• Title/Summary/Keyword: Shear Rate

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Rheological Properties of Antiphlamine-S® Lotion (안티푸라민-에스® 로션의 레올로지 특성 연구)

  • Kuk, Hoa-Youn;Song, Ki-Won
    • Journal of Pharmaceutical Investigation
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    • v.39 no.3
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    • pp.185-199
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    • 2009
  • Using a strain-controlled rheometer [Advanced Rheometric Expansion System (ARES)], the steady shear flow properties and the dynamic viscoelastic properties of $Antiphlamine-S^{(R)}$ lotion have been measured at $20^{\circ}C$ (storage temperature) and $37^{\circ}C$ (body temperature). In this article, the temperature dependence of the linear viscoelastic behavior was firstly reported from the experimental data obtained from a temperature-sweep test. The steady shear flow behavior was secondly reported and then the effect of shear rate on this behavior was discussed in detail. In addition, several inelastic-viscoplastic flow models including a yield stress parameter were employed to make a quantitative evaluation of the steady shear flow behavior, and then the applicability of these models was examined by calculating the various material parameters. The angular frequency dependence of the linear viscoelastic behavior was nextly explained and quantitatively predicted using a fractional derivative model. Finally, the strain amplitude dependence of the dynamic viscoelastic behavior was discussed in full to elucidate a nonlinear rheological behavior in large amplitude oscillatory shear flow fields. Main findings obtained from this study can be summarized as follows : (1) The linear viscoelastic behavior is almostly independent of temperature over a temperature range of $15{\sim}40^{circ}C$. (2) The steady shear viscosity is sharply decreased as an increase in shear rate, demonstrating a pronounced Non-Newtonian shear-thinning flow behavior. (3) The shear stress tends to approach a limiting constant value as a decrease in shear rate, exhibiting an existence of a yield stress. (4) The Herschel-Bulkley, Mizrahi-Berk and Heinz-Casson models are all applicable and have an equivalent validity to quantitatively describe the steady shear flow behavior of $Antiphlamine-S^{(R)}$ lotion whereas both the Bingham and Casson models do not give a good applicability. (5) In small amplitude oscillatory shear flow fields, the storage modulus is always greater than the loss modulus over an entire range of angular frequencies tested and both moduli show a slight dependence on angular frequency. This means that the linear viscoelastic behavior of $Antiphlamine-S^{(R)}$ lotion is dominated by an elastic nature rather than a viscous feature and that a gel-like structure is present in this system. (6) In large amplitude oscillatory shear flow fields, the storage modulus shows a nonlinear strain-thinning behavior at strain amplitude range larger than 10 % while the loss modulus exhibits a weak strain-overshoot behavior up to a strain amplitude of 50 % beyond which followed by a decrease in loss modulus with an increase in strain amplitude. (7) At sufficiently large strain amplitude range (${\gamma}_0$>100 %), the loss modulus is found to be greater than the storage modulus, indicating that a viscous property becomes superior to an elastic character in large shear deformations.

Thermal conductivity measurements of non-Newtonian fluids in a shear field (전단력 영역에서의 비뉴톤 유체의 열전도율 측정)

  • Lee, Dong-Ryeol;Irvine, Thomas F.
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.5
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    • pp.584-595
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    • 1998
  • An investigation was carried out to determine experimentally the thermal conductivities of non-Newtonian fluids in a shear field. Both time independent purely viscous and viscoelastic fluids were considered. A coaxial cylinder apparatus with a rotating outer cylinder was used to establish the velocity field in the test fluid. First, the thermal conductivity of distilled water measured to validate the instrument. The experimental water data agreed within 1% of literature values and there was no effect of outer cylinder rotation (shear field). However, for non-Newtonian fluids such as aqueous CMC and Separan solutions, there were significant increases in thermal conductivities of up to 70% for CMC and 50% for Separan depending on the shear rate, polymer concentration and temperature. Considering the shear rate dependent thermal conductivity in the study of heat transfer in non-Newtonian fluids could be important. As in natural convection, the momentum and energy equations could no longer be solved separately but would have to be solved simultaneously.

Development of a Lift Correction Method for Shear Flow Effects in BEM Theory (BEM 이론을 위한 전단유동 효과 보정 기법 개발)

  • Lee, Kyung Seh;Jung, Chin Hwa;Park, Hyun Chul
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.57.2-57.2
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    • 2011
  • In this study, the effects of shear flows around a 2-dimensional airfoil, S809 on its aerodynamic characteristics were analyzed by CFD simulations. Various parameters including reference inflow velocity, shear rate, angle of attack, and cord length of the airfoil were examined. From the simulation results, several important characteristics were found. Shear rate in a flow makes some changes in the lift coefficient depending on its sign and magnitude but angle of attack does not have a distinguishable influence. Cord length and reference inflow also cause proportional and inversely proportional changes in lift coefficient, respectively. We adopted an analytic expression for the lift coefficient from the thin airfoil theory and proposed a modified form applicable to the traditional load analysis procedure based on the blade element momentum theory. Some preliminary results applied to an well known load simulation software, FAST, are presented.

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EFFECTS OF UNIFORM SHEAR STRESS ON THE MIGRATION OF VASCULAR ENDOTHELIAL CELL (균일한 전단응력에 의한 혈관내피세포의 운동성 변화)

  • Shin, Jennifer H.;Song, Suk-Hyun
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1404-1408
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    • 2008
  • The migration and proliferation of vascular endothelial cells (VEC), which play an important role in vascular remodeling, are known to be regulated by hemodynamic forces in the blood vessels. When shear stresses of 2, 6, 15 dynes/$cm^2$ are applied on mouse micro-VEC in vitro, cells surprisingly migrate against the flow direction at all conditions. While higher flow rate imposes more resistance against the cells, reducing their migration speed, the horizontal component of the velocity parallel to the flow increases with the flow rate, indicating the higher alignment of cells in the direction parallel to the flow at a higher shear stress. In addition, cells exhibit substrate stiffness and calcium dependent migration behavior, which can be explained by polarized remodeling in the mechanosensitive pathway under shear stress.

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Characterization and influence of shear flow on the surface resistivity and mixing condition on the dispersion quality of multi-walled carbon nanotube/polycarbonate nanocomposites

  • Lee, Young Sil;Yoon, Kwan Han
    • Carbon letters
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    • v.16 no.2
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    • pp.86-92
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    • 2015
  • Multi-walled carbon nanotube (MWCNT)/polycarbonate (PC) nanocomposite was prepared by direct melt mixing to investigate the effect of the shear rate on the surface resistivity of the nanocomposites. In this study, an experiment was carried out to observe the shear induced orientation of the MWCNT in the polymer matrix using a very simple melt flow indexer with various loads. The compression-molded, should be eliminated. MWCNT/PC nanocomposite sample exhibited lower percolation thresholds (at 0.8 vol%) and higher electrical conductivity values than those of samples extruded by capillary and injection molding. Shear induced orientation of MWCNT was observed via scanning electron microscopy, in the direction of flow in a PC matrix during the extrusion process. The surface resistivity rose with increasing shear rate, because of the breakdown of the network junctions between MWCNTs. For real applications such as injection molding and the extrusion process, the amount of the MWCNT in the composite should be carefully selected to adjust the electrical conductivity.

Rheological Study on bentonite Clay Sedimentation with various concentrations of Sea water (해수의 농도 변화에 따른 bentonite 침전에 대한 유변학적 고찰)

  • 최상원;서호준
    • Journal of Environmental Science International
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    • v.5 no.1
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    • pp.35-41
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    • 1996
  • For studying of coagulation and sedimentation in estuarine clay, we obtained several flow curves with various concentrations of sea water by using Coutte type rotational rheometer. The initial shear stress on high concentration of sea water was observed big, but after this, its value is decreasing with increasing shear rate. The maximum pick of shear stress is decreasing with the decreasing of concentration of sea water The trend is same totally above for viscosity. The sedimentation times with the concentration of sea water vary in $\infty$ ~ 5 minutes. The zeta potential is changed dramatically between 114 and 118 concentration of sea water. That is consistent with the sedimentation graph. From these results, the phenomena of coagulation and sedimentation can be explained with viscoelastic terms on structual formation among particles by the changes of surface potential affected from contacting sea water to dispersed particles.

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Penetration behavior of biopolymer aqueous solutions considering rheological properties

  • Ryou, Jae-Eun;Jung, Jongwon
    • Geomechanics and Engineering
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    • v.29 no.3
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    • pp.259-267
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    • 2022
  • The rheological and penetration characteristics of sodium alginate and xanthan gum aqueous solutions were analyzed for the development of biopolymer-based injection materials. The results of viscosity measurements for the rheological characteristics analysis show that all aqueous biopolymer solutions exhibit a tendency for shear-thinning, i.e., the apparent viscosity decreases as the shear rate increases. In addition, a regression analysis using several models (Power-law, Casson, Sisko, and Cross) was applied to the shear-thinning fluid analysis results, the highest accuracy was determined by applying the power-law model. The micromodel experiment for the penetration characteristics analysis determined that all biopolymer aqueous solutions show higher pore saturation than water, and that pore saturation tends to increase as the flow rate and concentration increases. When comparing the rheological and penetration characteristics of the biopolymer aqueous solution used in this study, the xanthan gum aqueous solution showed a fully developed shear-thinning tendency, unlike the sodium alginate aqueous solution. This tendency is considered to have the advantage of enhancement injectability and pore saturation.

The Non Newtonian Flow Mechanism and Rheological Properties of Polyurethane Melts (용융 폴리우레탄의 비 뉴톤 유동 메카니즘과 유변학적인 성질)

  • Kim, Nam-Jeong
    • Elastomers and Composites
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    • v.44 no.4
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    • pp.423-428
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    • 2009
  • The non-Newtonian flow curves of polyurethane melts were obtained by using a Physica cone-plate rheometer at various temperatures. The rheological parameters were obtained by applying non-Newtonian flow equation to the flow curves for polyurethane samples. When the polyurethane samples are under increasing-decreasing shear rate modes, the hysteresis loop and thixotropic behavior were shown. Polyurethane melts behave as strong gels when they are subjected to shear flow, but when the applied stress surpasses the yield stress, they exhibit non-linear viscoelasticity. Upon decreasing shear rate, its shear stress remains smaller than the values measured in the increasing shear rate mode, because of broken of its structure.

Effects of Clearance on the Formation of Adiabatic Shear Band in Stepped Specimen (계단시편의 간극이 단열전단밴드의 형성에 미치는 영향)

  • Yoo, Y.H.;Jeon, G.Y.;Chung, D.T.
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.7 s.94
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    • pp.1700-1709
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    • 1993
  • The stepped specimen which is subjected to step loading is modeled to study the initiation and growth of adiabatic shear band using explicit time integration finite element method. Three different clearance sizes are tested. The material model for the stepped specimen includes effects of strain hardening, strain rate hardening and thermal softening. It is found that the material inside the fully grown adiabatic shear band experiences three phase of deformation, (1) homogeneous deformation phase, (2) initiation/incubation phase, and (3) fast growth phase. The second phase of deformation is initiated after sudden shear stress drop which occurs at the same time regardless of the clearance size. The incubation time prior to fast growth phase increases, as the clearance size of the stepped specimen increases. Whereas, after incubation period, the growth rate of the adiabatic shear band decreases, as the clearance size decreases. It is also found that two adiabatic shear band may develop instead of one for the smaller clearance size.

Non-Invasive Measurement of Shear Rates of Pulsating Pipe Flow Using Echo PIV (에코 PIV를 이용한 맥동 유동에서의 in vitro 전단률 측정 연구)

  • Kim, Hyoung-Bum;Chung, In-Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.12
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    • pp.1567-1572
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    • 2004
  • Although accurate measurement of velocity profiles, multiple velocity vectors, and shear stress in arteries is important, there is still no easy method to obtain such information in vivo. This study shows the utility of combining ultrasound contrast imaging with particle image velocimetry (PIV) for non-invasive measurement of velocity vectors. The steady flow analytical solution and optical PIV measurements (for pulsatile flow) were used for comparison. When compared to the analytical solution, both echo PIV and optical PIV resolved the steady velocity profile well. Error in shear rate as measured by echo PIV (8%) was comparable to the error of optical PIV (6.5%). In pulsatile flow, echo PIV velocity profiles agreed well with optical PIV profiles. Echo PIV followed the general profile of pulsatile shear stress across the artery but underestimated wall shear at certain time points. These studies indicate that echo PIV is a promising technique for the non-invasive measurement of velocity profiles and shear stress.