• Title/Summary/Keyword: Si(111)-H

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The Study of Low Temperature $\muC-Si/CaF_2$/glass Film Growth using Buffer layer (Buffer layer 를 이용한 저온 $\muC-Si/CaF_2$/glass 박막성장연구)

  • 김도영;안병재;임동건;이준신
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.589-592
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    • 1999
  • This paper describes direct $\mu$C-Si/CaF$_2$/glass thin film growth by RPCVD system in a low temperature for thin film transistor (TFT), photovoltaic devices. and sensor applications. Experimental factors in a low temperature direct $\mu$ c-Si film growth are presented in terms of deposition parameters: SiH$_4$/H$_2$ ratio, chamber total pressure, substrate temperature, rf power, and CaF$_2$ buffer layer. The structural and electrical properties of the deposited films were studied by means of Raman spectroscopy, I-V, L-I-V, X-ray diffraction analysis and SEM. we obtain a crystalline volume fraction of 61%, preferential growth of (111) and (220) direction, and photosensitivity of 124. We achieved the improvement of crystallinity and electrical property by using the buffer layers of CaF$_2$ film.

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실리콘 이종접합 태양전지의 Novel BSF Metal 적용 및 Laser Annealing에 관한 연구

  • An, Si-Hyeon;Jang, Gyeong-Su;Kim, Seon-Bo;Jang, Ju-Yeon;Park, Cheol-Min;Park, Hyeong-Sik;Song, Gyu-Wan;Choe, U-Jin;Choe, Jae-U;Jo, Jae-Hyeon;Lee, Jun-Sin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.604-604
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    • 2012
  • 기존의 실리콘 이종접합 태양전지는 후면에도 passivation layer인 i-a-Si:H 및 BSF층인 n-a-Si:H가 형성되는 구조를 가지고 있었다. 이러한 구조를 대체하기 위하여 본 연구에서는 실리콘 이종접합 태양전지의 후면 구조에 passivation 층 및 BSF층을 novel material인 Sb증착 및 RTP, laser anneal을 통해 새로운 BSF층 형성하고 태양전지 특성에 대해서 분석하였다. 이를 위해서 carrier lifetime, LIV, DIV 및 QE 등 전기적, 광학적 분석뿐만 아니라 SIMS 분석을 통하여 laser annealing 공정으로 형성된 BSF층의 depth profile 분석도 진행하였다. 또한 wafer orientation에 따른 특성을 분석하기 위하여 (100) 및 (111) wafer를 이용하여 분석하였다.

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DFT Study for Adsorption and Decomposition Mechanism of Trimethylene Oxide on Al(111) Surface

  • Ye, Cai-Chao;Sun, Jie;Zhao, Feng-Qi;Xu, Si-Yu;Ju, Xue-Hai
    • Bulletin of the Korean Chemical Society
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    • v.35 no.7
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    • pp.2013-2018
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    • 2014
  • The adsorption and decomposition of trimethylene oxide ($C_3H_6O$) molecule on the Al(111) surface were investigated by the generalized gradient approximation (GGA) of density functional theory (DFT). The calculations employed a supercell ($6{\times}6{\times}3$) slab model and three-dimensional periodic boundary conditions. The strong attractive forces between $C_3H_6O$ molecule and Al atoms induce the C-O bond breaking of the ring $C_3H_6O$ molecule. Subsequently, the dissociated radical fragments of $C_3H_6O$ molecule oxidize the Al surface. The largest adsorption energy is about -260.0 kJ/mol in V3, V4 and P2, resulting a ring break at the C-O bond. We also investigated the decomposition mechanism of $C_3H_6O$ molecules on the Al(111) surface. The activation energies ($E_a$) for the dissociations V3, V4 and P2 are 133.3, 166.8 and 174.0 kJ/mol, respectively. The hcp site is the most reactive position for $C_3H_6O$ decomposing.

Properties of Aluminum Films Deposited by CVD using DMEAA (DMEAA 소스로 기상화학 증착된 알루미늄 박막의 증착특성)

  • Jang, T.W.;Moon, W.;Baek, J.T.;Ahn, B.T.
    • Korean Journal of Materials Research
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    • v.6 no.3
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    • pp.333-340
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    • 1996
  • p-type(100) 실리콘 기판과 TiN(50nm)/Si 기판에 dimethylethylamine alane(DMEAA)을 반응소스로 하여 알루미늄을 증착시켜 증착온도와 유량, 반송가스 종류에 따른 방향성, 증착속도, 미세구조 변화에 대해 연구하였다. 알루미늄의 증착속도는 기판온도, 반송가스 종류 및 유량에 따라 100-650mn/min으로 다양하게 조절되었다. DMEAA의 증착 활성화에너지는 TiN 기판에서는 약 0.leV이었고 Si와 SiO2 기판에서는 각각 약 0.23eV, 0.24eV이었다. 알루미늄 박막의 방향성은 증착속도의 감소에 따라 (200)에서 (111)방향으로 변하였다. 증착된 알루미늄 박막의 불순물 함량은 산소의 경우 0.2at%, 탄소의 경우 1.8at.%이었다. DMEAA 소스에 의한 알루미늄의 증착속도는 반송가스가 Ar 일 때 보다 H2 가스를 사용하면 증착속도가 크게 증가하였으며 이는 반송가스에 의해 SiO2표면의 흡착 H 농도가 증가하고 흡착 H가 소스 가스와 반응하여 핵생성 site 로 작용하는 것으로 생각된다. 알루미늄 박막의 비저항은 표면 미세조직에 크게 영향을 받으며 그 값은 약 3-7$\mu$$\Omega$cm이었다.

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A Study on the Analysis of Magnetoresistive Behavior in Giant Magnetoresistive Spin Valve Trilayer Films (거대자기저항 스핀밸브 삼층박막의 자기저항 거동 해석에 관한 연구)

  • 김형준;이병일;주승기
    • Journal of the Korean Magnetics Society
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    • v.8 no.4
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    • pp.224-230
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    • 1998
  • The relationships between R-H curves of gaint magnetoresistance (GMR) spin valve trilayer films and M-H curves of each magnetic layer consisting of the trilayer films were analyzed and simple formula representing the relations between the curves were suggested for theoretical analysis and study of magnetoresistance (MR) in those films, especially where the MR is from the difference of coercivity. Using two kinds of NiFe/Cu/Co films, which had been deposited on Cu(50 $\AA$)/Si(111, 4$^{\circ}$ tilt-cut) and Cu(50 $\AA$)/glass, R-H and M-H curves were measured and compared with the calculated ones, which were obtained by appying the M-H curves of single NiFe and Co films, deposited on the same substrates, to the previously reported single-domain and multi-domain models. The calcuated ones were well consistent with the measured ones and the suggested simple relationships between R-H and M-H curves are thought to be very useful for the deep understanding of MR behavior and the reasonable approach to improve MR properties in GMR spin valve trilayer films.

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