• Title/Summary/Keyword: Silaspirotropylidene

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Synthesis and Photoluminescent Properties of Silaspirotropylidene (Silaspirotropylidene의 합성 및 광학적 특성)

  • Kwon, Yonghee
    • Journal of Integrative Natural Science
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    • v.2 no.3
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    • pp.215-218
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    • 2009
  • A silaspirotropylidene has been obtained from the reaction of the lithium salt of tetraphenylsilole dianion with 2 equiv of diphenylcyclopropene, followed by quenching with Me3SiCl. Silaspirotropylidene exhibits an unusual optical property its optical property was characterized by UV-vis and fluorescence spectroscopy. Absorption wavelength maxima of silaspirotropylidene was 420 nm. silaspirotropylidene displayed an emission band at 550 nm with excitation wavelength of 420 nm.

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