically active bacteria as catalyst. Stacked MFCs have been investigated for overcoming low electricity generation of single MFC. In this study, two-typed stacked-MFCs (submerged-flat and stand-falt) were operated according to electrode connection for optimal stacked technology of MFC. In case of submerged-flat MFC with all separator electrode assembly (SEA) sharing anode chamber, MFC with mixed-connection showed more voltage loss than MFC with single-connection method. And MFC stacked in parallel showed better voltage production than MFC stacked in series. In case of stand-flat MFC, voltage loss was bigger when SEAs sharing anodic chamber only were connected in series. Voltage loss was decreased when SEAs parallel connected SEAs sharing anodic chamber were connected in series.

• Journal of the Korean Ceramic Society
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• v.43 no.12 s.295
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• pp.798-804
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• 2006

Co-planar type single chamber solid oxide fuel cell with patterned electrode on a surface of electrolyte has been fabricated by robo-dispensing method and microfluidic lithography. The cells were composed of NiO-GDC-Pd or NiO-SDC cermet anode, $(La_{0.7}Sr_{0.3})_{0.95}MnO_3$ cathode, and yttria stablized zirconia electrolyte. The cell performance at $900^{\circ}C$ was investigated as a function of electrode geometries, such as anode-to-cathode distance, numbers of electrode pairs. Relationship between OCV and I-V characteristics at the optimized operation condition was also studied by DC source meter under the mixed gas condition of methane, air, and nitrogen. An increase of anode-facing-cathode area leads to lower OCV due to intermixing between product gases of anode and cathode, which in turn decreases the oxygen partial pressure difference.

• Journal of the Korean Ceramic Society
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• v.43 no.11 s.294
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• pp.746-750
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• 2006

NiO films and Ru co-sputtered NiO films were deposited by reactive magnetron sputtering for micro-solid oxide fuel cell anode applications. The deposited films were reduced to form porous films. The reduction kinetics of the Ru doped NiO film was more sluggish than that of the NiO film, and the resulting microstructure of the former exhibited finer pore networks. The possibility of using the films for the anodes of single chamber micro-SOFCs was investigated using an air/fuel mixed environment. It was found that the abrupt increase in the resistance is suppressed in the Ru co-sputtered film, as compared to undoped film.

• Journal of Microbiology and Biotechnology
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• v.25 no.7
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• pp.1114-1118
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• 2015

Microbial fuel cells (MFCs) have gathered attention as a novel bioenergy technology to simultaneously treat wastewater with less sludge production than the conventional activated sludge system. In two different operations of the MFC and aerobic process, microbial growth was determined by the protein assay method and their biomass yields using real wastewater were compared. The biomass yield on the anode electrode of the MFC was 0.02 g-COD-cell/gCOD-substrate and the anolyte planktonic biomass was 0.14 g-COD-cell/g-COD-substrate. An MFC without anode electrode resulted in the biomass yield of 0.07 ± 0.03 g-COD-cell/g-CODsubstrate, suggesting that oxygen diffusion from the cathode possibly supported the microbial growth. In a comparative test, the biomass yield under aerobic environment was 0.46 ± 0.07 g-COD-cell/g-COD-substrate, which was about 3 times higher than the total biomass value in the MFC operation.