• 한국환경보건학회지
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• 제31권4호
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• pp.280-286
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• 2005

The purpose of this investigation was to evaluate removal efficiency of $NH_4-N$ using the soil column. Soil, oyster shell and natural zeolite were used as a supporting media of soil column. Removal efficiencies of $NH_4-N$ were $35.9\%,\;41\%\;and\;93.4\%$ for the soil column packed with soil, natural $zeolite(20\%)$ and oyster $shell(20\%)$ at HRT of 72 hours, respectively. The addition of $20\%$ oyster shell to the soil accelerated nitrification in soil column. The influent ammonia nitrogen was mostly converted to nitrate nitrogen in the soil column and little ammonia nitrogen was found in the effluent. When the influent $NH_4-N$ concentration was 200 mg/l, the NIL-N removal was decreased at HRT of 48 hours, while nitrification was significantly increased after mechanical aeration. It was suggested that nitrification from higher $NH_4-N$ concentration was more affected by aeration in soil column process. The number of nitrifiers was approximately in a level of about $10^6\;MPN/g{\cdot}soil$ in the soil column mixed with oyster shell ($20\%$).

• 한국환경과학회지
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• 제15권11호
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• pp.1053-1059
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• 2006

This study was performed to investigate the possible uses of waste sludge for the removal of heavy metal ions. The adsorption experiments were conducted with wastes such as sewage treatment sludge, water treatment sludge and oyster shell to evaluate their sorption characteristics. Heavy metals selected were cadmium, copper and lead. in the sorption experiments on the sewage treatment sludge, water treatment sludge, oyster shell and soil, sorption occurred in the beginning and it reached equilibrium after 40 minutes on the oyster shell and 4 hour on the sewage treatment sludge and water treatment sludge. Results of Freundlich isotherms indicated that sewage treatment sludge could be properly used as an adsorbent for heavy metals and sorption strength of heavy metals was in the order of Pb > Cu > Cd. In the influence of pH on the adsorbents, sorption rate was more than 80% in pH 4 and most of heavy metals were adsorbed in pH 9. Adsorption rate of Cd decreased with decreasing pH and then adsorption rate of Cu was lower in soil.

• 청정기술
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• 제19권4호
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• pp.423-429
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• 2013

본 연구의 목표는 폐자원인 굴패각과 석탄회, 굴착잔토를 이용하여 경제성 있는 무다짐용 유동성 뒷채움재를 개발하는데 있다. 굴패각을 생석회(CaO)로 전환하는데 고온($800^{\circ}C$ 이상)의 에너지가 필요하였지만, 생석회와 석탄회의 포즐란 반응에 의해 생성된 고화물 공시체의 일축압축강도는 높지 않았다. 생석회와 고령토 또는 고로슬래그의 반응 생성물 공시체의 압축 강도를 측정하였다. 실험결과로부터 포즐란 반응을 통한 고화물 생성은 경제성이 없는 것으로 판명되었다. 굴패각($CaCO_3$)과 석탄회를 잔골재 개념으로 그 사용 가능성을 검토하였다. 굴패각과 시멘트 혼합물이 석탄회와 시멘트 혼합물보다 높은 강도를 나타내었다. 굴패각에 포함된 염분으로 인하여 콘크리트에 혼입되는 굴패각 양을 제한하는 것을 고려한다면, 시멘트, 굴패각, 석탄회 혼합물이 좋은 뒷채움재로 사용될 수 있을 것으로 판단되었다. 추가적으로 흙을 첨가하는 경우 고화물의 일축압축강도가 감소하였지만 최적화된 혼합비에서 뒷채움재 기준(일축압축강도와 유동성)을 모두 만족하는 결과를 나타내었다. 본 연구결과는 시멘트, 굴패각, 석탄회, 굴착잔토의 배합비를 최적화함으로써 경제성 있는 뒷채움재를 개발할 수 있다는 것을 보여준다.

• 보존과학회지
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• 제34권4호
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• pp.295-303
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• 2018

The application of reinforcing agents with hydraulic property and strength development characteristics was studied under conditions similar to those of mural-painting mortar made with oyster shell powder. Reinforcement mortar made with oyster shell powder showed hydraulic properties and strength to supplement the weaknesses of natural hydraulic lime(NHL); this confirmed its possibility as a wall-reinforcing material with enough strength for preserving mural paintings. Reinforcement mortar 1 showed hydraulic property and general characteristics of lime mortar, such as consistency and viscosity, as well as lower strength and higher whiteness compared to an NHL product. For Reinforcement mortar 2, the original wall sample characteristics were reflected by mixing more shell produced through calcination; and it showed similar strength to that of Reinforcement mortar 1 as well as high whiteness. In measuring the contraction ratio of reinforcement mortar samples, Reinforcement mortar 1 and 2 showed more stability in property change compared to the NHL Group.

• 한국패류학회지
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• 제27권4호
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• pp.291-297
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• 2011

2008년 4월에 전남 고흥군 포두면 남성리 지선에서 바지락이 서식하기 어려운 니질의 양식장에 폐기물로 처리되는 굴 패각을 분쇄하여 넣어준 후, 2008년 6월에 울산 태화강에서 채취한 바지락 종패를 씨뿌림하여 양식 가능성 여부를 조사하였다. 조사해역 저질의 입도분석에서 굴 패각을 넣어준 시험구에서 대조구에 비하여 평균 입도와 평균 분급도는 증가한 것으로 나타났다. 또한 퇴적물에서도 산휘발성황화물 (AVS), 화학적 산소요구량 (COD), 강열감량 (IL), 함수율이 굴 패각 시험구에서 증가한 것으로 나타났다. 굴 패각을 이용한 바지락 양식장 저질개선 후, 2008년 6월에 평균 각장 21.00 mm, 전중량 1.86 g을 씨뿌림하였다. 23개월이 경과한 2010년 4월에 굴 패각 시험구에서는 각장 36.10 mm, 전중량 8.92 g으로 성장하였으며, 최종 생존율은 43.5%로 나타났다. 그러나 굴 패각을 넣지 않은 대조구에서는 13개월이 경과한 2009년 7월에 각장 32.62 mm, 전중량 7.34 g으로 성장은 빠르게 나타났으나, 모두 폐사하는 결과를 나타냈다.

• 한국환경보건학회:학술대회논문집
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• 한국환경보건학회 2005년도 국제학술대회
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• pp.365-370
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• 2005

The objective of this study is to develop the sorbent of oyster shell, which can remove gaseous acid pollutants emitted from the incinerator and power plants. The physicochemical properties of prepared absorbents have been measured using ICP and BET Also, this study is to investigate the Hydration/calcination reaction in the fixed bed reactor. Thus, the results could be summarized as follows. Oyster shell can be used in powder type without former processing. It should be also noted that sulfation reactivity of oyster sample increases to about 5 times by calcination/hydration reaction due to the increase of specific surface area and pore volume. From these experiments, we have found that both $SO_2$ and $NO_x$ in simulated flue gas can be effectively removed by use of oyster absorbent.

• 콘크리트학회논문집
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• 제15권2호
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• pp.280-287
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• 2003

산업폐기물 중 하나인 굴패각(Oyster Shell, OS)에 대한 건설재료로써의 활용성을 검토하기 위해 굴패각을 혼합한 콘크리트의 장기역학적 특성과 내구성을 실험적으로 평가하였다. 실험결과에 따르면 굴패각을 10% 대체한 콘크리트의 장기강도는 굴패각을 대체하지 않은 콘크리트와 유사한 결과를 보였으나, 굴패각을 20% 대체한 콘크리트의 장기강도는 감소하는 것을 보였다. 즉, 일정 한도 이상의 굴패각 대체는 콘크리트의 장기재령 강도에 열화요인으로 작용할 수 있는 것으로 나타났고, 굴패각의 대체에 따른 탄성계수 저하는 대체율에 거의 비례적으로 저하하였으며 굴패각의 대체율 20%에서 약 10∼15% 저하하였다. 굴패각의 대체율이 증가할수록 건조수축 발생량은 증가하였으며 기존의 건조수축과 크리프 모델식은 굴패각의 증가에 따른 영향을 잘 반영하지 못하였고 이에 대한 예측식의 보정이 필요하다. 잔골재의 일부를 굴패각으로 대체하여도 콘크리트의 동결융해 저항성, 탄산화 저항성, 및 화학침식 저항성에는 나쁜 영향을 미치지 않으며, 투수 저항성은 오히려 크게 개선되었다.

• 한국환경과학회지
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• 제11권12호
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• pp.1291-1298
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• 2002

To utilize coastal aquaculture ground bottom sediment in which concentrations of harmful pollutants are low and organic content is high as an organic fertilizer alkaline stabilizers such as CaO, Oyster shell, Mg(OH)$_2$ were added to the bottom sediment organic additives of livestock or food wastes. Nutritive qualities of crude fertilizers were measured to examine effects of alkaline stabilizers and organic waste additions. The Mg(OH)$_2$-added crude fertilizer had significantly lower total carbon(T-C) and nitrogen(T-N) content, reflecting the dilution effect due to great amount of Mg(OH)$_2$ addition. However, the addition of oyster shell had no significant effect on the T-C and T-N content of the fertilizer. $P_2O_5$ and $K_2$O content was considerably higher in the mixed sample of aquaculture ground bottom sediments and livestock wastes than in the mixture of the sediments and food wastes, resulting from higher $P_2O_5$ and $K_2$O content in livestock wastes. Addition of Mg(OH)$_2$ increased the content of MgO In the crude fertilizer but significantly reduced the content of other nutritive elements such as $P_2O_5$, $K_2$O and CaO. Addition of oyster shell as an alkaline stabilizer seemed to have the advantage of saving time and expenses far dryness due to its role as a modulator of water content. Moreover, additions of effect Mg(OH)$_2$ decreased the concentrations of heavy metals in the fertilizer by the dilution while additions of oyster shell had no influence on heavy metal concentrations in the fertilizer.

• 한국물환경학회지
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• 제20권5호
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• pp.437-446
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• 2004

To develop sewage treatment apparatus by natural purification method, the sewage treatment plant that consisted of aerobic and anaerobic plot was constructed. And then, the effects of treatment conditions on the removal of pollutants in the relation to sewage loading, sewage injection method and season according to the pebble kind. Removal rate of BOD and COD according to the sewage loading in effluent were over 95 and 77%, respectively. Removal rate of nitrogen in treated water by aerobic plot and effluent using sand were about 22~40 and 49~75%, respectively. Those of effluent using sand 75%+ oyster shell 25% and sand 50%+ oyster shell 50% as filter media in comparison with using sand were about 7~25 and 16~23%, respectively. Removal rate of phosphorus in treated water by aerobic plot and effluent using sand as filter media were about 30~36 and 52~56%, respectively. Those of effluent using sand 75%+ oyster shell 25% and sand 50%+ oyster shell 50% in comparison with using sand as filter media were about 11~40 and 12~45%, respectively. Removal efficiency of BOD and COD according to the intermittent injection method of sewage were slightly decreased, but those of nitrogen and phosphorus were little varied in comparison with continuous injection method. Removal efficiency of BOD and COD in winter in comparison with the others were little varied, but those of nitrogen and phosphorus slightly decreased.

• 한국환경과학회지
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• 제30권8호
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• pp.703-708
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• 2021

To improve the environmental management and resources, in this study, we aimed to investigate the effect of adding oyster shell powder to Hanwoo manure on its characteristics and microbial composition during the storage period. Additives were deposited on top of the manure surface at the rate of 0, 0.5, and 1% of oyster shell powder per 200 g of Hanwoo manure in a plastic container with three replicates; however, untreated manure litter served as the control. Manure characteristics (dry matter, organic matter and crude ash) and microbial composition (lactic acid bacteria, yeast, Bacillus subtilis, Salmonella, and E.coli) were evaluated at day 0, 2, 4, and 8. Manure characteristics exhibited an effect on dry matter, organic matter, and crude ash at day 2 and 8 (p<0.05), and not for day 0 and 4 (p>0.05). With the exception of yeast content at day 4 of storage, lactic acid bacteria, yeast, Bacillus subtilis, Salmonella, and E.coli exhibited no significant differences in all conditions during the storage period. Conclusively, addition of 1% oyster shell powder to Hanwoo manure resulted in slightly better manure characteristics; however, its microbial composition remained unchanged.