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Surface-modified Nanoparticle Additives for Wear Resistant Water-based Coatings for Galvanized Steel Plates

  • Becker-Willinger, Carsten;Heppe, Gisela;Opsoelder, Michael;Veith, H.C. Michael;Cho, Jae-Dong;Lee, Jae-Ryung
    • Corrosion Science and Technology
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    • v.9 no.4
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    • pp.147-152
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    • 2010
  • Conventional paints for conversion coating applications in steel production derived mainly from water-based polymer dispersions containing several additives actually show good general performance, but suffer from poor scratch and abrasion resistance during use. The reason for this is because the relatively soft organic binder matrix dominates the mechanical surface properties. In order to maintain the high quality and decorative function of coated steel sheets, the mechanical performance of the surface needs to be improved significantly. In fact the wear resistance should be enhanced without affecting the optical appearance of the coatings by using appropriate nanoparticulate additives. In this direction, nanocomposite coating compositions (Nanomer$^{(R)}$) have been derived from water-based polymer dispersions with an increasing amount of surface-modified nanoparticles in aqueous dispersion in order to monitor the effect of degree of filling with rigid nanoparticles. The surface of nanoparticles has been modified for optimum compatibility with the polymer matrix in order to achieve homogeneous nanoparticle dispersion over the matrix. This approach has been extended in such a way that a more expanded hybrid network has been condensed on the nanoparticle surface by a hydrolytic condensation reaction in addition to the quasi-monolayer type small molecular surface modification. It was expected that this additional modification will lead to more intensive cross-linking in coating systems resulting in further improved scratch-resistance compared to simple addition of nanoparticles with quasi-monolayer surface modification. The resulting compositions have been coated on zinc-galvanized steel and cured. The wear resistance and the corrosion protection of the modified coating systems have been tested in dependence on the compositional change, the type of surface modification as well as the mixing conditions with different shear forces. It has been found out that for loading levels up to 50 wt.-% nanoparticles, the mechanical wear resistance remains almost unaffected compared to the unmodified resin. In addition, the corrosion resistance remained unaffected even after $180^{\circ}$ bending test showing that the flexibility of coating was not decreased by nanoparticle addition. Electron microscopy showed that the inorganic nanoparticles do not penetrate into the organic resin droplets during the mixing process but rather formed agglomerates outside the polymer droplet phase resulting in quite moderate cross linking while curing, because of viscosity. The proposed mechanisms of composite formation and cross linking could explain the poor effect regarding improvement of mechanical wear resistance and help to set up new synthesis strategies for improved nanocomposite morphologies, which should provide increased wear resistance.

On the Free Vibration Analysis of Thin-Walled Box Beams having Variable Cross-Sections (단면형상이 변하는 박판보의 진동해석에 관한 연구)

  • Lee, Gi-Jun;Sa, Jin-Yong;Kim, Jun-Sik
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.30 no.2
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    • pp.111-117
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    • 2017
  • In this paper, a local deformation effect in thin-walled box beams is investigated via a finite element modal analysis. The analysis is carried out for single-cell and multi-cell box beam configurations. The single-cell box beam with and without a neck, which mimics a simple wind-turbine blade, is analyzed first. The results obtained by shell elements are compared to those of one-dimensional(1D) beam elements. It is observed that the wall thickness plays a crucial role in the natural frequencies of the beam. The 1D beam analysis deviates from the shell analysis when the wall thickness is either thin or thick. The shell modes(local deformations) are dominant as it becomes thin, whereas the shear deformation effects are significant as it does thick. The analysis is extended to the single-cell box beam with a neck, in which the shell modes are confined to near the neck. Finally the multi-cell box beam with a taper, which is quite similar to real wind-turbine blade configuration, is considered to investigate the local deformation effect. The results reveal that the 1D beam analysis cannot match with the shell analysis due to the local deformation, especially for the lagwise frequencies. There are approximately 5~7% errors even if the number of segments is increased.

The Development of Real-time Feedback Vibration Control System Using Wireless Sensor Networks (무선 센서 네트워크를 이용한 실시간 Feedback 진동제어 시스템 개발)

  • Heo, Gwang Hee;Kim, Chung Gil;Ahn, Ui Jong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.3
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    • pp.60-66
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    • 2012
  • This paper aims to constitute a feedback vibration control system using wireless sensor networks and experiment it on a model structure to verify its effectiveness. For the purpose, we set up a feedback vibration control system composed of a wireless input/output(I/O) sensor node based on bluetooth, a home-made shear type MR damper, a shaker which generates a constant size of sine wave, and a simple beam model structure. The vibration control experiment was performed by shaking the 1/4 point of beam with a shaker. At the moment of shaking, we controled the vibration with MR damper which was placed vertically on the center of beam. Simultaneously, by acquiring acceleration response at the 2/4 point of beam, we evaluated the effectiveness of control capability. The control command was set to send a voltage signal to MR damper when the acceleration response, acquired from the wireless I/O sensor node placed at the center of beam, was more than a certain amount. Although the realtime feedback vibration control system constituted in this paper is effective only within a limited command system, it has been proven that the system was able to effectively decrease the vibration of structure by generating a control command aimed for realtime purpose. The system also showed a possibility to be used as a structural response control system adapting a variety of semi-active control algorithm.

The Structure of Oriental Wooden Pagoda (동양목조탑파(東洋木造塔婆)의 구조형식(構造形式)에 관한 연구(硏究) - 법주사(法住寺) 팔상전(捌相殿)과 법륭사(法隆寺) 오중탑(五重塔)의 비교분석적 측면에서 -)

  • Kim, Kyeong-Pyo;Fujii, Keisuke;Lee, Min-Sup
    • Journal of architectural history
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    • v.1 no.1 s.1
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    • pp.88-105
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    • 1992
  • This dissertation aims to investigate the structure of Palsangjeon, a five story wooden pagoda in Pubjoo Temple which is the only wooden pagoda existing in Korea, by a comparative study of the Palsangjeon with Japanese counterparts. By doing so, the writer of the present investigation attempts to find out its structural originality. The main finding of this study are as follows. The upper part of Palsangjeon is constructed with square log frameworks called GuiTl and Sacheon-Ju around the central column. The four walls along Sacheon-Ju from the 1st level to the 3rd well resists the outside horizontal piressure. And Gui-Tl structure on the 5th level copes much better with shear force. So this frame consisting of Sacheon-Ju and log frameworks might be viewed an semi-core system, This core is supported once again by the frame of Go-Ju. That is to say. Go-Ju supports frame of Sacheon-Ju. And the frame of Pyeong-Ju on the 4th and the 5th levels also supports it. The frame of Go-Ju is supported by the frame of Pyeong-Ju on the 1st and the 2nd levels. So this structure is designed to resist the wind and also keep the balance by properly distributing vertical pressure. The plan and the elevational structure of Palsangjeon keep the balance by the perfect symmetric structure. And the frame of Sacheon-Ju forming semi-core system can resist both the lateral load and the vertical pressure for the balance of its structure. The five story pagoda in Horyuji used to stand on a central which is desigend to support the main body of the pagoda from the first level. The principles of balance is used between the Ha-Aag and short to react the rafter. Sacheon-Ju and edge column is against the lateral load. The structural jointing system is stable thanks to the log framewroks formed on every level. The five story pagoda in Horyuji poseses the structual system originated from the ancient wooden pagoda. The pagoda is found to express simple, sincere and straight forward form. On the other hand, it could be seen as a stucture resisting the earthquake and the lateral load, Palsangjeon is an excellent building which religions function is well harmonized with its structure and appearance. It not only functions extremely well as a regions place like other pagodas, but also excellently shows how multi-story wooden building should be structured.

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Lateral-Torsional Buckling Strength of I-girder with Corrugated Steel Webs under Linear Moment Gradient (선형 모멘트 구배가 작용하는 파형강판 I-거더의횡-비틂 좌굴 강도)

  • Moon, Jiho;Lim, Nam-Hyoung;Lee, Hak-Eun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.3A
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    • pp.149-160
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    • 2012
  • Corrugated steel plates have several advantages such as high resistance for shear without stiffeners, minimization of welding process, and high fatigue resistance. To take advantage of these benefits, several researchers have attempted to use corrugated steel plate as a web of I-girders. The lateral-torsional buckling is the major design aspect of such I-girders. However, lateral-torsional buckling of the I-girder with corrugated steel webs still needs to be investigated especially for a real loading condition such as non-uniform bending. This paper investigated the lateral-torsional buckling strength of the I-girder with corrugated steel webs under linear moment gradient by using finite element analysis. From the results, it was found that the buckling behavior of the I-girder with corrugated steel webs differed depending on the number of periods of the corrugation. Also, a simple equation for the moment gradient correction factor of the I-girder with corrugated steel webs was suggested. The inelastic lateral-torsional buckling strength of the I-girder with corrugated steel webs was then discussed based on current design equations for ordinary I-girders and the results of finite element analysis.

Rip-off Failure Mechanism of Reinforced Concrete Beams Strengthened with CFRP Plate (CFRP로 성능향상된 철근콘크리트 보의 Rip-off 파괴메커니즘 고찰)

  • Sim Jong-Sung;Moon Do-Young;Park Cheol-Woo;Park Sung-Jae;Choi Kwang-Min
    • Journal of the Korea Concrete Institute
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    • v.17 no.6 s.90
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    • pp.993-1000
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    • 2005
  • Various types of FRP materials have been applied for structural strengthening of RC beams in various forms. When CFRP plates are used, a premature failure used to occur before enough strengthening effect appears. This is primarily due to the rip-off of CFRP Plate attached on RC beams. Despite of numerous studies on the rip-off failure of externally strengthened RC beams, its failure mechanism is not definitely clarified yet. Investigations from literatures have shown that the rip-off failure is dependant on the vertical and shear stresses at the level of main reinforcements in RC beams. This study suggests an analytical model to Investigate the rip-off failure load based on the stress states at the level of main reinforcements. The proposed model is relatively simple and produces very comparable results to the test data. It is believed that the proposed model can be successfully used to provide more information on the rip-off failure mechanisms and its prevention.

Development of Analytical Model to Predict the Inelastic Moment Capacity of Reinforced Concrete and Masonry Shear Wall (전단벽 구조물의 모멘트 저항능력에 관한 비탄성 해석모델개발)

  • 홍원기;이호범;변근주
    • Magazine of the Korea Concrete Institute
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    • v.5 no.4
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    • pp.123-134
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    • 1993
  • A rapid progress has been made over last decade in the state-of-the-art earthquake structura1 engineering towards a better understanding of both the earthqauke ground motion and structural response. These efforts seek to ensure that there will be no serious injury or loss of life in the event of earthquake, and that structures can be built at minimum cost. The design of structures in general, concrete structures in particular, to resist strong ground input motions is not a simple matter, and analytical models for such structures must be developed from a design perspective that accounts for the complexities of the structural responses. The primary obj ective of earthquake structural engineering research is to ensure the safety of structures by understanding and improving a design methodology. Ideally, this would require the development of an analytical model related to a design methodology that ensures a ductile performance. For the accurate assessment of the adequacy of analytically developed model, experiments conducted to study the inplane inelastic cyclic behavior of structures should verify the analytical approach. The fundamental goal of this paper is to present and demonstrate experimentally verified analytical methods that provide the adequate degree of safety and confidience in the behavior of reinforced concrete structural components. This study further attempts to extend the developed modeling techruque for use by practicing structural engineers for both the analysis and design.Plication of the relaxed diaphragm through left thoracotomy was done and result was excellent as seen on Fig. 5. Cause of eventration of the left hemidiaphragm was due to paralysis of the left phrenic nerve which was tested during thoracotomy.

The Study on the Rheological Properties of Polymer Matrix for MIF (Molded-In Foaming) Process (MIF (Molded-In Foaming) 공정에 적합한 고분자 기재의 유변학적 특성 연구)

  • Kim, Mingeun;Song, Hyeong Yong;Kim, Dong Gun;Kim, Hyo Jun;Park, Geon Uk;Yu, Jae Keun;Hyun, Kyu
    • Elastomers and Composites
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    • v.49 no.4
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    • pp.323-329
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    • 2014
  • In order to select polymer matrix for MIF (Molded-In Foaming) process, in this study, we investigated rheological properties of commercial polymers, SBC (Styrene-Butadiene Copolymers, K-resin KK38) and SBS (Styrene- Butadiene-Styrene, KTR 101 and KTR 301). In time sweep test, the rheological properties ($G^{\prime}$, $G^{{\prime}{\prime}}$, ${\eta}^*$) of SBS at 155 and $170^{\circ}C$ display almost constant value as a function of time from 0 s to 1800 s. On contrast, the rheological properties of SBS at 185 and $200^{\circ}C$ exponentially increase as a function of time. It could be due to gelation of SBS at high temperature conditions. These increment of rheological properties are not observed in SBC. From LAOS (large amplitude oscillatory shear) test, the nonlinear rheological properties of SBS at 155 and $200^{\circ}C$ after 1800 s are compared. The nonlinear rheological properties at $155^{\circ}C$ show simple strain thinning behavior such as linear homopolymer, however, the nonlinear rheological properties at $200^{\circ}C$ show 2 times strain thinning behavior (Payne effect). It well match with the gelation of SBS at $200^{\circ}C$. From rheological studies, it is confirmed that the proper polymer matrix for MIF process (low rheological properties at initial time and high rheological properties after process) is SBS KTR 301.

The Composite Behaviors of Fabricated Concrete Deck Simple Bridges (바닥판조립식 단순보교량의 합성거동에 관한 연구)

  • 구민세;장성수;윤우현
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.12 no.4
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    • pp.525-535
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    • 1999
  • In this study, a new method of fabricated concrete deck bridge construction is proposed. This paper details the method in which concrete multi-girders and fabricated concrete decks are rested on the upper flange of the girder and the female to female type sheat-key is formed to connect girder and deck. The finite element analysis is performed to verify the accuracy of the structural behaviors of the fabricated concrete deck bridge by comparing with experimental results. The first task performed is the analysis of the equilibrium of the member force occurring between the deck and the girder. After verifying equilibrium of the member force determined by the finite element analysis, this process is applied to the analysis of maximum member force as the position of design load. This task is utilized to determine the safety of each member according to the same scale finite element model. The final process in this study is to compare the deflection of girders used in experiment with that of the same scale finite element model to verify the strength of fabricated cincrete deck bridge. By this comparison, it is shown that the behavior of the fabricated concrete deck bridge is almost same as the finite element analysis. The second task is to analyze the load distribution effect according to the number of diaphragms and the composite effect due to the cinnection of the deck and girder by the finite element analysis. From the results of second task, it is found that the load distribution effect is not related to the number of diaphragms in case of the central loading, but is related to the number of diaphragms for eccentric loading. Analysis of the load distribution indicates that the effective number of diaphragm is three. It is also shown that the maximum deflection is decreased to almost one half due to the composite action of the deck and girder.

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Gold Mineralization of the Youngbogari Mine, Youngdong Area (영동지역 영보가리 광산의 금광화 작용)

  • Heo, Chul-Ho;Chi, Se-Jung
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.2 s.52
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    • pp.115-124
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    • 2007
  • Electrum-sulfide mineralization of the Youngbogari mine area occurred in two stages of massive quartz veins that fill the fractures along the fault/shear zones in the Precambrian gneiss. Ore mineralogy is simple, consisting of arsenopyrite $(31.4{\sim}33.4atom.%As)$, pyrite, sphalerite $(4.1{\sim}17.6mole%FeS)$, galena, chalcopyrite, argentite, and electrum. Electrum $(60.3{\sim}87.6atom.%Ag)$ is associated with galena, chalcopyrite and late sphalerite infilling the fractures in quartz and sulfides. Fluid inclusion data show that ore mineralization was formed from $H_2O-CO_2-CH_4-NaCl$ fluids $(X_{CO2+CH4}=0.0\;to\;0.2)$ with low salinities (0 to 10wt.% eq. NaCl) at temperatures between $200^{\circ}\;and\;370^{\circ}C$. Gold-silver mineralization occurred later than the base-metal sulfide deposition, at temperatures near $250^{\circ}C$ and was probably a result of cooling and decreasing sulfur fugacity caused by sulfide precipitation and/or $H_2S$ loss through fluid unmixing.