• Title/Summary/Keyword: Silver Ion

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Chemical Leaching of Silver from Diverse Resources (다양한 자원으로부터 은의 화학적 침출)

  • Xing, Weidong;Lee, Manseung
    • Resources Recycling
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    • v.26 no.1
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    • pp.3-10
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    • 2017
  • The special properties of silver are often indispensable in the manufacture of advanced materials. Therefore, it is of importance to develop a process to recover silver which is necessary for the production of advanced materials from diverse resources. In this manuscript, the developed processes for the leaching of silver from diverse resources are reviewed. For this purpose, the advantages and disadvantages of using some inorganic acids (nitric and sulfuric acid) and their mixture with other oxidizing agents (ozone, oxygen, hydrogen peroxide and ferric ion) were investigated. Moreover, the leaching of silver with thiourea and thiosulfate was compared over those by inorganic acids in terms of environmental effect.

Kinetics of Water Vapor Adsorption by Chitosan-based Nanocomposite Films

  • Seog, Eun-Ju;Zuo, Li;Lee, Jun-Ho;Rhim, Jong-Whan
    • Food Science and Biotechnology
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    • v.17 no.2
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    • pp.330-335
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    • 2008
  • Water vapor adsorption kinetics of 3 different types of chitosan-based films, i.e., control chitosan, chitosan/montmorillionite (Na-MMT), and chitosan/silver-zeolite (Ag-Ion) nanocomposite films, were investigated at temperature range of $10-40^{\circ}C$. In all the films, water vapor is initially adsorbed rapidly and then it comes slowly to reach equilibrium condition. Reasonably good straight lines were obtained with plotting of 1/($m-m_0$) vs. l/t. It was found that water vapor adsorption kinetics of chitosan-based films was accurately described by a simple empirical model and the rate constant of the model followed temperature dependence according to Arrhenius equation. Arrhenius kinetic parameters ($E_a$ and $k_o$) for water vapor adsorption by chitosan-based films showed a kinetic compensation effect between the parameters with the isokinetic temperature of 315.52 K.

Effect of Flow Rate on the Continuous Cycling Electrolytic Treatment Process for Silver Ion Containing Wastewater (은 함유 폐수의 연속 순환 전해처리 시 유량변화가 회수 공정에 미치는 영향)

  • Chung, Won-Ju;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.23 no.5
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    • pp.577-580
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    • 2007
  • The influence of flow rate has been investigated on the treatment efficiency of continuous cycling electrolytic process employing artificial and actual photographic wastewater which containing silver ion. For artificial wastewater, the treatment efficiency of process was found to rise ca. three times when the flow rate of wastewater was increased from 3 mL/min to 15 mL/min. The process efficiency was doubled under the same condition regarding actual wastewater. The effect of flow rate on the treatment efficiency was observed to be altered according to the metal ionic form and solution composition. The coefficient of mass transfer was estimated using model equation, which verified that the raised treatment efficiency at higher flow rate was due to the increased mobility of ionic species.

Preparation and Characterization of Biopolymer-Based Nanocomposite Films: Chitosan-Based Nanocomposite Films with Antimicrobial Activity

  • Rhim, Jong-Whan
    • 한국포장학회:학술대회논문집
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    • 2006.11a
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    • pp.54-73
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    • 2006
  • Four different types of chitosan-based nanocomposite films were prepared using a solvent casting method by incorporating with four types of nanoparticles, i.e., an unmodified montmorillonite (Na-MMT), an organically modified montmorillonite (Cloisite 30B), a Nano-silver, and a Ag-zeolite (Ag-Ion). X-ray diffraction patterns of the nanocomposite films indicated that a certain degree of intercalation was formed in the nanocomposite films, with the highest intercalation in the Na-MMT-incorporated films followed by films with Cloisite 30B and Ag-Ion. SEM micrographs showed that in all the nanocomposite films, except the Nanosilver-incorporated one, nanoparticles were dispersed homogeneously throughout the chitosan polymer matrix. Consequently, mechanical and barrier properties of chitosan films were affected through intercalation of nanoparticles, i.e., tensile strength (TS) increased by 7-16%, while water vapor permeability (WVP) decreased by 25-30% depending on the nanoparticle material tested. In addition, chitosan-based nanocomposite films, especially silver-containing ones, showed a promising range of antimicrobial activity.

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THE EFFECT OF AN APPLIED BIAS UPON THE REFLECTANCE AND ADHESION OF SILVER FILMS BEING SPUTTER-DEPOSITED ON POLYESTER SUBSTRATE

  • Ri, Eui-Jae;Hoang, Tae-Su
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.257-264
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    • 1999
  • Thin reflective films are synthesized by using PVD methods with a bright metal of Al or Ag. For purposes of improving the reflectance and adhesion of such films particularly, substrate bias was applied during sputtering (namely, ion-plating) to enhance the deposition process with higher energy. And we succeeded in fabricating a quality silver film which possesses an adhesion of $85{\;}Kg/\textrm{cm}^2$ and a high reflectivity of more than 96%. Both of reflectivity and adhesion are better in case of bias sputtering as controlled than nonbias sputtering, particularly the bias of 50-100 V showed most effective. The microstructures of sample films were examined by using various equipments and the XRD spectrum in particular showed that <111> direction is the preferred growth orientation.

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Evaluation of Chloride Ion Binding Capacity of Hardened Portland Cement Paste Containing Hydrotalcite (경화된 하이드로탈사이트 혼입 포틀랜드 시멘트 페이스트의 염소이온 고정능력 평가)

  • Han, Jae-Do;Lee, Yun-Su;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.27-28
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    • 2018
  • Deterioration of reinforced concrete structures due to salt corrosion is a phenomenon that can be easily seen, and the main reason for deterioration is chloride ion. Therefore, researches are actively conducted to control chlorine ion penetration worldwide. The purpose of this study is to evaluate the chloride ion fixation capacity of Portland cement paste containing Hydrotalcite. For this purpose, cement paste containing 0%, 2.5%, and 5% of Hydrotalcite was sealed and cured for 28 days, and the cured cement paste was crushed. Chloride ion solution was prepared at a concentration of 0.5M using NaCl, and the powdered cement paste was reacted for a specific time in aqueous chloride ion solution. After the reaction, the concentration of the chloride ion aqueous solution was measured using a silver nitrate potentiometric titrator, and the reacted cement paste was analyzed using XRD and FT-IR.

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