• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2008년도 추계학술대회 논문집
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• pp.431-434
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• 2008

In the present study, direct quenching of alloyed steel after hot forging was simulated using commercial finite element program, $FORGE^{TM}$. A typical heat treatment of alloyed steels consists of quenching for hard martensite and subsequent tempering for toughness. In the practice, forgings which cool down to room temperature are heated to temperature of austenite regime. As investigated in the present study, direct quenching of hot forged stock would be beneficial in terms of energy saving. This process has already been propose and termed as ausforging or forged hardening. However, it is well known that quenching temperature would be the most critical factor to control heat treated forging properties. And it is very difficult to control quenching temperature when forged stock gets directly quenched after forging. In this study, we have calculated final forging temperature of stock. Also, quenching simulation was conducted using a series of material parameter which were also calculated using JMATpro, a commercial program for physical properties of materials.

• 열처리공학회지
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• 제8권1호
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• pp.53-64
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• 1995

A study was made to characterize the microstructures and mechanical properties of the base metal and the heat-affected zone(HAZ) in Cu-bearing HSLA-100 steel. The Gleeble thermal/mechanical simulator was used to simulated the weld HAZ. The relationship between microstructure and toughness of HAZ was studied by impact test, O. M, SEM, TEM, and DSC. The toughness requirement of military specification value was met in all test temperatures for the base metal. The decrease of HAZ toughness comparing to base plate is ascribed to the coarsed-grain and the formation of bainite. Obliquely sectioned Charpy specimens show that secondary crack propagate easily along bainite lath. Improved toughness(240J) at HAZ of $Tp_2=950^{\circ}C$ is due to the fine grain, and reasonable toughness(160~00J) in the intercritical reheated HZA is achieved by the addition of small amount of carbon which affects the formation of "M-A". Cu precipitated during ageing for increasing the strength of base metal is dissolved during single thermal cycle to $1,350^{\circ}C$ and is precipitated little on cooling and heating during subsequent weld thermal cycle. Thus, the decrease of toughness does not occur owing to the precipitation of Cu.

• 한국재료학회지
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• 제21권1호
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• pp.39-45
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• 2011

In this study, the heat flow of the plant scale aluminum extrusion process was investigated to establish optimum continuous heat treatment conditions. During the extrusion of 6061 aluminum alloy, processing parameters such as the extrusion pressure, speed and temperature histories of billets were logged as a function of time. The surface temperature of the billets increased at constant ram speed, while it decreased with decreases of the ram speed. In order to maintain the billet temperature within a solutionizing temperature range prior to the succeeding water quenching step, the ram speed or the temperature of the blower should be controlled. The temperature histories of the billets during the extrusion and hot air blowing processes were successfully simulated by using the velocity boundary model in ANSYS CFX. The methodology to design an optimum process by using a commercial simulation program is described in this study on the basis of the metallurgical validation results of the microstructural observation of the extrudates. The developed model allowed the advantages of taking into account the motion of the extrudate coupled with the temperature change based on empirical data. Calculations were made for the extrudate passing through the isothermal chamber maintained at appropriate temperature. It was confirmed that the continuous heat treatment system is beneficial to the productivity enhancement of the commercial aluminum extrusion industry.

• Journal of Ginseng Research
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• 제39권4호
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• pp.304-313
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• 2015

Background: Ginsenoside Rg3 is a promising anticancer agent. It is usually produced by heat treatment of ginseng, in which ginsenoside Rb1 is the major ginsenoside. A kinetic study was conducted to optimize ginsenoside Rg3 production by the heat treatment of ginsenoside Rb1. Methods: Ginsenoside Rb1 was heated using an isothermal machine at $80^{\circ}C$ and $100^{\circ}C$ and analyzed using HPLC. The kinetic parameters were calculated from the experimental results. The activation energy was estimated and used to simulate the process. The optimized parameters of ginsenoside Rg3 production are suggested based on the simulation. Results: The rate constants were $0.013h^{-1}$ and $0.073h^{-1}$ for the degradation of ginsenosides Rb1 and Rg3 at $80^{\circ}C$, respectively. The corresponding rate constants at $100^{\circ}C$ were $0.045h^{-1}$ and $0.155h^{-1}$. The estimated activation energies of degradation of ginsenosides Rb1 and Rg3 were 69.2 kJ/mol and 40.9 kJ/mol, respectively. The rate constants at different temperatures were evaluated using the estimated activation energies, and the kinetic profiles of ginsenosides Rb1 and Rg3 at each temperature were simulated based on the proposed kinetic model of consecutive reaction. The optimum strategies for producing ginsenoside Rg3 from ginsenoside Rb1 are suggested based on the simulation. With increased temperature, a high concentration of ginsenoside Rg3 is formed rapidly. However, the concentration decreases quickly after the reaching the maximal concentration value. Conclusion: The optimum temperature for producing ginsenoside Rg3 should be the highest temperature technically feasible below $180^{\circ}C$, in consideration of the cooling time. The optimum reaction time for heat treatment is 30 min.

• 대한기계학회논문집A
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• 제36권9호
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• pp.1059-1064
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• 2012

본 연구에서는 냉간 굽힘 후 잔류응력 제거 열처리된 곡관에서 기계적물성치를 파악하기 위해서, 냉간 굽힘과 잔류응력 제거 열처리를 모사한 모사시편을 이용하여 인장시험을 수행하였다. 시험 결과로부터 냉간 가공 후 잔류응력 제거 열처리를 수행할지라도 재료의 강도는 냉간 가공 전에 비해 증가하고 연성은 감소되는 것을 확인하였다. 또한, 강도 증가와 연성 감소는 냉간 가공시 적용된 변형률이 클수록 심화되었다. 따라서, 냉간 굽힘시 변형이 크게 발생하는 곡관의 외호부와 내호부는 직관에 비해 강도는 높고 연성은 낮을 것으로 예측되며, 곡관의 측면은 굽힘 가공 전의 직관과 유사한 기계적물성치를 보일 것으로 예측되었다.

• 열처리공학회지
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• 제18권2호
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• pp.112-118
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• 2005

Study was focused on the effect of the cooling rate on the embrittlement behavior of Zircaloy-4 cladding simulated Loss Of Coolant Accident (LOCA) environment. Claddings were oxidized at given temperature and given time followed by various water quenching in the range of $0.6^{\circ}C$ and $100^{\circ}C$ per second. Cladding failed after water quenching above the threshold oxidation. Threshold oxidation was decreased as the cooling rate increased, which is due to the matensite structure formed during fast cooling rate.

• 한국표면공학회지
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• 제56권6호
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• pp.401-411
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• 2023

This study investigates the synthesis, characterization, and application of zinc oxide (ZnO) nanoparticles for corrosion resistance and stress corrosion cracking (SCC) mitigation in high-temperature and high-pressure environments. The ZnO nanoparticles are synthesized using plasma discharge in water, resulting in rod-shaped particles with a hexagonal crystal structure. The ZnO nanoparticles are applied to Alloy 600 tubes in simulated nuclear power plant atmospheres to evaluate their effectiveness. X-ray diffraction and X-ray photoelectron spectroscopy analysis reveals the formation of thermodynamically stable ZnCr₂O₄and ZnFe₂O₄ spinel phases with a depth of approximately 35 nm on the surface after 240 hours of treatment. Stress corrosion cracking (SCC) mitigation experiments reveal that ZnO treatment enhances thermal and mechanical stability. The ZnO-treated specimens exhibit increased maximum temperature tolerance up to 310 ℃ and higher-pressure resistance up to 60 bar compared to non-treated ZnO samples. Measurements of crack length indicate reduced crack propagation in ZnO-treated specimens. The formation of thermodynamically stable Zn spinel structures on the surface of Alloy 600 and the subsequent improvements in surface properties contribute to the enhanced durability and performance of the material in challenging high-temperature and high-pressure environments. These findings have significant implications for the development of corrosion-resistant materials and the mitigation of stress corrosion cracking in various industries.

• 대한치과교정학회지
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• 제44권5호
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• pp.246-253
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• 2014

Objective: To evaluate the bioactivity, and the biomechanical and bone-regenerative properties of Ti6Al4V miniscrews subjected to anodization, cyclic precalcification, and heat treatment (APH treatment) and their potential clinical use. Methods: The surfaces of Ti6Al4V alloys were modified by APH treatment. Bioactivity was assessed after immersion in simulated body fluid for 3 days. The hydrophilicity and the roughness of APH-treated surfaces were compared with those of untreated (UT) and anodized and heat-treated (AH) samples. For in vivo tests, 32 miniscrews (16 UT and 16 APH) were inserted into 16 Wistar rats, one UT and one APH-treated miniscrew in either tibia. The miniscrews were extracted after 3 and 6 weeks and their osseointegration (n = 8 for each time point and group) was investigated by surface and histological analyses and removal torque measurements. Results: APH treatment formed a dense surface array of nanotubular TiO2 layer covered with a compact apatite-like film. APH-treated samples showed better bioactivity and biocompatibility compared with UT and AH samples. In vivo, APH-treated miniscrews showed higher removal torque and bone-to-implant contact than did UT miniscrews, after both 3 and 6 weeks (p < 0.05). Also, early deposition of densely mineralized bone around APH-treated miniscrews was observed, implying good bonding to the treated surface. Conclusions: APH treatment enhanced the bioactivity, and the biomechanical and bone regenerative properties of the Ti6Al4V alloy miniscrews. The enhanced initial stability afforded should be valuable in orthodontic applications.

• The Korean Journal of Ceramics
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• 제4권4호
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• pp.336-339
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• 1998

Bioactive titanium metal can be prepared by simple 5M-NaOH treatment and subsuquent heat treatment at $600^{\circ}C$ to form an amorphous sodium titanate on its surface. In the present study, mechanism of apatite formation on the titanium metal was investigated by examining its surface compositional and structural changes in a simulated body fluid. The apatite formation on the metal was found to proceed in the sequence of 1)$Na^+$ ion release from the sodium titanate to form hydrated titania abundant in Ti-OH groups, 2) early and selective binding of calcium ions with the Ti-OH groups to form a calcium titanate, and 3) late binding of phosphate ions to make apatite nucleation and growth. This indicates that Ti-OH groups do not directly induce the apatite nucleation, but via formation of a calcium titanate.

• 한국해양공학회지
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• 제21권5호
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• pp.33-38
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• 2007

The welding methods have been applied in the most structural products from multi-field of automobile, ship construction and construction, and so on. The structure steel must have enough strength of structure. In this study, SS400 steel and STS304 steel were used to estimate the corrosion characteristics of the weld thermal cycle simulated HAZ. To evaluate the corrosion characteristics, also, the materials with two conditions were used in 3.5% NaCl. The one is to the drawing with diameter of ${\Phi}10$ and the other is to the residual stress removal treatment. The electrochemical polarization test and immersion test were carried out. From test results, corrosion potential, corrosion current density, weight loss ratio and corrosion rate were measured. In the kinds of SS400 steels, corrosion potential of weld thermal cycle simulated specimens after the heat treatment showed somewhat the direction of noble potential. And in the base metal to be drawing weight loss ratio and corrosion rate occurred higher than the other kinds. In the kinds of STS304 steels, the result of base metal to be drawing was similar to results of SS400 steels, too. Two kinds of $750^{\circ}C$ and $1300^{\circ}C$ of weld thermal cycle simulation after the heat treatment were rather higher than the other kinds in weight loss ratio and corrosion rate.