• 유기물자원화
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• 제21권2호
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• pp.88-96
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• 2013

본 연구의 목적은 고형폐기물의 메탄발생 특성을 나타내기 위한 1차 반응식과 S형태 식들의 적합성을 평가하는 것이다. S형태 식은 수정 Gompertz와 Logistic 식을 사용하였다. 모델의 적합성을 평가하기 위해 잔차제곱합, 표준제곱근 오차, Akaike's information criterion 등의 통계분석을 실시하였다. AIC (Akaike's information criterion)는 모델의 변수 개수 차이에 따른 모델 적합성을 비교하기 위하여 적용하였다. 1차 반응식의 경우 지체기를 고려하지 않을 때보다 고려하였을 경우 잔차제곱합과 표준제곱근 오차는 감소하는 것으로 나타났다. 그러나 1차 반응식의 경우 S형태 식보다 AIC가 상대적으로 높게 나타났다. 이는 S형태 식이 1차 반응식보다 메탄발생특성을 나타낼 때에 더욱 적합한 것으로 사료된다.

• Carbon letters
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• 제4권4호
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• pp.185-191
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• 2003

Two types of carbon fiber based high modulus- and isotropic-pitch were exposed to isothermal oxidation in air and $CO_2$ gas and the weight change was measured by TGA apparatus. The kinetic equation was introduced $f=1-{\exp}(-at^b)$ and the constant b was obtained in the range of 1.02~1.68 for the isotropic fiber and obtained 0.91~1.93 for the high modulus fiber respectively. In considering the effect of the atmosphere for isothermal oxidation, the value of the constant b obtained in the carbon dioxide was higher than that obtained in the air. Therefore, it was found that the pitch based carbon fiber shows sigmoidal characteristic when it is oxidized in the carbon dioxide. In addition, it was also found that $k_f = 0.5$, which was reaction constant at f = 0.5, was a very useful parameter for evaluation of the oxidation reactivity of pitch based carbon fibers. According to the consideration, it is suggested that the conversion-time curves of the pitch based carbon fibers are correlated by normalized equation $f=1-{\exp}(-A{\tau}^B)$, where ${\tau}=t/t_f= 0.5$.