• 한국연소학회:학술대회논문집
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• 2001.06a
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• pp.90-98
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• 2001

Characteristics of high temperature rocket nozzle flow is discussed along with the aspects of computational analysis. Three methods of nozzle flow analysis, frozen-equilibrium, shifting-equilibrium and non-equilibrium approaches, were discussed, those were coupled with the methods of computational fluid dynamics code. A chemical equilibrium code developed for the analysis of general hydrocarbon fuel was coupled with three approaches of nozzle flow analysis. The approaches were used for the performance prediction of KSR-III Rocket, and compared with the theoretical results from NASA CEA (Chemical Equilibrium with Applications) code.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.03a
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• pp.448-451
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• 2008

Three methods of nozzle flow analysis, frozen-equilibrium, shifting-equilibrium and non-equilibrium approaches, were used to rocket nozzle flow, those were coupled with the methods of computational fluid dynamics code. For a design of high temperature rocket nozzle, chemical equilibrium analysis which shares the same numerical characteristics with frozen flow analysis can be an efficient design tool for predicting maximum thermodynamic performance of the nozzle. Frozen fluid analysis presents the minimum performance of the nozzle because of no consideration for the energy recovery. On the other hand, the case of chemical-equilibrium analysis is able to forecast the maximum performance of the nozzle due to consideration for the energy recovery that is produced for the fast reaction velocity compared with velocity of moving fluid. In this study, using the chemical equilibrium flow analysis code that is combined the modified frozen-equilibrium and the chemical-equilibrium. In order to understand the thermochemical characteristic components and the accompanying energy recovery, shifting-equilibrium flow analysis was carried out for the 30 $ton_f$-class KARI liquid rocket engine nozzle together with frozen flow. The performance evaluation based on the 30 $ton_f$-class KARI LRE nozzle flow analyses will provide an understanding of the thermochemical process in the nozzle and performances of nozzle.

• 한국전산유체공학회:학술대회논문집
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• 2001.05a
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• pp.144-148
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• 2001

Characteristics of high temperature rocket nozzle flow is discussed along with the aspects of computational analysis. Three methods of nozzle flow analysis, frozen-equilibrium, shifting-equilibrium and non-equilibrium approaches, were discussed those were coupled with the methods of computational fluid dynamics. A chemical equilibrium code developed for the analysis of general hydrocarbon fuel was coupled with three approaches of nozzle flow analysis, and a test was made for a bell nozzle at typical operation condition. As a results, the characteristics of the approaches were discussed in aspects of rocket performance, thermal analysis and computational efficiency.

• Proceedings of the KSME Conference
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• 2001.06a
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• pp.854-859
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• 2001

An eigenvalue analysis of a tunable micro-mechanical actuator is presented. The actuator is modeled as a continuum structure. The eigenvalue modified by the tuning voltage is computed through the linearization of the relation between the electrostatic force and the displacement at the equilibrium. A staggered algorithm is employed to perform the coupled analysis of the electrostatic and elastic fields. The stiffness matrix of the actuator is modified at this equilibrium state. The displacement field is perturbed using an eigenmode profile of the actuator. The configuration change of the actuator due to perturbation modifies the electrostatic field and thus the electrostatic force. The equivalent stiffness matrix corresponding to the perturbation and the change in the electrostatic force is then added to stiffness matrix in order to explain natural frequency shifting. The numerical examples are presented and compared with the experiments in the literatures.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2007.11a
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• pp.105-109
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• 2007

Three methods of nozzle flow analysis, frozen-equilibrium, shifting-equilibrium and non-equilibrium approaches, were used to rocket nozzle flow, those were coupled with the methods of computational fluid dynamics code. For a design of high temperature rocket nozzle, chemical equilibrium analysis which shares the same numerical characteristics with frozen flow analysis can be an efficient design tool for predicting maximum thermodynamic performance of the nozzle. In this study, shifting-equilibrium flow analysis was carried out for the 30 $ton_f$-class KARl liquid rocket engine nozzle together with frozen flow. The performance evaluation based on the 30 $ton_f$-class KARl LRE nozzle flow analyses will provide an understanding of the thermochemical process in the nozzle and performances of nozzle.

• Journal of the Korean Society of Propulsion Engineers
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• v.12 no.3
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• pp.9-15
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• 2008

Nozzle flow analyses of $30\;ton_f$-class KARI liquid rocket engine for high altitude propulsion are carried out using a chemically frozen and equilibrium flow analysis code developed previously. It is considered that the combined frozen- and shifting- equilibrium analysis is cost-effective regarding the convergence characteristics and modeling uncertainties, though the non-equilibrium analysis is most reliable approach. A dependable performance prediction could be attainable through the present analyses that account for the recombination process and thermal and kinetic energy recovery during the expansion process with viscous effects.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.108-108
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• 2006

The role of conformational entropy of polymer chains in polymer crystallization is investigated by molecular modeling and theory. The entropy of folded loops dominates at experimentally relevant temperatures to dictate short equilibrium lamellar thicknesses, which are much smaller than the extended chain thickness. Also the entropic barriers control the kinetics of polymer crystallization. These results based on chain entropy are different from the classical views of how polymer chains crystallize.

• Journal of Korean Society of Transportation
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• v.8 no.2
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• pp.27-41
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• 1990

In this study the economic impacts of government support of shipping industry in the labor rich country are appraised in a general equilibrium model. Shipping industry subsidies (which are supposed to be supplied by lump-sum tax) will decrease disposable income by shifting productive resources from traded goods to the comparatively disadvantageous transport sector, and at the same time reduce the implicit tariff effect by lowering transport costs. The net effect of shipping industry subsidies is to increase social welfare because the latter positive effect of shipping industry subsidies is to increase social welfare because the latter positive effect dominates the former negative effect. Such an increase in social welfare can never be expected from competitive traded goods industry subsidies in the case of which social welfare will actually decrease because of inefficient resource allocation resulting from the subsidies. In addition it is worth noting that the subsidies on the most capital intensive shipping industry will rectify unevenness in income distribution by raising relative price of labor contrary to subsidies on capital intensive traded goods.

• Journal of the Korean Magnetic Resonance Society
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• v.1 no.2
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• pp.126-140
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• 1997

Mesoporous MCM-41 gallosilicate material was synthesized through shifting through shifting gallosilicate polymer equilibrium towards a MCM-41 phase by addition of acid. The location of Cu(II) exchanged into MCM-41 and its interaction with various adsorbate molecules were investigated by electron spin responance and electron spin echo modulation spectroscopies. It was found that in the fresh hydrated material, Cu(II) is octahedrally coordinated to six water molecules. This species is located in a cylindrical channel and rotates rapidly at room temperature. Evacuation at room temperature removes three of these water molecules, leaving the Cu (II) coordinated to three water molecules and anchored to oxygens in the channel wall. Dehydration at 45$0^{\circ}C$ produces one Cu (II) species located in the inner surface of a channel as evidenced by broadening of its ESR lines by oxygen. Adsorption of polar molecules such as water, methanol and ammonia on dehydrated CuNa-MCM-41 gallosilicate material causes changes in the ESR spectrum of Cu (II), indicating the complex formation with these adsorbates. Cu (II) forms a complex with six molecules of methanol as evidenced by an isotropic room temperature ESR signal and ESEM data like upon water adsorption. Cu(II) also forms a complex containing four molecules of ammonia based on resolved nitrogen superhyperfine interaction.

• Bulletin of the Korean Chemical Society
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• v.35 no.5
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• pp.1491-1494
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• 2014

High-crystallinity poly(3-hexylthiophene) (P3HT) thin films were prepared by aging the precursor solutions, prepared using a good solvent, chloroform, at low temperatures prior to spin-casting. Lower solution temperatures significantly improved the molecular ordering in the spin-cast P3HT films and, therefore, the electrical properties of field-effect transistors prepared using these films. Solution cooling enhanced the electrical properties by shifting the P3HT configuration equilibrium away from random coils and toward more ordered aggregates. At room temperature, the P3HT molecules were completely solvated in chloroform and adopted a random coil conformation. Upon cooling, however, the chloroform poorly solvated the P3HT molecules, favoring the formation of ordered P3HT aggregates, which then yielded more highly crystalline molecular ordering in the P3HT thin films produced from the solution.