• Title/Summary/Keyword: Silver complex

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A Study of the Fabrics Used for the Official Hats in Baekje Dynasty (백제 관모에 사용된 직물 연구)

  • Park, Yoon-Mee
    • Journal of the Korean Society of Costume
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    • v.59 no.3
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    • pp.82-95
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    • 2009
  • The kind and the use of the fabrics for crown manufacture in the Baekje period has been studied by characterizing the imprinted fabrics on the crowns and the diadem ornaments from the old tomb. The contact region with the skin inside of the crown and the region between the bark of white birch and the gilt bronze openwork plates contained fabrics. The fabrics used in the gilt-bronze crown were all plain weave silk except that of Yongwonri tomb where loosely woven thin tabby was used. There have been 4-types of iron framed diadem of the Baekje, which comprise the inverted triangle-shaped diadem only with iron frame, the diadem with gold plate ornament in the iron frame, the diadem decorated with mica plate and gold plate, and the diadem with silver ornament in the iron frame. The fabrics used in the triangle shaped iron frame diadem include plain weave silk, irregular plain woven silk, thin tabby, complex silk gauze, twill weave on plain ground, and warp-faced compound weave. The iron frames were wrapped with the fabrics from one layer up to three layers, and the iron diadem was covered with one later of loosely woven textile such as irregular plain woven silk, thin tabby, and complex silk gauze. But in case of decorating the iron diadem with gold Plate ornaments, multiple layers of fabric were used to sustain the weight of the ornaments. The fabrics in the iron diadem frame were sewed with running stitch, overedge stitch or hemming stitch, diagonal hemming stitch, half back stitch), and overcast stitch.

Indoor Air Quality in Various Type of Public Facilities at Honam Province (호남지역의 다중이용시설별 실내공기질 실태 조사)

  • Seo, Byeong-Ryang;Jeong, Man-Ho;Jeon, Jun-Min
    • Journal of Environmental Health Sciences
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    • v.32 no.5 s.92
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    • pp.387-397
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    • 2006
  • This study was performed to investigate the characteristics of indoor air quality(IAQ) in 91 public facilities from September 2004 to March 2005 in the Honam province(Chonnam, Gwangju). The measured air pollutants are $PM_{10}$, formaldehyde(HCHO), CO, $CO_{2}$ and total suspended bacteria(TSB), the maintenance standard materials of IAQ management law established by ministry of environment in Korea(MOE). We also surveyed establishment and operation of ventilation equipment. It was measured $1.2m{\sim}1.5m$ on the floor between 8 o'clock AM and 7 o'clock PM. As the result, $PM_{10}$ and CO was showed the highest concentration, $188.89{\mu}g/m^{3}$, 8.67 ppm, at the indoor parking. The concentration of HCHO was the highest in large store and steamer room. The concentration was respectively $118.70{\mu}g/m^{3}\;and\;113.21{\mu}g/m^{3}$. The concentration of $CO_{2}$ was the highest at the reading room of the library on the condition of natural ventilation. The concentration of $CO_{2}$ was 1,816 ppm and higher than the IAQ standards established by MOE. The TSB was just measured in the hospital and silver town. It was the highest at the admission room of hospital. The concentration of TSB was $766CFU/m^{3}$. The public facilities of this study were not exceed each maintenance standards except $CO_{2}$ but it was surveyed that the management will be needed about some air pollutant according to target facilities.

Organopalladium(II) Complexes as Ionophores for Thiocyanate Ion-Selective Electrodes

  • Kim, Dong-Wan;Lee, So-Hyun;Kim, Jung-Hwan;Kim, Jin-Eun;Park, Jong-Keun;Kim, Jae-Sang
    • Bulletin of the Korean Chemical Society
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    • v.30 no.10
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    • pp.2303-2308
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    • 2009
  • A thiocyanate poly(vinyl chloride) (PVC) membrane electrode based on [1,2-bis(diphenylphosphino)ethane]dihalopalladium( II), [(dppe)$PdX_2$, X = Cl ($L^1$), X = I ($L^2$)] as active sensor has been developed. The diiodopalladium complex, [(dppe)$PdI_2](L^2$) displays an anti-Hofmeister selectivity sequence: $SCN^-\;>\;I^-\;>\;{ClO_4}^-\;>\;Sal^-\;>\;Br^-\;>\;{NO_2}^-\;>\;{HPO_4}^-\;>\;AcO^-\;>\;{NO_3}^-\;>\;{H_2PO_4}^-\;>\;{CO_3}^{2-}$. The electrode exhibits a Nernstian response (-59.8 mV/decade) over a wide linear concentration range of thiocyanate ($(1.0\;{\times}\;10^{-1}\;to\;5.0\;{\times}\;10^{-6}$ M), low detection limit ($(1.1\;{\times}\;10^{-6}$ M), fast response $(t_{90%}$ = 24 s), and applicability over a wide pH range (3.5∼11). Addition of anionic sites, potassium tetrakis[p-chlorophenyl] borate (KTpClPB) is shown to improve potentiometric anion selectivity, suggesting that the palladium complex may operate as a partially charged carrier-type ionophore within the polymer membrane phase. The reaction mechanism is discussed with respect to UV-Vis and IR spectroscopy. Application of the electrode to the potentiometric titration of thiocyanate ion with silver nitrate is reported.

The Petrochemical and Structural Study on the Charyong Batholith and its Associated Metallic Deposits (차령화강암(車嶺花崗岩) 저반(底盤)과 이에 관련된 금속광상(金屬鑛床)의 암석학적(岩石學的) 및 지질구조적(地質構造的) 연구(硏究))

  • Kim, Ok Joon
    • Economic and Environmental Geology
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    • v.10 no.3
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    • pp.107-117
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    • 1977
  • The Charyong batholith extends northeasterly from the west coast to the west of Wonju in the central parts of Korean Penninsula. The batholith is separated by the metamorphic complex into the northern and the southern granites. and is believed to intrude during the Daebo orogeny of early Jurassic to early Cretaceous age. It constitutes a sort of anticlinorium and the metamorphic complex can be regarded as a huge roof pendant. The modal analysis indicates that the Charyong batholith belongs to a series of adamellite-granodiorte-to-nalite. The oxidation property happened during a magmatic segregation reveals that the batholith shows in general orogenic assimilation trend. The granites of early to middle Jurassic age show orogenic assimilation trend, whereas those of late Jurassic to early Cretaceous age post orogenic noassimilation trend. The fracture system of the whole region is two folds: the fractures having attitute of $N25{\sim}40^{\circ}E$ and $70^{\circ}SE$ are regarded as tension fractures, and those of NS, and 50E to vertical and $N50^{\circ}E$ and $80^{\circ}E$ to vertical as shear fractures. All these facts suggest definitely that the Charyong batholith is the syntectonic intrusives during the Daebo orogeny. The mineral deposits in the area studied are gold-silver deposits in majority which was named by O,J.Kim(1970) as the Chonan metallogenic province. They are sulfides baring quartz veins which were emplaced along the tension and shear fractures originated by the Daebo orogeny.

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Feasibility Study on Silver Nanoparticle Application to a Radioisotope Carrier (은나노입자의 방사성 동위원소 운반체 적용 유효성 검증 연구)

  • Jang, Beom-Su;Lee, Joo-Sang;Park, Hae-Jun;Kim, Hwa-Jung;Park, Sang Hyun
    • Journal of Radiation Industry
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    • v.5 no.3
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    • pp.197-202
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    • 2011
  • In this study, an Ag-polyaniline-silica (Ag-PANI-silica) nanoparticle was evaluated as a radioisotope carrier. An Ag-PANI-silica nanoparticle was incubated in the $^{125}I$ solution for a duration of 24 hr to test its radioisotope absorptivity. During the incubation, radioactivity of the nanoparticle was measured at 3, 6, 12, and 24 hr. After a 24 hr incubation, $^{125}I$-Ag-PANI-silica nanoparticle was incubated in a fresh saline for a duration of 48 hr to check its stability. Additionally, the $^{125}I$-Ag-PANI-silica nanoparticle was injected to the ICR mouse to investigate its in-vivo distribution characteristics. The $^{125}I$ absorption yield of the Ag-PANI-silica nanoparticle was higher than 95% after a 6 hr incubation period in the $^{125}I$ solution. And $^{125}I$-Ag-PANI-silica was stable for 48 hr at 80% yield at room temperature. The SPECT/CT image of a mouse that received $^{125}I$-Ag-PANI-silica complex showed that the $^{125}I$-Ag-PANI-silica complex was distributed in the lung, stomach and thyroid at 30 min post injection. From these results, the Ag-PANI-silica nanoparticle has good radio-iodine carrying property and can be applicable for the purpose of diagnosis and therapy.

The Crystal Structure of an Iondine Sorption Complex of Dehydrated Calcium and Silver Exchanged Zeolite A ($Ag^+$이온과 $Ca^{2+}$이온으로 치환한 제올라이트 A를 탈수한 후 요오드를 흡착한 결정구조)

  • Bae, Myung-Nam;Kim, Yang;Kim, Un-Sik
    • Korean Journal of Crystallography
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    • v.6 no.2
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    • pp.118-124
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    • 1995
  • The crystal structure of an iodine sorption complex of vacumm-dehydrated Ag+ and Ca2+ exchanged zeolite A(a=12.174(3)Å) has been determined at 21℃ by single-crystal X-ray diffraction techniques in the cubic space group Pm3m. The crystal was prepared by flow method for three days using exchange solution in solution in which mole ratio of AgNO3 and Ca(NO3)2 was 1:150 with total concentration of 0.05 M. The complex was prepared by dehydration at 360℃ and 2×10-6 Torr for 2 days, followed by exposure to about 14.3 Torr of iodine vaporat 80℃ for 24 hours. Full-matrix least-squares refinement converged to the final error indices of R1=0.082, R2=0.068 using 122 reflections for which I > 3σ(I). Two Ag+ ions, 1.1 Ag+ ions, and 4.45 Ca2+ ions per unit cell are located on three different three-fold axes associated with 6-ring oxygens. Two Ag+ ions per unit cell are in the large cavity, 1.399(4)Å from the (111) plane of three oxygens. Another 1.1 Ag+ ions are found at opposite sites. Six iodine molecules are sorbed per unit cell. Each I2 molecule approaches a framework oxide ion axially (O-I=3.43(2)Å, I-I=2.92Å, I-I-O;166.1(3)°), by a charge transfer complex interaction. Two Ag+ ions make a close approach to the iodine molecules (Ag-I ; 2.73(2)Å).

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Tarnish Behavior of Palladium-Indium-Silver alloy (Pd-In-Ag 합금의 변색거동에 관한 연구)

  • Kim, Hwa-Soo;Kim, Seong-Yun;Lee, Kyu-Hwan;Shin, Myung-Chul;Dzo, Man Hyung
    • Analytical Science and Technology
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    • v.11 no.2
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    • pp.125-129
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    • 1998
  • The purpose of this study was to give a quantitative analysis for assessing the tarnish resistance of alloys at the artificial saliva, 0.9% NaCI solution and Ringer's solution. In light of development in low-nobility alloys, it is important that tarnish test is standardized to analyse the tarnish properties of the compositions. There are concerns with the long term chemical stability of these alloys and the resistance to tarnish. Chemical stability is a complex problem involving alloy composition, nobility, microstructure and environment.

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Preparation and Characterization of Core/Shell-type Ag/Chitosan Nanoparticles with Antibacterial Activity

  • Lin, Yue;Jing, Wang;Kang, Pan;Xiaoming, Zhang;Zhouping, Wang;Wenshui, Xia
    • Bulletin of the Korean Chemical Society
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    • v.32 no.4
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    • pp.1277-1281
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    • 2011
  • Making use of chitosan (CS) and ethylenediaminetetraacetic acid (EDTA) as a reaction system, CS-EDTA nanoparticles were synthesized through a facile counterion complex coacervation method. $Ag^+$ could enter porous CS nanoparticles synthesized with this method, allowing Ag nanoparticles within chitosan nanoparticles were synthesized by reducing silver nitrate with chitosan. Because of the noncovalent interaction between CS and EDTA, the EDTA could be easily removed via dialysis against water, and pure core/shell-type Ag/CS nanoparticles could be obtained. The nanoparticles showed higher antibacterial activity toward E. coli than the active precursor Ag nanoparticles and CS.

A Study on the Planning of Agropolis Framework (농업혁신도시의 표준 프레임워크 도출에 관한 연구)

  • Choi, Soo-Myung;Kim, Young-Joo
    • Journal of Korean Society of Rural Planning
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    • v.11 no.4 s.29
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    • pp.17-24
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    • 2005
  • The sustainable development of local communities is faced with limitation due to poor infrastructure and lack of cooperation among stake-holders. To overcome such circumstances and thus to ensure balanced development of the local communities, the central government is driving construction of innovative cities mainly through transfer of public institutions to local cities. In this study, to contribute to the development of plans for the future agropolis' associated with the transfer of public institutions, efficient organization mechanisms of the agropolis such as basic structure and spatial allocation was examined through analyses of advanced cases(Sophia Antipolis, St. Hyacinthe Science Part Food Valley, Stoneleigh Park) of foreign countries. The analyses showed that the organization of agropolis were consisted of three main components; 1) agricultural and food industry complex conducting R&D, 2) service facilities(information, trade, consulting and advertisement) supporting agricultural and food industries and rural enterprise center in charge of a variety of events including exhibition, rural experience, education, and contest, 3) silver facilities such as hospital and town providing medical service and residence. Based on the results, inventories of facilities which are necessary in 'the future agropolis' and their spatial allocation were suggested.

Characterization of a Substance from Photobacterium damsela subsp. piscicida that Non-specifically Binds to Streptavidin

  • Jung Tae Sung;Kim D. Thompson;Adams Aelexandra;Oh Myung Joo
    • Fisheries and Aquatic Sciences
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    • v.3 no.1
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    • pp.52-63
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    • 2000
  • Non-specific reaction has been a problem in doing, especially, research and diagnosis for infectious agents. Avidin-biotin-peroxidase complex (ABC) techniques has widely been used to amplify a reaction. Photobacterium damse1a subsp. piscicdia (formerly Pasteurella piscicida) exhibited a capacity to bind with streptavidin non-specifically. The band, estimated 26 K Da in Western blotted paper, was blocked with biotin but incompletely. In an attempt to explore an involvement of the non-specific substance in attaching piscine cells, cell attachment test performed using anti- Ph. d. subsp piscicida sera raised mouse and rabbit exhibited slightly blocking effects for Mediterranean (1736) and significantly for Japanese (Sp 92144) isolate. Biotin decreased the attachment ability significantly for Sp92144 but it was not effective to 1736. Both isolates showed greatly enhanced attachment ability with poly-L-lysin. The non-specific binding substance was contained in bacterial extracellular products (ECPs). The substance was able to purified with 2-imminobiotin affinity column, the purified substance appeared to have 4 bands in silver staining, and had a carbohydrate branch. This purified substance showed cytotoxic effects selectively between 5 piscine cell lines. Moreover, it stimulated rainbow trout macrophage in terms of reduction of cytochrome cas well as yeast phagocytosis, significantly.

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