• Title/Summary/Keyword: Silver ions

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Antimicrobial Effect of Metal tons Substitution to HAp, Zeolite (HAp, Zeolite에 여러 금속 Ion 치환시 나타나는 항균효과)

  • Kim, Yun-Jong;Kim, Taek-Nam;Kim, Sang-Bae;Jo, Seong-Baek;Jo, Geon-Jun;Lee, Tae-Hyeong
    • Korean Journal of Materials Research
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    • v.11 no.2
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    • pp.120-125
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    • 2001
  • Generally, hydroxyapatite(HAp), zeolite, carbon molecular sieve , activated carbon and alumina are used as heavy metal ions adsorption materials. Among those adsorption materials, HAp which has good positive ion-exchange ability with metal ion, and zeolite are utilized in wastewater treatment. Most of water pollutions are caused by hazardous heavy metals ions as well as bacteria in waste water. In this study, a adsorption materials (HAP and zeolite) are ion-exchanged with a well known antimicrobial metal ions, such as $Ag^+,\;Cu^{2+},\;and\;Zn^{2+}$, in order to give a adsorption of heavy metal ions and a killing effects of bacteria. The antimicrobial effects of adsorption materials are observed using by E. Coli. The results show that there is a complete antimicrobial effect in the adsorption materials with $Ag^+$ at the concentration of $1{\times}10^{-4}$cell/$m\ell$ of E. Coli until 24 hours. However, there is not good antimicrobial effects in the adsorption materials with $Cu^{2+},\;and\;Zn^{2+}$ substitution. Feng et. al. showed the denaturation effects of silver ions which induces the condensed DNA molecules and losing their replication abilities.

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Effect of Pulsed Nd:YAG Laser Energy on Crystallization in $Li_2O - Al_2O_3 - SiO_2$ Glass

  • Lee, Yong--Su;Kang, Won--Ho
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2001.07a
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    • pp.104-109
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    • 2001
  • A 355 nm (3.5 eV) neodymium:yttrium aluminum gamet laser, produced by a harmonic generator, was used to create silver metallic particles as seeds for nucleation in photosensitive glass containing Ag+ and Ce3+ ions. The pulse width and frequency of the laser were 8 ns and 10 Hz, respectively. Heat treatment was conducted at 570 C for 1 h, following laser irradiation, to produce crystalline growth, after which a LiAlSi3O8 crystal phase appeared in the laser-irradiated Li2O A1203 SiO2 glass. For the Present study, we compared the effect of laser-induced crystallization on glass crystallization with that of spontaneous crystallization by heat treatment.

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Influence of Silver Ions in HA Film on Morphology of Macrophages

  • Feng, Q.L.;Kim, T.N.;Kim, J.W.
    • Journal of the Korean Vacuum Society
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    • v.7 no.s1
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    • pp.50-56
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    • 1998
  • Ion beam assisted deposition (IBAD) was successfully used to produce a dense and ultra-adherent Hydroxyapatite (HA) film on titanium alloy and alumina. Recently it is also proved that the HA coatings on alumina substrate treated with 20 ppm $AgNO_3$ had the structure of $(Ag, Ca)_10(PO_4)6(OH)_2$, which exhibited excellent antimicrobial effects. The present paper aims to morphlogically characterize the adhesion of macrophages on newly developed Ag-HA coated alumina and Ti6A14V substrates and to evaluate the biocompatibility of the coatings in vitro. It can be found that the cell number on alumina of the concentration of $AgNO_3$ in the treatment, the cell number on Ag-HA coatings decreased. Up to 20 ppm $AgNO_3$ by Ag-treatment, the morphological development of the cells on Ag-HA coating was similar to that of the cells on HA coating, suggesting the biotolerance of the Ag-HA coatings.

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The study of Ag etching effect by adding compound on the lead frame process (Lead frame 공정 중 화합물에 따른 Ag 에칭효과)

  • 이경수;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.859-862
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    • 2001
  • This study describes a selective Ag etching solution for use with pattern on the surface of copper. This etching solution uses potassium iodide and potassium sulfate as the ligand that coordinates to the metal ions and ferricyanide as the oxidant. The etching rate was depended on the concentration of co-ligands and time. But the etching rate wasn't depended on the pH(2∼6), and oxidant(K$_3$Fe(CN)$\_$6/). Complete etching of silver can be achieved rapidly within 90sec for 4.46${\mu}$m thick metal films when aqueous solutions containing K$_3$Fe(CN)$\_$6/, K$_2$S$_2$O$\_$8/ and KI was used. This etching solution was characteristic of anisotropic etching.

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Preparation and characterization of expanded graphite/Ag nanoparticle composites for the improvement of thermal diffusion

  • Hong, Seok Hwan;Lee, Won Gyu
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.410-415
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    • 2018
  • Expanded graphite (EG)/Ag nanoparticle composites were synthesized by the chemical reduction of Ag ions, followed by the addition of expanded graphite into an Ag reducing solution. The prepared composites showed uniform dispersion of Ag nanoparticles on the surface of expanded graphite and exhibited relatively higher thermal conductivities than those of pure expanded graphite. In the case of 10% Ag content in the composite, the thermal conductivity in the thickness direction was 78% higher than the pure expanded graphite. We suggest that EG/Ag nanoparticle composites are a strong candidate for advanced heat spreading material.

The Coloring Effect of Glasses by Ag+ Ion Exchange (Ag+ 이온교환에 따른 유리의 착색 효과)

  • 이용근;이동인;윤종석;이희수
    • Journal of the Korean Ceramic Society
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    • v.26 no.4
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    • pp.499-504
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    • 1989
  • Coloring effect, mechanical properties resulting from silver ions exchange of glasses immersed into the mixed molten salt of KNO3 and AgNO3 were investigated in this study. Ion exchange coloring of glasses made it possible to obtain glasses with a range from yellow to yellowish-brown, and spectral transmittance was investigated. The amount of ion exchange and peneration depth increased with treatment temperature and time. The activation energy decreased with mole fraction of AgNO3. It can be seem that the bending strength of ion exchanged glasses were 3~4 times higher than the parent glass and Ag+ colloids prevented from increasing surface microhardness.

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Potentiometric Determination of Copper with 2,5-Dimercapto-1,3,4-thiadiazole (2,5-Dimercapto-1,3,4-thiadiazole에 의한 구리의 전위차 적정 정량)

  • Young Gu Ha
    • Journal of the Korean Chemical Society
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    • v.20 no.4
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    • pp.277-279
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    • 1976
  • A potentiometric titration method has been developed for the titration of copper with 2,5-dimercapo-1,3,4-thiadizole in aqueous solution using a silver electrode as an indicator electrode vs. the standard calomel electrode as a reference electrode. The 2,5-dimercapto-1,3,4-thiadiazole is very sensitive reagent for copper, which has been found to be highly selective for potentiometric determination of copper. Direct titration of trace amount of copper (0.02${\sim}$0.1 mg) is possible in the presence of a number of foreign ions in aqueous solution containing potassium hydrogen phthalate and sodium fluoride as masking agent under atmosphere.

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Fabrication of Low Temperature Cofired Ceramic (LTCC) Chip Couplers for High Frequencies ; II. Effect of Sintering Process on Ag Diffusion (고주파용 저온 동시소성 세라믹(LTCC)칩 커플러 제조: II. Ag 이온 확산에 대한 소결공정의 영향)

  • 이선우;김경훈;심광보;구기덕
    • Journal of the Korean Ceramic Society
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    • v.36 no.5
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    • pp.490-496
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    • 1999
  • The sintering behavior of LTCC (low temperature cofired ceramics) chip couplers was investigated in relation with Ag diffusion at the interface of glass ceramic substrate-Ag electrode. Sintering temperature was in the range of 825$^{\circ}C$-975$^{\circ}C$. The commercial green sheet and silver electrode were used. Below 875$^{\circ}C$ the diffusion of the Ag ion into the substrate and the penetration of glassy phases into the electrode occurred due to an increase of fluidity. Thus the lectrode line was severely deformed and damaged. At 975$^{\circ}C$ the transformation of crystalline phases into glassy phases and the melting of the Ag electrode resulted in the diffusion of the considerable amount of Ag ions.

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The Solid-electrolyte Characteristics of Ag-doped Germanium Selenide for Manufacturing of Programmable Metallization Cell (Programmable Metallization Cell 제작을 위한 Ag-doped Germanium Selenide의 고체전해질 특성)

  • Nam, Ki-Hyun;Chung, Hong-Bay
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.5
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    • pp.382-385
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    • 2009
  • In this study, we studied switching characteristics of germanium selenide(Ge-Se)/silver(Ag) contact formed by photodoping for use in programmable metallization cell devices. We have been investigated the switching characteristics of Ag-doped chalcogenide thin films. Changed resistance range by direction of applied voltage is about $1\;M{\Omega}$ $\sim$ hundreds of $\Omega$. The cause of these resistance change can be thought the same phenomenon such as resistance variation of PMC-RAM. The results imply that the separated Ag-ions react the atoms or defects in chalcogenide thin films.

Nanoparticles Modified With Cationic Thiol Surfactant as Efficient Inhibitors for the Corrosion of Carbon Steel

  • Azzam, Eid M.S.;Sami, Radwa M.;Alenezi, Khalaf M.;El Moll, Hani;Haque, A.
    • Journal of Electrochemical Science and Technology
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    • v.12 no.3
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    • pp.308-316
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    • 2021
  • In this work, we report synthesis, characterization and corrosion inhibition properties of cationic thiol surfactant-capped silver (SC-Ag-NPs) and gold (SC-Au-NPs) nanoparticles. SC-Ag-NPs and SC-Au-NPs were characterized using regular techniques include TEM. Corrosion study was carried out using carbon steel (CS) in 3.5% NaCl aqueous solution and characterized using multiple electrochemical techniques. Our results suggest that the paint containing SC-Ag-NPs and SC-Au-NPs endow efficient corrosion protection to the CS. Especially, SC-Au-NPs based paint form a stronger barrier between the metal and the corrosive ions, leading to better inhibition properties.