• Proceedings of the Korea Water Resources Association Conference
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• 2007.05a
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• pp.8-14
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• 2007

Water quality in Lake Rotorua, New Zealand, deteriorated since the 1960s because of excessive phytoplankton growths due principally to increasing nitrogen and phosphorus in the lake waters. Nutrient concentrations in eight of the nine major streams feeding Lake Rotorua have increased since 1965. The groundwater system has a key role in the hydrology of the Lake Rotorua catchment and the groundwater system is probably the control on the time delay between intensification of agricultural land use and response of surface water quality. All major, and many minor streams, in the catchment are fed by springs. Two lithological units are most important to groundwater flow in the Lake Rotorua catchment: Mamaku Ignimbrite, erupted in about 200,000 years ago and Huka Formation sediments which filled the caldera left by the Mamaku Ignimbrite eruption. Rainfall recharge to groundwater in the groundwater catchment of Lake Rotorua is estimated as approximately 17300 L/s. A calibrated steady-state groundwater flow model estimates that approximately 11100 L/s of this flow discharges into streams and then into the lake and the balance travels directly to Lake Rotorua as groundwater discharge through the lake bed. Land use has impacted on groundwater quality. Median Total Nitrogen (TN) values for shallow groundwater sites are highest for the dairy land use (5.965 mg/L). Median TN values are also relatively high for shallow sites with urban-road and cropping land uses (4.710 and 3.620 mg/L, respectively). Median TN values for all other uses are in the 1.4 to 1.5 mg/L range. Policy development for Lake Rotorua includes defining regional policies on water and land management and setting an action plan for Lake Rotorua restoration. Aims in the action plan include: definition of the current nutrient budget for Lake Rotorua, identification of nutrient reduction targets and identification of actions to achieve targets. Current actions to restore Lake Rotorua water quality include: treatment of Tikitere geothermal nitrogen inputs to Lake Rotorua, upgrade of Rotorua City sewage plant, new sewage reticulation and alum dosing in selected streams to remove phosphorus.

• Journal of Korea Water Resources Association
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• v.49 no.11
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• pp.923-930
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• 2016

This study was to evaluate the stream depletion from groundwater pumping in shallow aquifer using the Hunt's analytical solution (2009) which considers a two-layer leaky aquifer-stream system. From the total 2,187 cases of simulations with combinations of various aquifer and stream properties, the streamflow depletion rates divided by the groundwater pumping rate showed the low values when the stream depletion factor (SDF) is higher than 1,000-10,000, and was more sensitive to the aquitard hydraulic conductivity than the streambed hydraulic conductivity. The comparison of the Hunt's solution (2009) with the Hunt's solution (1999) of a single layer aquifer indicated that the maximum difference between the dimensionless stream depletions calculated by using both solutions is above 0.3, and the stream depletion is significantly affected by the hydraulic properties of the $2^{nd}$ layer as the SDF of the first layer increases. The Hunt's solution (2009) was applied to the real shallow groundwater well that is located in Chunju-Si, and the results revealed that the groundwater pumping has significant effects on streamflow in a short period of time, showing that the dimensionless stream depletion exceeds 0.8 within a few days. It was also found that the shallow groundwater pumping effects on stream depletion are highly dependent on the stream-well distance for the locations with high hydraulic diffusivity of $1^{st}$ layer and low vertical leakance between $1^{st}$ and $2^{nd}$ layers.

• Proceedings of the KSEEG Conference
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• 2003.04a
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• pp.99-102
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• 2003

Shallow groundwater systems are highly vulnerable to anthropogenic contamination and are characterized by a variety of redox condition. The redox state is a key parameter to control the nitrate contamination which is related to nitrification or denitrification processes. In relation to the control of nitrate problem, it is very important to understand the source, transport and fate of nitrogen compounds in a groundwater system. (omitted)

• Journal of the Korean earth science society
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• v.41 no.6
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• pp.630-646
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• 2020

In rural areas, nitrate-nitrogen (NO3-N) pollution caused by agricultural activities is a major obstacle to the use of shallow groundwater as domestic water or drinking water. In this study, the water quality characteristics of shallow groundwater in Hyogyo-ri agricultural area of Yesan-gun, Chungcheongnam-do province was studied in connection with land use and chemical composition of soil layer. The average NO3-N concentration in groundwater exceeds the domestic and agricultural standard water qualities of Korea and is caused by anthropogenic sources such as fertilizer, livestock wastewater, and domestic sewage. The groundwater type mainly belongs to Ca(Na)-Cl type, unlike Ca-HCO3 type, a general type of shallow groundwater. The average NO3-N concentration (7.7 mg L-1) in groundwater in rice paddy/other (upstream, ranch, and residential) area is lower than the average concentration (22.8 mg L-1) in farm field area, due to a lower permeability in paddy area than that in farm field area. According to the trend analysis by the Mann-Kendall and Sen tests, the NO3-N concentration in the shallow groundwater shows a very weak decreasing trend with ~0.011 mg L-1yr-1 with indicating almost equilibrium state. Meanwhile, SO42- and HCO3- concentrations display annual decreasing trend by 15.48 and 13.15%, respectively. At a zone of 0 to 5 m below the surface, the average hydraulic conductivity is 1.86×10-5 cm s-1, with a greater value (1.03×10-4cm s-1) in sand layer and a smaller value (2.50×10-8 cm s-1) in silt layer.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.10a
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• pp.152-154
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• 2005

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.09a
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• pp.119-120
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• 2004

Urban groundwater has a unique hydrologic system because of the complex surface and subsurface infrastructures such as deep foundation of many high buildings, subway systems, and sewers and public water supply systems. It generally has been considered that increased surface impermeability reduces the amount of groundwater recharge. On the other hand, leaks from sewers and public water supply systems may generate the large amounts of recharges. All of these urban facilities also may change the groundwater quality by the recharge of a myriad of contaminants. This study was performed to determine the factors controlling the recharge of deep groundwater in an urban area, based on the hydrogeochemical characteristics. The term ‘contamination’ in this study means any kind of inflow of shallow groundwater regardless of clean or contaminated. For this study, urban groundwater samples were collected from a total of 310 preexisting wells with the depth over 100 m. Random sampling method was used to select the wells for this study. Major cations together with Si, Al, Fe, Pb, Hg and Mn were analyzed by ICP-AES, and Cl, N $O_3$, N $H_4$, F, Br, S $O_4$and P $O_4$ were analyzed by IC. There are two groups of groundwater, based on hydrochemical characteristics. The first group is distributed broadly from Ca-HC $O_3$ type to Ca-C1+N $O_3$ type; the other group is the Na+K-HC $O_3$ type. The latter group is considered to represent the baseline quality of deep groundwater in the study area. Using the major ions data for the Na+K-HC $O_3$ type water, we evaluated the extent of groundwater contamination, assuming that if subtract the baseline composition from acquired data for a specific water, the remaining concentrations may indicate the degree of contamination. The remainder of each solute for each sample was simply averaged. The results showed that both Ca and HC $O_3$ represent the typical solutes which are quite enriched in urban groundwater. In particular, the P$CO_2$ values calculated using PHREEQC (version 2.8) showed a correlation with the concentrations of maior inorganic components (Na, Mg, Ca, N $O_3$, S $O_4$, etc.). The p$CO_2$ values for the first group waters widely ranged between about 10$^{-3.0}$ atm to 10$^{-1.0}$ atm and differed from those of the background water samples belonging to the Na+K-HC $O_3$ type (<10$^{-3.5}$ atm). Considering that the p$CO_2$ of soil water (near 10$^{-1.5}$ atm), this indicates that inflow of shallow water is very significant in deep groundwaters in the study area. Furthermore, the P$CO_2$ values can be used as an effective parameter to estimate the relative recharge of shallow water and thus the contamination susceptibility. The results of our present study suggest that down to considerable depth, urban groundwater in crystalline aquifer may be considerably affected by the recharge of shallow water (and pollutants) from an adjacent area. We also suggest that for such evaluation, careful examination of systematically collected hydrochemical data is requisite as an effective tool, in addition to hydrologic and hydrogeologic interpretation.ion.ion.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2000.11a
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• pp.232-236
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• 2000

Multi-regression statistical analyses were applied for the water quality data of shallow alluvial ground water (n = 47) collected from the Youngdeok area, in order to quantitatively generalize the natural (non-anthropogenic) causes of regional water quality variation. Seven samples having the high contamination index ( $C_{a}$ > 3) reflect the striong effects by anthropogenic activity. Most of the alluvial groundwaters have acquired their quality primarily due to the dissolution of carbonate minerals. The results of multi-regression analysis show that chlorine is mainly derived from seawater effect. Sulfur isotopic compositions of dissolved sulfur and the S $O_4$/Cl ratio also enable us to discriminate the samples (n = 18) which are affected by atmospheric input of marine aerosol (sea-spray) and also by mixing between freshwater and seawater. Hydrogen and oxygen isotope data of the samples collected lie close to the local meteoric water line obtained from nearby Pohang city but has lower slope (5.45) on the $\delta$D-$^{18}$ O plot, indicating that alluvial groundwater was recharged from infiltrated meteoric water which has undergone some degree of kinetic evaporation. The estimated initial isotopic composition of the recharged water ($\delta$D = -74.8$^{0}$ /$_{00}$, $\delta$$^{18}$ O = -10.8$^{[-1000]}$ /$_{[-1000]}$ ) suggests that the alluvial ground water recharge largely occurs during summer storm events.s.s.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2006.04a
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• pp.303-306
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• 2006

Using a variety of chemical geothermometers we estimate the temperature of a deep geothermal reservoir in relation to thermal groundwater in the Bugok area, southern Korea, in order to assess the potential use of geothermal energy in South Korea. Thermal water at Bugok has been exploited down to about 400 m below the land surface and shows the highest outflow temperatures (up to $78{\circ}C$) in South Korea. Based on the hydrochemical data and occurrence, groundwater in Bugok can be classified into three groups: $Na-SO_4$ type thermal groundwater (CTGW) occurring in the central part (about 0.24 $km^2$) $Ca-HCO_3$ type cold groundwater (SCGW) occurring in shallow peripheral parts of CTGW; and the intermediate type groundwater (STGW). CTGW waters are typical of thermal water in the area, because they have the highest outflow temperatures and contain very high concentrations of Na, K and $SiO_2$ due to the sufficient reaction with silicate minerals in deep reservoir. Their enriched $SO_4$ was likely formed by gypsum dissolution. The major ion composition of CTGW shows the general approach to a partial equilibrium state with rocks at depth. The application of various alkali ion geothermometers yields temperature estimates in the range of 88 to $198{\circ}C$ for the thermal reservoir. Multiple mineral equilibrium calculation indicates asimilar but narrower temperature range between about 100 and $155{\circ}C$. These temperature estimates are not significantly higher than the measured outflow temperatures for CTGW Considering the heat loss during the ascent- of thermal waters, this fact may suggest that a thermal reservoir in the study area is likely located at relatively shallow depths (possibly close to the depth of preexisting wells). Therefore, we suggest a high potential for geothermal energy development around the Bugok area in southern Korea.

• Journal of Soil and Groundwater Environment
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• v.8 no.1
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• pp.57-67
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• 2003

Nitrate contamination by human activities is a serious problem to water-supply in agricultural area. Shallow groundwater is the main source of water-supply, but it is very sensitive to contamination. Study area for nitrate contamination is a region of Iljuk, Kyunggi where is an agricultural area having many livestock facilities in various scales. As a result, the points having availability of incoming of external contaminant are 77%, and the ones over the Drinking Water Limit (DWL) are 32～42%. For a nitrogen isotope analysis, all the points having availability of incoming of external contaminant have $\delta$$^{15}$ N-NO$_3$ values over 5$\textperthousand$, and the points of 59% are strongly affected by nitrogen originated from animal wastes. The major source of nitrate in this area is intensive livestock facilities. Even though a livestock facility had enclosed, it affects groundwater quality for a long time. The chemical property of contaminant source is various according to animal species in surface water, but not in groundwater since some solutes are removed by reactions during an inflow to subsurface.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 2001.10a
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• pp.479-483
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• 2001

This Study was carried out to know the soil properties and the quality of shallow groundwater in the plastic film house fields around mid-Korea. This study was conducted at 11 sites in Suweon, Pyungtaek, Yongin, and Chunchen on May, June, July and August in 1999. The the average concentration of nitrate-nitrogen was 19.1 mg/L, it reached almost to the limiting level, 20 mg/L. Moreover about 36.4% of survey sites exceeded limiting level to agricultural groundwater quality. And Sulfur concentrations also at some sites exceeded to agricultural groundwater quality limit level (50 mg/L), which could make damage to the crop. Nitrate-nitrogen, which is one of the most important factors in the groundwater quality, It has highly positive correlation with any other ion in groundwater. This result showed that groundwater quality management practices should be taken for the agricultural production as well as for environment at the plastic film house areas.