• Journal of the Korean Vacuum Society
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• v.4 no.1
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• pp.32-39
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• 1995

SnO2/AI/Ag/AI/SnO2층 구조로 이루어진 열처리 가능한 열선반사막을 직류 스퍼터링법에 의해 soda-lime silicate 유리위에 형성시켰다. 이 코팅유리를 $650^{\circ}C$에서 열처리하면 가시광선 투과율 85%이상, plasma wavelength 970nm 이하를 얻을 수 있었다. 따라서 이 구조의 막은 유리 곡가공에 견디는 열적 안정성을 나타내었으며, 코팅유리의 열처리에 따른 전기적 특성 및 열적 안정성은 각각 Ag와 AI층의 두께에 의존하였다.

• Journal of the Korean Ceramic Society
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• v.30 no.5
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• pp.339-346
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• 1993

Inproving laser efficiency, optimum content of Nd3+ which is active ion and effect of Cr3+ as a sensitizer are investigated in 60SiO2.30Li2O.10CaO host glass. The glasses are fabricated with the addition of Nd3+, Cr3+ and then optical properties such as absorption spectrum, fluorescence spectrum and fluorescence lifetime were studied. Finally, lasing efficiency was measured. From this study, optimum content of Nd2O3 appeared to be 3.5wt% and it was observed that the energy absorbed by optical exicitation of the Cr3+ is transfered to the Nd3+. Addition of Cr2O3 tend to improve characteristic of laser oscillation for the laser glass.

• Journal of Welding and Joining
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• v.21 no.2
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• pp.35-41
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• 2003

Sintered alumina ceramics were joined by 2 kinds of SiO$_2$-CaO-A1$_2$O$_3$ glass solders having a similar expansivity as alumina. Wetting of glass/alumina was examined by sessile drop method. The observation of interface and bending strength related to alumina/glass/alumina systems were investigated by means of SEM/EDX and 4-point bending test. the result are summarized as follow: (1) Wetting of glass solders on alumina was good at temperatures higher than 145$0^{\circ}C$. (2) When the joining temperature wan high, diffusion and/or reactions between solder md alumina took place at the interface. These diffusions and reactions occurring at the interface greatly affected the bending strength of joining body. (3) Highest strength corresponding to 80% that of alumina was obtained by the solder of 35SiO$_2$-35CaO-30A1$_2$O$_3$(wt%) glass.

• Journal of the Korean Ceramic Society
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• v.17 no.3
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• pp.151-157
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• 1980

Crystallization phenomena of glasses of fused natural basalt rocks were studied by DTA, X-ray phase analysis, electron microscopy, and other techniques. Crystallization was catalyzed by the addition of either chromite ore or $P_2O_5$, both up to 5 wt %. Various heat treatments were used, and their influences on controlling the microstructures and properties of the products were studied to develop high strength glass-ceramic material of the $CaO-Al_2O_3(Fe_2O_3)-MgO(FeO)-SiO_2$ system from the domestic basalts. Magnetite precipitates were found to be a nucleation initiator in every case of the crystallization. Diopside, anorthite, clinoenstatite and monticellite were identified as silicate crystalline phases contained in the crystallized products. The crystallite size was in the range of 0.1-2.5$\mu\textrm{m}$. The fine crystallites were approximately cubic, but large crystallites were either plate or needle shape. The thermal expansion coefficient, microhardness and modulus of rupture of glass-ceramics were ranged from 78.5 to 81.8$\times$10-7 cm/cm/$^{\circ}C$, from 820 to 930kg/$\textrm{mm}^2$, and from 1800 to 2800kg/$\textrm{cm}^2$, respectively.

• Journal of the Korean Ceramic Society
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• v.24 no.2
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• pp.101-110
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• 1987

The relative electrical conductivity of vacuum deposited Al films on a soda-lime(2947) and an alumino boro silicate(7809) glass was investigated with the variation of the relative humidity,temperature and film thickness. The structure and microstructure of Al films before and after exposure to the humidity wereexamined by the X-ray Diffractormenter(XRD) and Scanning Electron Microscope(SEM). As the relative humidity increased, the electrical conductivity of Al films on both glasses was decreased. However, the Al films on 7809 glass showed higher conductivity than that of 2947 glass under the same testing conditions. The decreasing of electrical conductivity was caused by the formation of Aluminum hydroxide which was made by the reaction between the aluminum films and water vapor.

• Journal of Welding and Joining
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• v.20 no.3
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• pp.116-121
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• 2002

For the accumulation of a fundamental knowledge about the behavior of glass solder during the joining of ceramics, the wettability of solder on silicon nitride have been measured by sessile drop method. $SiO_2-MgO-Al_2O_3$ g1ass solder and oxynitride glass solders were selected as examples while silicon nitride which were used as substrates. Contact angle of solder on silicon nitride didn't decrease with time at high nitrogen content in the solder, but low nitrogen content in solders have the time-dependent property. Reason which contact angle of low nitrogen content in solders decrease on silicon nitride was that diffusion of nitrogen take place between solder and silicon nitride.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.633-634
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• 2005

Transparent conducting glasses exhibit high ohmic losses that are apparent in the case of large size Dye Sensitized Solar Cells (DSSCs). In this study, we investigated the impact of current collectors over the efficiency of DSSCs. The Silver current collectors were prepared on both counter electrode and working electrode surface by screen printing method. For long term stability in electrolyte environment and also to avoid the charge recombination, current collectors are protected by sodium silicate overcoat layer. These current collectors were characterized for their microstructure parameters. Also current collector's stability in electrolyte environment has been investigated.

• Journal of the Mineralogical Society of Korea
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• v.28 no.1
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• pp.61-69
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• 2015

While the macroscopic properties and eruption style of basaltic and phonolitic melts are different, the microscopic origins including atomic structures are not well understood. Here we report the atomic structure differences of glass in diopside-anorthite eutectic composition (basaltic glass) and phonolitic glass using high-resolution 1D and 2D solid-state Nuclear Magnetic Resonance (NMR). The $^{27}Al$ MAS NMR spectra for basaltic glass and phonolitic glass show that the full width at half maximum (FWHM) of Al for basaltic glass is about twice than phonolitic glass, suggesting the topological disorder of basaltic magma is larger than that of phonolitic magma. The $^{27}Al$ 3QMAS NMR spectra for basaltic glass and phonolite glass show much improved resolution than the 1D MAS NMR, resolving Al and Al. Approximately 3.3% of Al is observed for basaltic glass, demonstrating the configurational disorder of basaltic magma is larger than phonolitic magma. This result confirms that the topological disorder of Al in basaltic glass is larger than that of phonolitic glass. The observed structural differences between basaltic glass and phonolitic glass can provide an atomistic origin for change of the macroscopic properties with composition including viscosity.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.16 no.5
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• pp.227-234
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• 2006

Microstructures of free surface and interior of glass-ceramics obtained by heat treating silicate glass specimen containing electric arc furnace dust(EAF dust) were observed. The crystallization temperature, $T_c$ of glassy specimen was measured around $850^{\circ}C$ from the result of different thermal analysis so heat treatment temperature to obtain glass-ceramic specimen was selected as $950^{\circ}C$ for 1 hr. Glass specimens containing 50 wt% dust were amorphous, while glass specimens containing 70 wt% dust showed spinel crystal peaks in XRD results. In case of glass-ceramic specimens, spinel crystalline phase was appeared with willemite, and willemite crystal peak intensity increased with increasing dust contents. The fractured surface of glass specimens containing 50 wt% dust was smooth like mirror surface, but that containing 70 wt% dust showed spinel crystals of 10 ${\mu}m$ size in glass matrix. In case of glass-ceramic specimens, ZnO crystal particles of $2{\sim}5{\mu}m$ size were produced in free surface and glassy phase, spinel and willemite crystal phases existed in interior. There were no crystals in glasses containing 50 wt% dust, while glass containing 70 wt% dust had 14 vol% crystals. Crystallinity of glass-ceramic specimens containing 50 and 70 wt% dust were 19 and 43%, respectively. When microstructures of glass and glass-ceramic specimens were observed through SEM after TCLP experiment, glass specimens showed flaking phenomenon while glass-ceramic specimens showed a slight corrosion evidence without any cracks.

• Applied Chemistry for Engineering
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• v.24 no.4
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• pp.382-390
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• 2013

Foaming process of waste soda lime glasses by just chemical composition control of vitreous feed materials was investigated to find a novel and efficient recycling process. For the chemical composition control of feed materials, 10 wt. parts of $SiO_2$, 0.5 wt. parts of $Na_2SO_4$, 3.0 wt. parts of $B_2O_3$, and 0.3 wt. parts of carbon black as the foaming agent were mixed with 100 wt. parts of soda-lime vitreous feed powder. Proper conditions for foaming process in tunnel kiln are the foaming temperature of $830{\sim}850^{\circ}C$, the foaming time of 30~35 min, and the vitreous feed powder particle size of -325 mesh. Properties of foamed glass blocks obtained under these foaming conditions showed the density of $0.17{\sim}0.21g/cm^3$, thermal conductivity of $0.06{\pm}0.005kcal/h{\cdot}m{\cdot}^{\circ}C$, moisture absorption of 1.1~1.5%, and compressive strength of $20{\sim}30kgf/mm^2$.