• Title/Summary/Keyword: Silicon solar cells

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Enhancement of Electrical Conductivity for Ag Grid using Electrical Sintering Method (정전류 전기 소결법을 이용한 Ag 전극 배선의 전도성 향상)

  • Hwang, Jun Y.;Moon, Y.J.;Lee, S.H.;Kang, K.;Kang, H.;Cho, Y.J.;Moon, S.J.
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.114.1-114.1
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    • 2011
  • Electrical sintering of the front electrode for crystalline silicon solar cells was performed applying a constant DC current to the printed lines. Conducting lines were printed on glass substrate by a drop-on-demand (DOD) inkjet printer and silver nanoparticle ink. Specific resistance and microstructure of sintered silver lines and were measured with varying DC current. To find the relation between temperature increase with changing applied current and specific resistance, temperature elevation was also calculated. Sintering process finished within a few milliseconds. Increasing applied DC current, specific resistance decreased and grain size increased after sintering. Achieved minimum specific resistance is approximately 1.7 times higher than specific resistance of the bulk silver.

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PC-1D doping profile due to the effects on the BSF back P-type silicon solar cells, research on high efficiency (PC-1D 도핑프로파일에서 BSF 후면전계효과에 따른 P타입 결정질 실리콘 고효율 태양전지에 관한 연구)

  • Park, Yongho;Kim, Bonggi;Lee, Junsin
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.59.1-59.1
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    • 2011
  • BSF 후면전계효과는 태양전지의 개방전압 증가를 결정하며 효율에 매우 중요한 요인이다. 본 연구에서는 p-type에서의 후면전계효과를 확인하기 위해 PC1D 시뮬레이션(Simulation)을 통해 p+ 영역의 표면농도와 깊이에 따른 전기적 특성을 분석 하였다. 최적효율을 찾기위해 면저항을 $30{\Omega}/{\square}$으로 고정하고 깊이와 표면 농도값을 가변하였다. 최적화 결과 표면농도값이 작아지고 깊이가 커질수록 효율이 좋아지는 경향이 나타났으며 Peak doping=$5{\times}10^{18}cm^{-3}$, Juction depth=12.52um에서 최고효율 19.14%를 얻을 수 있었다. 본 시뮬레이션을 바탕으로 실제 태양전지 제작 과정에 적용 가능하다. p-type 태양전지 제작에서 후면의 p+ 영역의 깊이를 증가시키고, 표면 농도를 낮추는 공정을 통해 효율향상을 기대 할 수 있다.

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Performance of a Static Concentrator Photovoltaic Based on 4× Compound Parabolic Concentrator for Electric Vehicle Applications

  • Hoang Vu;Tran Quoc Tien;Nguyen Van Nhat;Ngoc Hai Vu;Seoyong Shin
    • Current Optics and Photonics
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    • v.8 no.4
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    • pp.375-381
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    • 2024
  • In this report, we present the design, fabrication, and experiment of a static solar system for electric vehicle (EV) applications. The static concentration component is composed of compound parabolic concentrators (CPCs) couplings with multi-junction solar cells, where a flat silicon panel is added to the bottom of the CPV structure to maximize power generation. This design allows the system to collect both direct sunlight and diffused sunlight. The CPCs were fabricated with acrylic with a geometric concentration ratio of 4×. We built a prototype with a (3 × 3) cell array of CPCs with a thickness of 25 mm, which is as thin as conventional flat photovoltaic panels, and performed an outdoor experiment that showed that after six hours of operation, the system had an acceptance angle of approximately 43° and an average daily efficiency of 22.85%.

Electrical Characteristics of c-Si Shingled Photovoltaic Module Using Conductive Paste based on SnBiAg (SnBiAg 전도성 페이스트를 이용한 Shingled 결정질 태양광 모듈의 전기적 특성 분석)

  • Yoon, Hee-Sang;Song, Hyung-Jun;Kang, Min Gu;Cho, Hyeon Soo;Go, Seok-Whan;Ju, Young-Chul;Chang, Hyo Sik;Kang, Gi-Hwan
    • Korean Journal of Materials Research
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    • v.28 no.9
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    • pp.528-533
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    • 2018
  • In recent years, solar cells based on crystalline silicon(c-Si) have accounted for much of the photovoltaic industry. The recent studies have focused on fabricating c-Si solar modules with low cost and improved efficiency. Among many suggested methods, a photovoltaic module with a shingled structure that is connected to a small cut cell in series is a recent strong candidate for low-cost, high efficiency energy harvesting systems. The shingled structure increases the efficiency compared to the module with 6 inch full cells by minimizing optical and electrical losses. In this study, we propoese a new Conductive Paste (CP) to interconnect cells in a shingled module and compare it with the Electrical Conductive Adhesives (ECA) in the conventional module. Since the CP consists of a compound of tin and bismuth, the module is more economical than the module with ECA, which contains silver. Moreover, the melting point of CP is below $150^{\circ}C$, so the cells can be integrated with decreased thermal-mechanical stress. The output of the shingled PV module connected by CP is the same as that of the module with ECA. In addition, electroluminescence (EL) analysis indicates that the introduction of CP does not provoke additional cracks. Furthermore, the CP soldering connects cells without increasing ohmic losses. Thus, this study confirms that interconnection with CP can integrate cells with reduced cost in shingled c-Si PV modules.

Comparison of Passivation Property on Hydrogenated Silicon Nitrides whose Antireflection Properties are Identical (반사방지 특성을 통일시킨 실리콘 질화막 간의 패시베이션 특성 비교)

  • Kim, Jae Eun;Lee, Kyung Dong;Kang, Yoonmook;Lee, Hae-Seok;Kim, Donghwan
    • Korean Journal of Materials Research
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    • v.26 no.1
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    • pp.47-53
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    • 2016
  • Silicon nitride ($SiN_x:H$) films made by plasma enhanced chemical vapor deposition (PECVD) are generally used as antireflection layers and passivation layers on solar cells. In this study, we investigated the properties of silicon nitride ($SiN_x:H$) films made by PECVD. The passivation properties of $SiN_x:H$ are focused on by making the antireflection properties identical. To make equivalent optical properties of silicon nitride films, the refractive index and thickness of the films are fixed at 2.0 and 90 nm, respectively. This limit makes it easier to evaluate silicon nitride film as a passivation layer in realistic application situations. Next, the effects of the mixture ratio of the process gases with silane ($SiH_4$) and ammonia ($NH_3$) on the passivation qualities of silicon nitride film are evaluated. The absorption coefficient of each film was evaluated by spectrometric ellipsometry, the minority carrier lifetimes were evaluated by quasi-steady-state photo-conductance (QSSPC) measurement. The optical properties were obtained using a UV-visible spectrophotometer. The interface properties were determined by capacitance-voltage (C-V) measurement and the film components were identified by Fourier transform infrared spectroscopy (FT-IR) and Rutherford backscattering spectroscopy detection (RBS) - elastic recoil detection (ERD). In hydrogen passivation, gas ratios of 1:1 and 1:3 show the best surface passivation property among the samples.

The electrical and optical properties of transparent ZnO:Al films using HCl wet chemical etching (HCL 습식 에칭에 의한 ZnO:Al 투명전도막의 전기적, 광학적 특성)

  • Yoo, Jin-Su;Lee, Jeong-Chul;Kang, Ki-Hwan;Kim, Seok-Ki;Yoon, Kyung-Hoon;Song, Jin-Soo;Park, I-Jun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05b
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    • pp.62-65
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    • 2002
  • Transparent conducting aluminum-doped Zinc oxide films (ZnO:Al) were prepared by rf magnetron sputtering on glass (Coming 1737) substrate as a variation of the deposition condition. After deposition, the smooth ZnO:Al films were etched in diluted HCl (0.5%) to examine the electrical and surface morphology properties as a variation of the time. The most important deposition condition of surface-textured ZnO films by chemical etching is the processing pressure and the substrate temperature. In low pressures (0.9mTorr) and high substrate temperatures $({\leq}300^{\circ}C)$, the surface morphology of films exhibits a more dense and compact film structure with effective light-trapping to apply the silicon thin film solar cells.

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Optimization of p-i-n amorphous silicon thin film solar cells using simulation (시뮬레이션을 통한 p-i-n 비정질 실리콘 박막 태양전지의 최적화)

  • Park, Seung-Man;Lee, Young-Suk;Jung, Sung-Wook;Yi, Jun-Sin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.436-436
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    • 2009
  • 현재 상용화되어 있는 결정질 태양전지의 경우 높은 실리콘 가격으로 인해 저가화에 어려움을 격고 있다. 따라서 태양전지 저가화의 한 방법으로 박막태양전지가 주목을 받고 있다. P-I-N 구조의 박막태양전지에서 각 층의 thickness, activation energy, energy bandgap은 고효율 달성을 위한 중요한 요소이다. 본 논문에서는 박막태양전지 P-I-N layer의 가변을 통하여 고효율을 달성하기 위한 simulation을 수행하였다. 가변 조건으로는 p-layer의 thickness, activation energy 그리고 energy bandgap을 단계별로 변화시켰고 i-layer는 thickness를 n-layer는 thickness와 activation energy를 가변하여 최적의 조건을 찾아 분석하였다. 최종 simulation 결과 p-layer의 thickness 5nm, activation energy 0.3eV 그리고 energy bandgap 1.8eV에서, i-layer thickness 400nm, n-layer thickness 30nm, activation energy 0.2eV에서 최고 효율 11.08%를 달성하였다.

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Optimization of microcrystaliline silicon thin film solar cells using simulation (i-layer 두께와 back reflect layer 유무가 미세결정 실리콘 박막태양전지에 미치는 영향)

  • Park, Seung-Man;Lee, Young-Suk;Jung, Sung-Wook;Yi, Jun-Sin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.437-437
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    • 2009
  • 현재 상용화되어 있는 결정질 태양전지의 경우 높은 실리콘 가격으로 인해 저가화에 어려움을 격고 있다. 따라서 태양전지 저가화의 한 방법으로 박막태양전지가 주목을 받고 있다. P-I-N 구조의 박막태양전지에서 I-layer 각 층의 thickness, activation energy, energy bandgap은 고효율 달성을 위한 중요한 요소이다. 본 논문에서는 박막태양전지 P-I-N layer의 가변을 통하여 고효율을 달성하기 위한 simulation을 수행하였다. 가변 조건으로는 p-layer의 thickness, activation energy 그리고 energy bandgap을 단계별로 변화시켰고 i-layer는 thickness를 n-layer는 thickness와 activation energy를 가변하여 최적의 조건을 찾아 분석하였다. 최종 simulation 결과 p-layer의 thickness 5nm, activation energy 0.3eV 그리고 energy bandgap 1.8eV에서, i-layer thickness 400nm, n-layer thickness 30nm, activation energy 0.2eV에서 최고 효율 11.08%를 달성하였다.

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A study on the properties of transparent conductive ZnO:Al films on variaton substrate temperature (기판온도 변화에 따른 ZnO:Al 투명 전도막의 특성 변화)

  • Yang, J.S.;Seong, H.Y.;Keum, M.J.;Son, I.H.;Shin, S.K.;Kim, K.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.525-528
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    • 2001
  • ZnO:Al thin film can be used as a transparent conducting oxide(TCO) which has low electric resistivity and high optical transmittance for the front electrode of amorphous silicon solar cells and display devices. This study of electrical, crystallographic and optical properties of Al doped ZnO thin films prepared by Facing Targets Sputtering(FTS), where strong internal magnets were contained in target holders to confine the plasma between the targets, is described. Optimal transmittance and resistivity was obtained by controlling flow rate of $O_2$ gas and substrate temperature. When the $O_2$ gas rate of 0.3 and substrate temperature $200^{\circ}C$, ZnO:Al thin film had strongly oriented c-axis and lower resistivity( < $10^{-4}{\Omega}-cm$ ).

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A study of etch-back structure for high efficiency in crystalline silicon solar cells (결정질 태양전지의 고효율화를 위한 선택적 도핑 중 에치-백 구조에 관한 연구)

  • Jung, Woo-Won;Yang, Du-Hwan;Lee, Yong-U;Gong, Dae-Yeong;Kim, Seon-Yong;Yi, Jun-Sin
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.347-347
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    • 2009
  • 결정질 태양전지의 공정에 있어서 호모지니어스(homogeneous)한 구조보다 향상된 변환효율을 얻기 위해 선택적 도핑 방법에 관한 연구가 활발하다. 선택적 도핑 방법이란 에미터(emitter) 층을 $n^{++}$ 영역과 $n^+$ 영역으로 나누어 향상된 전류밀도와 개방전압을 얻기 위한 방법이다. 본 연구에서 제시된 RIE 에치-백 구조는 다수의 선택적 도핑 방법 중 하나이다. 기존의 에치-백 구조는 전면 전극 형성 후 RIE 공정을 수행하기 때문에 전면 전극이 손상되고 RIE 데미지(damage)가 발생되는 문제점이 있었다. 그러나 본 연구에서 제시된 구조는 기존의 에치-백 구조와 달리 RIE 에칭 후 발생된 데미지를 제거하는 추가적인 공정인 질산 패시베이션(nitric acid passivation)이 수행되었다. 또한 본 연구에서 새롭게 제시된 블라킹 마스크 페이스트(blocking mask paste)는 기존의 에치-백 구조에서 발생된 전극 손상 문제를 해결해 주고 있다. 이러한 결과로 호모지니어스 구조보다 향상된 전류밀도 (35.77 mA/$cm^2$), 개방전압 (625 mV), FF (78.01%), 변환효율 (17.43%)를 얻었다.

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