• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.411-411
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• 2012

Over the recent years, surface enhanced Raman spectroscopy (SERS) has dramatically grown as a label-free detecting technique with the high level of selectivity and sensitivity. Conventional SERS-active nanostructured layers have been deposited or patterned on rigid substrates such as silicon wafers and glass slides. Such devices fabricated on a flexible platform may offer additional functionalities and potential applications. For example, flexible SERS-active substrates can be integrated into microfluidic diagnostic devices with round-shaped micro-channel, which has large surface area compared to the area of flat SERS-active substrates so that we may anticipate high sensitivity in a conformable device form. We demonstrate fabrication of flexible SERS-active nanostructured substrates based on soft-lithography for simple, low-cost processing. The SERS-active nanostructured substrates are fabricated using conventional Si fabrication process and inkjet printing methods. A Si mold is patterned by photolithography with an average height of 700 nm and an average pitch of 200 nm. Polydimethylsiloxane (PDMS), a mixture of Sylgard 184 elastomer and curing agnet (wt/wt = 10:1), is poured onto the mold that is coated with trichlorosilane for separating the PDMS easily from the mold. Then, the nano-pattern is transferred to the thin PDMS substrates. The soft lithographic methods enable the SERS-active nanostructured substrates to be repeatedly replicated. Silver layer is physically deposited on the PDMS. Then, gold nanoparticle (AuNP) inks are applied on the nanostructured PDMS using inkjet printer (Dimatix DMP 2831) to deposit AuNPs on the substrates. The characteristics of SERS-active substrates are measured; topology is provided by atomic force microscope (AFM, Park Systems XE-100) and Raman spectra are collected by Raman spectroscopy (Horiba LabRAM ARAMIS Spectrometer). We anticipate that the results may open up various possibilities of applying flexible platform to highly sensitive Raman detection.

• Applied Chemistry for Engineering
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• v.23 no.6
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• pp.515-520
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• 2012

In this review, the fabrication of silicon based memory capacitor and organic memory thin film transistors (TFTs) was discussed for their potential identification tag applications and biosensor applications. Metal or non-metal nanoparticles (NPs) could be capped with chemicals or biomolecules such as protein and oligo-DNA, and also be self-assembly monolayered on corresponding target biomolecules conjugated dielectric layers. The monolayered NPs were formed to be charging elements of a nano floating gate layer as forming organic memody deivces. In particular, the strong and selective binding events of the NPs through biomolecular interactions exhibited effective electrostatic phenomena in memory capacitors and TFTs formats. In addition, memory devices fabricated as organic thin film transistors (OTFTs) have been intensively introduced to facilitate organic electronics era on flexible substrates. The memory OTFTs could be applicable eventually to the development of new conceptual devices.

• Advances in concrete construction
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• v.17 no.2
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• pp.111-126
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• 2024

During the clinkering stages of cement production, the chemical composition of fine raw materials such as limestone and clay, which include iron oxide (Fe₂O₃), silicon dioxide (SiO₂) and aluminum oxide (Al₂O₃), significantly influences the quality of the final product. Specifically, the chemical interaction of Fe₂O₃ with CaO, SiO₂ and Al₂O₃ during clinkerisation plays a key role in determining the chemical reactivity and overall quality of the final cement, shaping the properties of the concrete produced. As an extension, this study aims to investigate the physical effects of incorporating nanosized Fe₂O₃ particles as fillers in concrete matrices, and their impact on concrete structures, namely slabs. To accurately model the reinforced concrete (RC) slabs, a refined trigonometric shear deformation theory (RTSDT) is used. Additionally, the stochastic Eshelby's homogenization approach is employed to determine the thermoelastic properties of nano-Fe₂O₃ infused concrete slabs. To ensure comprehensive coverage in the study, the RC slabs undergo various mechanical loads and are exposed to temperature fields to assess their thermo-mechanical performance. Furthermore, the slabs are assumed to rest on a three-parameter viscoelastic foundation, comprising the Winkler elastic springs, Pasternak shear layer and a damping parameter. The equilibrium governing equations of the system are derived using the principle of virtual work and subsequently solved using Navier's technique. The findings indicate that while ferric oxide nanoparticles enhance the mechanical properties of concrete against mechanical loading, they have less favorable effects on its performance against thermal exposure. However, the viscoelastic foundation contributes to mitigating these effects, improving the concrete's overall performance in both scenarios. These results highlight the trade-offs between mechanical and thermal performance when using Fe₂O₃ nanoparticles in concrete and underscore the importance of optimizing nanoparticle content and loading conditions to improve the structural performance of concrete structures.