• Title/Summary/Keyword: Silver halide

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Studies on the Homogeneous Precipitiation of Silver Halide (Silver Halide의 均一沈澱法에 關한 硏究)

  • Park, Doo-Won;Oh, Sang O.
    • Journal of the Korean Chemical Society
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    • v.6 no.2
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    • pp.122-124
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    • 1962
  • The silver halide precipitate tends to separate in curdy form of flocculated colloid when it is precipitated by direct mixing of reactant solutions. This type of precipitate has a great tendency to adsorb or occlude foreign ions in the solution.When silver halide in precipitated from homogeneous solution using the slow hydrolysis of Alkyl halide or Ally halide, the precipitate becomes dense, filterable and uniform in particle size which is very advantageous in gravimetric analysis.We found that silver halide precipitates obtained from homogeneous solution with hydrogen halide formed by the hydrolysis of alkyl halide do not give the color change with fluorescein as adsorption indicater, while silver halide precipitates obtained by direct mixing method give sharply pink color which appear to be uniformly distributed through the solution in silver ion excess.

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Fabrication and characterization of silver-halide sensitized gelatin diffraction grating derived from Slavich PFG-01 holographic plates (Slavich PFG-01을 이용한 은염 홀로그래피 회절 격자의 제작 및 특성)

  • 임춘우;박성진;석성수;최대욱;오철한
    • Proceedings of the Optical Society of Korea Conference
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    • 2000.02a
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    • pp.292-293
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    • 2000
  • Silver-halide sensitized gelatin(SHSG)의 처리 과정에서 silver-halide입자가 감광유제(emulsion)로부터 제거되고, 노출영역과 비노출영역 사이의 gelatin경화정도로 인한 굴절률 변조로 홀로그램 이미지를 기록한다. 일반적으로 널리 사용되는 홀로그램 감광물질로는 silver-halide, dichromated gelatin, photoresist, photochrome 등이 있는데, 이중 silver-halide는 다른 감광물질과 비교하여 고해상도와 큰 감광대역폭, 높은 S/N비, 취급의 용이성과 경제적 이점, 균일한 제품으로 상용화될 수 있다는 점에서 가장 편리하게 사용되고 있는 기록 매질이다. (중략)

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Adsorption of 2-Cyanonaphthalene on Silver Sol Investigated by Raman Spectroscopy$^\dag$

  • Park, Seong Hyeon;Lee, Eun A;Jang, Du Jeon;Kim, Myeong Su;Kim, Gwan
    • Bulletin of the Korean Chemical Society
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    • v.16 no.2
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    • pp.130-134
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    • 1995
  • Surface-enhanced Raman (SER) scattering of 2-cyanonaphthalene (2-CN) has been investigated in silver sol. Addition of halide ions was needed to obtain authentic SER spectra of the molecule. The SER spectra thus obtained exhibited a slight but noticeable dependence on the kind of halide ions used. This halide-dependent spectral variation was attributed to the orientational change of molecule on silver sol surface. A possible mechanism for such an orientational change is proposed in terms of the competitive adsorption of 2-CN with halide ions on the so-called halide-specific sites.

Image Enhancement Algorithm in Imaging Systems for Electronic Photography (전자사진용 화상시스템의 화상개선 알고리즘)

  • 박용주;김지홍
    • Journal of the Korean Graphic Arts Communication Society
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    • v.20 no.1
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    • pp.133-145
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    • 2002
  • A study on electronic imaging system with silver halide photography emulation by a parametric approach will be introduced. The study contains the comparison analysis between silver halide imaging process and electronic imaging process, the characterization of the detailed process in those imaging chains, such as exposure, developing, photographic print and the other photographic and digital process. We investigated the characteristic curve between optical density and the amount of exposure in silver halide and digital photography systems. Under wide range of exposure condition, several sensitometric parameters were obtained via studio and outdoor photographic experiments with conventional photography and a digital camera. whose experimental results will be shown. Finally, the comparison between electronic imaging and conventional photography via silver halide photography emulation and modeling the silver halide process wi13 be discussed.

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A Study on the Preparation of the Silver Selenide Electrode and Its Properties (Silver Selenide 전극의 제조 및 그 특성에 관한 연구)

  • Gwon-Shik Ihn;Tae-Won Min;Soo-Hyung Lee
    • Journal of the Korean Chemical Society
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    • v.20 no.4
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    • pp.280-289
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    • 1976
  • The silver selenide electrode has been prepared and its properties as an indicating electrode for silver ion have been investigated. Epoxy resin was used as a filler of silver selenide electrode. Silver metal plate was directly connected with the membrane of the electrode and the silver paste was used as its binder. The sintered electrode was more sensitive and stable than the pressed electrode, and the silver selenide electrode more sensitive than the silver sulfide electrode to silver ion. The linear relationship between the electrode potential and logarithmic concentration of silver ion has been observed down to 10-6 M for the electrode. Several heavy metal ions except mercuric ion did not interfere this linearity, but halide, cyanide, and thiocyanate ions did intensively interfere owing to the formation of silver compounds and complexes. This electrode has been applied to the potentiometric titration for determining halide ion. It is concluded that interferences from ,$CN^-, SCN^-, S^-, I^-, Br^-, Cl^- and Hg^{2+}$ ions are detrimental to the practical use of the electrodes for measuring pAg.

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Development of Noncontact Temperature Sensor Using Silver Halide Optical Fiber for Medical Usages (Silver Halide 광섬유를 이용한 의료용 비접촉식 온도 센서 개발)

  • Yoo, Wook-Jae;Cho, Dong-Hyun;Jang, Kyoung-Won;Chung, Soon-Cheol;Tack, Gye-Rae;Lee, Bong-Soo
    • Journal of Biomedical Engineering Research
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    • v.27 no.6
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    • pp.337-342
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    • 2006
  • We have developed a noncontact temperature sensor using a silver halide optical fiber. The infrared collimator and focus head are connected both ends of a silver halide optical fiber with SMA connectors and used to collimate radiations of a heat source and to focus them to infrared sensors such as a pyroelectric sensor and a thermopile sensor, respectively. The relation ships between the temperatures of a heat source and the output signals of the infrared sensors are determined to measure the surface temperature of a heat source. The measurable temperature range is from 25 to $60^{\circ}C$. It is expected that a noncontact temperature sensor using a silver halide optical fiber can be developed for medical usages such as temperature monitoring during hyperthermia, cryosurgery, laser surgery and diagnostic procedure based on the results of this study.

PHOTOSENSITIVITY OF HETEROJUNCTION TYPE GRAINS IN CUBIC SILVER HALIDE MICROCRYSTALS

  • Park, In Yeong
    • Journal of Photoscience
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    • v.3 no.3
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    • pp.159-161
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    • 1996
  • Photosensitivity of silver halide emulsion depends on the properties of the microcrystals. Size, shape, grain distribution and chemical composition as well as the inner structure or the topography of the latent image specks affect on the optical properties and play an important role in the photographic process. In the present paper, a study on the sensitization of emulsion containing AgBrClI core/shell grains showed that for the given size, shape, halide content and crystal habit, under the optimal conditions the photosensitivity of the heterojunction type grains are different from that of the common regular grains. The optimal photosensitivity was obtained at the iodide content of 2.0 mo1%.

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Diffraction Efficiency Analysis of Silver Halide Film for Color Holography Recording

  • Park, Sung Chul;Kim, Sang Il;Son, Kwang Chul;Kwon, Soon Chul;Lee, Seung Hyun
    • International Journal of Internet, Broadcasting and Communication
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    • v.7 no.2
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    • pp.16-27
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    • 2015
  • Holography technology which was developed by Dennis Gabor (1900~1979) in 1948 is a technology to record wave planes of actual 3D objects. It is known as the only technology which can express 3D information most perfectly close to human-friendly. Holography technology is widely used in advertisement, architecture and arts as well as science technology areas. Especially, digital holographic print which is an applied area is greatly used in military map, architecture map and cultural asset restoration by printing and reproducing 3D information. Holography is realized by recording and reproducing the amplitude and phase information on high resolution film using coherent light like laser. Recording materials for digital holographic printer are silver halide, photoresist and photopolymer. Because the materials have different diffraction efficiency according to film characteristics of each manufacturer, appropriate guide lines should be suggested through efficiency analysis of each film. This paper suggests appropriate guide lines through the diffraction efficiency measurement of silver halide which is a holographic printer recording medium. And the objective of this study is to suggest appropriate guide lines through diffraction efficiency analysis of Ultimate 08-C and PFG-03C which are commercially used. The experiment was prepared by self-diffraction efficiency system which measures the strength with the defector by penetrating RGB recording medium and concentrating diffracted beams through collimating lens. The experiment showed Geola's PFG-03C which is a silver halide for full color has price/performance advantage in optical hologram recording, but recording angles and reproduction angles are irregular for digital holographic printer recording. Ultimate's Ultimate08-C for full color shows its diffraction efficiency is relatively stable and high according to recording angles and laser wavelength.

Effect of Continuous Oil Phase on Preparation of Silver Halide Nanoparticles using AOT-Based W/O Microemulsions (AOT W/O 마이크로에멀젼을 이용한 할로겐화은 나노입자 제조에서 연속상 오일의 영향)

  • Jung, KilYong;Lim, JongChoo
    • Korean Chemical Engineering Research
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    • v.45 no.4
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    • pp.364-371
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    • 2007
  • Effects of continuous oil phase on silver halide nanoparticles were investigated where nanoparticles were prepared using two different types of water-in-oil(W/O) microemulsions containing silver and halide, respectively. Phase behavior experiments for ternary systems containing AOT surfactant, hydrocarbon oil and aqueous solution of an inorganic salt showed that the region of one phase W/O microemulsion was found to be broadened with an increase in the alkyl chain length of a hydrocarbon mainly due to an increase in hydrophilic nature of a surfactant. With the information of phase behavior experiments, silver halide nanoparticles were prepared using different AOT-based microemulsion systems and photomicrographs obtained by transmission electron microscopy indicated that about 10 nm size particles of relatively spherical shape were obtained. It has been found that an increase in alkyl chain length of a hydrocarbon results in a decrease in particle size because of higher intermicellar exchange rate among microemulsion drops. The average particle size was also found to increase with the inorganic salt composition of initial aqueous solution.

Study on PVC Mixed Silver Iodide Membrane Electrode (PVC 를 섞은 요오드화은 막전극에 관한 연구)

  • Kwon Young-Soon;Kim Jung-Hee;Park Kee-Chae
    • Journal of the Korean Chemical Society
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    • v.20 no.6
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    • pp.486-493
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    • 1976
  • The PVC mixed silver iodide pellet was prepared by means of the Infrared Pellet presser and the pellet was used as an indicating membrane electrode, to measure the potentials for various silver ion activities, ranging from $10^{-1}$ to $10^{-6}$ M. The potential responses to silver ion activities were linear and the slope was much close to Nernstian relation as compared with that of the pure silver iodide pellet membrane electrode and the PVC coated silver iodide pellet membrane electrode. The mechanical property and chemical durability of this electrode were found much better than the others. This electrode did not show significant response to the other except silver ion, but had good response to halide ions, i.e., iodide, chloride, bromide and cyanide ions, in the concentration range $10^{-1}$ to $10^{-6}$ M. This electrode could be used as an indicating electrode in potentiometric titrations of single halide ion and also halide mixture with standard solution of silver nitrate.

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