• Bulletin of the Korean Chemical Society
• /
• 제33권4호
• /
• pp.1135-1140
• /
• 2012

An electrochromatographic microchip with carboxyl-group-derivatized mono-disperse silica packing was prepared from the corresponding colloidal silica solution by utilizing capillary action and self-assembly behavior. The silica beads in water were primed by the capillary action toward the ends of cross-patterned microchannel on a cyclic olefinic copolymer (COC) substrate. Slow evaporation of water at the front of packing promoted the self-assembled packing of the beads. After thermally binding a cover plate on the chip substrate, reservoirs for sample solutions were fabricated at the ends of the microchannel. The packing at the entrances of the microchannel was silver coated to fix utilizing an electroless silver-plating technique to prevent the erosion of the packed structure caused by the sudden switching of a high voltage DC power source. The electrochromatographic behavior of the microchip was explored and compared to that of the microchip with bare silica packing in basic borate buffer. Electrophoretic migration of Rhodamine B was dominant in the microchip with the carboxyl-derivatized silica packing that resulted in a migration approximated twice as fast, while the reversible adsorption was dominant in the bare silica-packed microchip. Not only the faster migration rates of the negatively charged FITC-derivatives of amino acids but also the different migration due to the charge interaction at the packing surface were observed. The electrochromatographic characteristics were studied in detail and compared with those of the bare silica packed microchip in terms of the packing material, the separation potential, pH of the running buffer, and also the separation channel length.

• 한국주조공학회지
• /
• 제22권3호
• /
• pp.137-143
• /
• 2002

Silica sand, zircon sand, and steel shots were used as mold packing materials in lost foam casting of the aluminum alloy bar. Vibration acceleration in three directions and temperatures in the casting and mold were measured, and packing and cooling characteristics of these materials were investigated. Packing densities increased with increase in vibration magnitude and time, and were $1.41{\sim}1.49g/cm^2$ for silica sand, $2.54{\sim}2.86g/cm^2$ for zircon sand, and $3.92{\sim}4.52g/cm^2$ for steel shots. Sound castings were obtained only without evacuation of the flask during pouring. Solidification time became faster in order of silica sand, zircon sand and steel shot packing because steel shot has the highest cooling capacity of them. Solidification time of steel shot packing was shortened to about 1/2 of silica sand packing. Cooling capacity of sand mold was generally evaluated by heat diffusivity of the mold, however could be simply evaluated with specific heat per unit volume of the packing material in lost foam casting.

• Bulletin of the Korean Chemical Society
• /
• 제35권1호
• /
• pp.45-50
• /
• 2014

A fully packed capillary electrochromatographic (CEC) microchip with an on-column micro-solid phase extraction (SPE) bed for the preconcentration and separation of organic analytes was prepared. A linear microchannel with monodisperse colloidal silica packing was formed on a cyclic olefinic copolymer microchip with two reservoirs on both ends. Silver-cemented silica packing frit structure was formed at the entrance of the microchannel by electroless plating treatment as a base layer. A gold coating was formed on it by reducing $Au^{3+}$ to gold with hydroxylamine. Finally micro-SPE bed was formed by self-assembly adsorption of 1-dodecanethiol on it. Micro-SPE beds were about 100-150 ${\mu}m$ long. Approximately $10^3$ fold sensitivity enhancements for Sulforhodamine B, and Fluorescein in nM concentration levels were possible with 80 s preconcentration. Basic extraction characteristics were studied.

• Advances in concrete construction
• /
• 제10권5호
• /
• pp.431-441
• /
• 2020

For the purpose of improving the properties of UHPC as well as the economic efficiency in production of the material, Availability of river sands as fine aggregate instead of micro silica sand were investigated. Four different sizes of river sands were considered. Using river sand instead of micro silica sand increased the flowability, and decreased the yield stress and plastic viscosity in rheological properties, and the effect was higher with larger particle size of river sand. It was demonstrated by analyses based on the packing density. In the results of compressive strength and elastic modulus, even though river sand was not as good as micro silica sand, it could provide high strength of over 170 MPa and elastic modulus greater than 40 GPa. The difference in compressive strength depending on the size of river sand was explained with the concept of maximum paste thickness based on the packing density of aggregate. The flexural performance with river sand also presented relatively lower resistance than micro silica sand, and the reduction was greater with larger particle size of river sand. The flexural performance was proven to be also influenced by the difference in the fiber orientation distribution due to the size of river sand.

• 한국산업보건학회지
• /
• 제25권1호
• /
• pp.95-103
• /
• 2015

Objectives: This study was conducted in order to better understand the conceptual model and Stoffenmanager nano module and apply it to the synthesis and packing processes of nanomaterials. Methods: Site visits were conducted to five nanomaterial production processes. Product and exposure variables were investigated in these workplaces. Hazard banding and exposure classification of the synthesis and packing processes of nanomaterials were conducted using documents and the website of Stoffenmanager Nano. Results: The five sites featured different products, packing tasks, ventilation and local exhaust, and others. The hazards for nano-nickel and copper were classified as E. The hazards for both fumed silica and indium tin oxide were classified as D. The hazard for spherical silica was classified as C. The exposure classes in the synthesis process of nanomaterials ranged from 2 through 4. The exposure classes in the packing process of nanomaterials ranged from 1 through 4. Conclusions: Application of Stoffenmanager nano to the synthesis and packing processes of nanomaterials helped to better understand the control level of the work environment and to suggest appropriate actions. The comparison of each process showed the effect of the production process and handling of solids and ventilation on exposure class.

• 한국환경과학회지
• /
• 제21권3호
• /
• pp.305-312
• /
• 2012

This work is to study the variations of adsorption characteristics of binary vapor according to packing system of double-layer bed by fixed bed experiment. Breakthrough curves of single and binary vapor composed of acetone and benzene on single-layer and double-layer adsorption bed composed of activated carbon (AC) and silica-aluminar (SA) were compared. Adsorptions of binary vapor on double-layer bed were influenced by the differences of surface area between adsorbents as well as the polarity difference between adsorbent and adsorbate. The roll-up phenomenon of acetone vapor was happened by replacement with competing adsorption between acetone vapor and benzene vapor on AC bed, but it was not happened on SA bed because acetone vapor and benzene vapor had less difference in affinity with SA bed. The breakthrough times of acetone vapor and benzene vapor on AC/SA double-layer bed were three times and 1.4 times larger respectively than on SA/AC double-layer bed, the differences of breakthrough times were relatively larger than the equilibrium adsorption capacities according to packing system of double-layer bed.

• 한국전기전자재료학회논문지
• /
• 제32권3호
• /
• pp.246-251
• /
• 2019

A solvent free, highly concentrated silica-acryl monomer hybrid sol was synthesized using aqueous colloidal silica as a precursor. The effects of the silica particle size, type of surface treatment agent employed, and silica content on the formation of the hybrid sol were systematically studied. The optical and physical properties of the coating solution prepared using the hybrid sol were also characterized. The viscosity of the hybrid sol tended to decrease as the particle size of the silica and the molecular weight of the surface treatment agent increased. The PET substrate coated with MPTMS-Mix (mixture, 70 wt%) solution showed the highest surface hardness (6 H) and low surface roughness ($Ra=0.044{\mu}m$), which could be attributed to an increase in packing density caused by the infiltration of small particles into the pores formed between larger particles.

• 한국세라믹학회:학술대회논문집
• /
• 한국세라믹학회 2002년도 추계총회 및 연구발표회 초록집
• /
• pp.120.2-120
• /
• 2002

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
• /
• pp.267.1-267.1
• /
• 2013

In modern science and technology, the organization of building blocks, such as spherical particles and zeolite, is important to form a nanostructure. So, it is essential to develop methods for organizing them into large scale for many precise applications. Up to now, reflux and stirring is widely used method for organization of colloidal particles. However, because this method is hard to organize building block with high coverage and uniform orientation, it is necessary to research another method. In this work, we synthesized spherical silica particles using St$\"{o}$ber method and organized them on the glass which is coated with 3-chloropropyltrimethoxysilane (CP-TMS) and polyethyleneimine (PEI) using Sonication method. Although spherical silica particles are difficult to attach on the glass due to their small attachment site, we improved this problem by coating PEI. We introduced two mode of reaction promotion, sonication (SO) and sonication with stacking between the bare glass (SS), and investigated degree of coverage (DOC) and degree of close packing (DCP).

• 반도체디스플레이기술학회지
• /
• 제8권2호
• /
• pp.49-53
• /
• 2009

The oxygen barrier films were formed on poly(ethylene terephthalate) (PET) substrate by a sol-gel process using 3-aminoproprytrimethoxysilane (APTMOS). The effects of solvent type, coating times and incorporation of fumed silica on oxygen permeability coefficient were investigated. The APTMOS coating film prepared from methanol as a solvent exhibited higher oxygen barrier properties than that using THF. The oxygen permeability coefficient of coated film with APTMOS/methanol by coating 7 times was measured to be $2.28{\times}10^{-6}$, while that of PET film was $1.16{\times}10^{-4}$ GPU. The addition of fumed silica does not affect the oxygen barrier properties. It may be explained that silica particles disrupt chain packing, which leads to an increase in free volume for permeation.