• Title/Summary/Keyword: Silicone

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Dimensional Properties of Low Temperature Plasms and Silicone Treated Wool Fabric

  • Kim, Min-Sun;Kang, Tae-Jin
    • Fibers and Polymers
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    • v.2 no.1
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    • pp.152-156
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    • 2001
  • Three different silicone polymer systems, such as aminofunctional, epoxyfunctional, and hydrophilic epoxyfunctional silicone polymers, were applied onto plasma pretreated wool fabric to improve the dimensional properties. The results showed that the plasma pretreatment modified the cuticle surface of the wool fiber and increased the reactivity of wool fabric toward silicone polymers. Felting shrinkage of plasma and silicone treated wool fabric was decreased with different level depending on the applied polymer system. Fabric tear strength and hand were adversely affected by plasma treatment, but these properties were favorably restored on polymer application. Therefore, it has been concluded that the combination of plasma and silicone treatments can achieve the improved dimensional stability, and better performance properties of wool fabric. The surface smoothness appearances of treated fabrics were measured using a new evaluation system, which showed good correspondence with the results of KES-FB4 surface tester.

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Synthesis and Characterization of Phenyl Modified Silicone Polymer (페닐기를 도입한 실리콘 고분자의 합성 및 물성)

  • Lee, Ha-Hyoung;Lee, Hae-Joon;Kim, Jung-Hyun
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.633-638
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    • 1996
  • The phenyl modified silicone polymer, 1,1-diphenyl-1-methyl-7-hydroxydodecamethylheptasiloxysilane, was synthesized to prepare the silicone polymer with good cold-proof and heart-proof properties. From the TGA analysis in the range of $100{\sim}800^{\circ}C$, the phenyl modified silicone polymer had good thermal properties than polydimethylsiloxane. And furthermore fluidity was maintained even below $0^{\circ}C$. Also, the silicone rubber blended with the phenyl modified silicone polymer had better mechanical properties than the silicone rubber.

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The Effects of Silicone oil in Deep Fat Frying Process (튀김과정에서의 Silicone oil의 효과에 관한 연구)

  • 원미량
    • Journal of the Korean Home Economics Association
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    • v.19 no.2
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    • pp.213-221
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    • 1981
  • This theiss deals with the effects of addition of silicone oil to the polymerization and oxidation of frying oil in the practical deep fat frying process. The measurement of frying oil stability was carried out under various silicone oil content and compared with controlled frying process. In controlled frying process A.V., C.O.V., TBA, and contents of petroleumether insoluble fatty acids were increased as time was increased. It means thermal oxidized polymerization and hydrolysis of frying oil was occurred. When silicone oil was added to frying oil, it's thermal stability was better than that of the controlled oil and the degree of thermal stability was changed according to the contents of silicone oil. We obtained the highest degree of thermal stability when silicone oil was added 1ppm.

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Interfacial Breakdown Phenomena in XLPE/EPDM Laminates (XLPE/EPDM laminate의 계면절연파괴괴현상)

  • 남진호;서광석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.540-543
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    • 1999
  • In order to determine what indluences the interfacial breakdown in EPDM/XLPE laminates. We studied the interfacial breakdown phenomena at several interfacial conditions. Breakdown strength in laminates pasted with silicone oil was higher than that with silicone grease. As a function of heat treatment time in a vacuum, interfacial breakdown strength increased much in XLPE/EPDM laminates pasted with silicone grease but increased a little in that with silcone oil. FT-IR spectrum of silicone oil was similar to that is silicone grease. FT-lR spectrum of silicone oil was not changed by the heat treatment in a vacuum, but in silicone grease another peak appeared.

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Effects of Ageing Factors on Low Molecular Weight Silicone Fluids Content Fluids Content and Surface Hydrophobicity in HTV Silicone Rubber (HTV 실리콘 고무에서 열화인자에 따른 저분자량 성분과 표면 발수성의 변화)

  • 허창수;연복희;조한구
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.12 no.1
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    • pp.1-10
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    • 1999
  • In this paper, we have investigated the effects of the environmental factors on Low Molecular Weight (LMW) silicone fluid contents existing in high temperature vulcanized (HTV) silicone rubber sample, using dipping method and contact angle, current measurement. Artificial treatments such as immersion in water, elevated temperature, UV irradiation and dry band arcing under salt-fog condition are selected as the environmental factors. This results will be helpful to investigate the degradation with time and to expect a life time, because the LMW silicone content, which is important to recovery the hydrophobicity of silicone rubber surface, show different results by each environmental factors.

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The Effect of Plasma Treatment on Surface Properties and Adhesion Characteristics of semiconductive Silicone Rubber (반도전성 실리콘 고무의 표면 특성과 접착특성에 미치는 플라즈마 처리의 영향)

  • Hwang, Sun-Mook;Hong, Joo-Il;Hwang, Cheong-Ho;Huh, Chang-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.254-255
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    • 2005
  • In this work, the effects of plasma treatment on surface properties of semi conductive silicone rubber were investigated in terms of X-ray photoelectron spectroscopy(XPS). The adhesion characteristics of semiconductive-insulating interface layer of silicone rubber were studied by measuring the T-peel strengths. As a result, semiconductive silicone rubber surfaces treated with plasma discharge led to and increase in oxygen-containing functional groups, resulting in improving the degree of adhesion of the semiconductive-insulating interface layer of silicone rubber. these results are probably due to the modifications of surface functional groups or polar component of surface free energy of the semi conductive silicone rubber.

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Improvement in Interfacial Performances of Silicone Rubber by Oxygen Plasma Treatment

  • Lee, Ki-Taek;Seo, Yu-Jin;Huh, Chang-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.232-233
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    • 2005
  • The Surface of semi-conductive silicone rubber was treated by oxygen plasma to improve adhesion and electric performance in joints between insulating and semi-conductive silicone materials. Surface characterizations were assessed using contact angle measurement and Fourier transform infrared spectroscope (FTIR). Adhesion level was understood from T-peel tests between plasma treated semi-conductive and insulating material. Electrical breakdown strength was measured to understand the charge of electrical performance. From the results, the oxygen plasma treatment produces a significant increase in function group of containing oxygen which can be mainly ascribed to the creation of carbonyl groups on the silicone surface from the strength were improved. Therefore it is concluded then plasma treatment leads to decrease voids originating form poor adhesive, and the improve the adhesion in silicone interface. So we could obtain higher electrical design level of silicone material used for electrical apparatus using oxygen plasma treatment.

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Insulation rehabilitation of water tree aged cables by silicone treatment (실리콘 처리에 의한 수트리 열화케이블의 절연회복)

  • 김주용;송일근;한재홍;이동영;문재덕
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.14 no.1
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    • pp.14-21
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    • 2000
  • This paper presents the results of performance evaluation of silicone treatment technique which was developed for the insulation rehabilitation of water tree aged XLPE power cables. We treated the water tree aged 325 [$\textrm{mm}^2$] CN/CV cables with silicone, and then analyzed the degree of insulation rehabilitation as a function of time. AC breakdown test was conducted to evaluate insulation rehabilitation. The diagnosis test using relaxation current measurement and the characteristic analysis of insulation were also performed to estimate silicone treated cable. AC breakdown strength of silicone treated cable for one year was increased, resulting from the chemical reaction between silicone fluid and water. This experiment showed that the silicone treatment technique was effective for insulation rehabilitation of the water tree aged cables.

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Effect of Methyl Silicone, TBHQ and BHA/BHT on Frying and Storage Stabilities of the Vegetable Salad Oil in High Density Polyethylene Bottles (TBHQ, BHA/BHT 및 Methyl silicone이 식용유의 저장성과 고온에서의 안정성에 미치는 영향)

  • Rhee, Joon-Shick
    • Korean Journal of Food Science and Technology
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    • v.10 no.2
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    • pp.250-257
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    • 1978
  • Functional additives such as methyl silicone, TBHQ and BHA/BHT have been evaluated for their effects on storage and frying stabilities of the vegetable salad oil. All test results strongly suggest that methyl silicone improved the frying stability and TBHQ improved the storage stability. BHA/BHT improved neither storage stability, nor frying stability of the vegetable saladoil. Based on the test results, it is recommended that methyl silicone in the range of $1.0{\pm}0.5ppm$ and TBHQ in the range of 200ppm be added to the vegetable salad oil for the improvement of frying and storage stabilities.

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Adhesion Characteristics of Semiconductive and Insulating Silicone Rubber by Oxygen Plasma Treatment (산소 플라즈마 처리에 의한 반도전-절연 실리콘 고무의 접착 특성)

  • Lee Ki- Taek;Huh Chang-Su
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.2
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    • pp.153-157
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    • 2006
  • In this work, the effects of plasma treatment on surface properties of semiconductive silicone rubber were investigated in terms of X-ray photoelectron spectroscopy (XPS) and contact angles, The adhesion characteristics of semiconductive-insulating interface layer of silicone rubber were studied by measuring the T-peel strengths, The results of the chemical analysis showed that C-H bonds were broken due to plasma discharge and Silica-like bonds(SiOx, x=3${\~}$4) increased, It is thought that semiconductive silicone rubber surfaces treated with plasma discharge led to an increase in oxygen-containing functional groups, resulting in improving the degree of adhesion of the semiconductive-insulating interface layer of silicone rubber. However, the oxygen plama for 20 minute produces a damaged oxidized semiconductive silicone rubber layer, which acts as a weak layer producing a decrease in T-peel strength, These results are probably due to the modifications of surface functional groups or polar component of surface free energy of the semiconductive silicone rubber.