• Title/Summary/Keyword: Silver complex

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A UBET Analysis of The Warm Forming Process of Magnetron Anode (마그네트론 양극의 온간성형 공정의 UBET해석)

  • 조관형;배원병;김영호;양동열
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1995.04b
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    • pp.204-208
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    • 1995
  • Copper magnetron anode of a microwave-oven consists of an cylindrical outer-tube and various inner-vanes. The magnetron anode is produced by the complex process ; vane blanking, pipe cutting and sliver-alloy brazing of vanes. Recently, the backward extrusion process for forming vanes has been developed to avoid the complex procedures. The developed process is analyzed by using upper-bound elemental technique(UBET). In the UBET analysis, the upper-bound load, the configuration and the vane-height of final extruded product are determined by minimizing the total power consumption with respect to chosen parameters. To verify theoretical analysis, experiments have been carried out with pure plasticine billets at room temperature, using different web-thickness and number of vanes. The theoretical predictions both for forming load and vane-height are in reasonable agreement with the experimental results.

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Antimicrobial Activity Assessment of Functional Plastics which Contained Ag-Hydroxyl Apatite Agent (Ag-Hydroxyl Apatite를 담지한 기능성 플라스틱의 항균성능 평가)

  • 임윤택;최형기;안용현
    • KSBB Journal
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    • v.16 no.2
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    • pp.123-127
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    • 2001
  • For testing antimicrobial activity of functional plastics containing antimicrobial agent. We have used Escherichia. coli (ATCC 25922) and Staphylococcus. aureus (ATCC 6538P) with plastics which contained a Ag-hydroxyl apatite agent. In this paper, effect of antimicrobial test on plastics containing silver complex agent which accomplished by using test condition that Trypticase Soy Broth (TSB solution have diluted 500 times with 0.1 M phosphate buffer), pH7.2, Temp. $37\pm1^{circ}C$ and 120 rpm for 24 hr. the condition give the opportunity to better perform the antimicrobial active effect of individual functional plastics. As result. the test conditions were best effect of antimicrobial by using plastic contained minimum 0.5% with Ag-hydroxyl apatite agent.

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Gold and Silver Mineralization of the Soowang Ore Deposits in Muju, Korea (무주 수왕광상의 금-은 광화작용)

  • Park, Hee-In;Youn, Seok-Tai
    • Journal of the Korean earth science society
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    • v.25 no.6
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    • pp.484-494
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    • 2004
  • The Soowang Au-Ag deposits occur as quartz veins which filled fissures in middle Cretaceous porphyritic granite an/or gneiss of the Precambrian Sobaegsan gneiss complex. The paragenetic studies suggest that vein filling can be divided into four identifiable stages (I to IV). Stage I is the main sulfide stage, characterized by the deposition of base-metal sulfide and minor electrum. Stage II is the electrum stage, whereas stage III represents a period of the deposition of silver-bearing sulfosalts and minor electrum. Stage IV is the post ore stage. Mineralogical and fluid inclusion evidences suggest that mineralization of the Soowang deposits were deposited by the cooling of the fluids from initial high temperatures 300$^{\circ}C$ to later low temperatures 150$^{\circ}C$. The salinity of the fluids were moderate, ranging from 10.4wt.% equivalent NaCl in sphalerite to 3.1wt.% equivalent NaCl in barite. The gold-silver mineralization of the Soowang mine occurred at temperatures between 140 and 250$^{\circ}C$ from fluids with log $fs_2$ from -12 to -18 atm. A consideration of the pressure regime during ore deposition, based on the fluid inclusion evidence of boiling, suggests lithostatic pressure of less than 210 bars. This pressure condition indicates that vein system of the Soowang deposit formed at depth around 800 m below the surface at the time of gold-silver mineralization.

X-ray and Spectroscopy Studies of Mercury (II) and Silver (I) Complexes of α-Ketostabilized Phosphorus Ylides (α-케토안정화된 일리드화 인의 수은(II) 및 은(I) 착물에 대한 X-선 및 분광학적 연구)

  • Karami, K.;Buyukgungor, O.;Dalvand, H.
    • Journal of the Korean Chemical Society
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    • v.55 no.1
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    • pp.38-45
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    • 2011
  • The complexation behavior of the $\alpha$-ketostabilized phosphorus ylides $Ph_3P$=CHC(O) $C_6H_4-X$ (X=Br, Ph) towards the transition metal ions mercury (II) and Silver (I) was investigated. The mercury(II) complex {$HgX_2$ [Y]} 2 ($Y_1$=4-bromo benzoyl methylene triphenyl phosphorane; X=Cl(1), Br(2), I(3), $Y_2$=4-phenyl benzoyl methylene triphenyl phosphorane; X=Cl(4), Br(5), I(6)) have been prepared from the reaction of $Y_1$ and $Y_2$ with $HgX_2$ (X=Cl, Br, I) respectively. Silver complexes [$Ag(Y_2)_2]$ X(X=$BF_4$(7), OTf(8)) of the $\alpha$-keto-stabilized phosphorus ylides ($Y_2$) were obtained by reacting this ylide with AgX (X=$BF_4$, OTf) in $Me_2CO$. The crystal structure of complexes (1) and (4) was discussed. These reactions led to binuclear complexes C-coordination of ylide and trans-like structure of complexes $[Y_1HgCl_2]_2$. $CHCl_3$ (1) and $[Y_2HgCl_2]_2$ (4) is demonstrated by single crystal X-ray analyses. Not only all of complexes have been studied by IR, $^1H$ and $^{31}P$ NMR spectroscopy, but also complexes 1-3 have been characterized by $^{13}$CNMR.