• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.12
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• pp.8665-8672
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• 2015

In this study, to investigate the feasibility of malodorous substance and organic matter removal by digest sludge in sewage treatment plants, ammonia, methyl mercaptan(MMC), and hydrogen sulfide($H_2S$) in a reactor submerged with BIO-CLOD(BIO-CLOD) and a reactor not submerged with BIO-CLOD(Non BIO-CLOD) were measured at 24 hours, 48 hours, and 72 hours after the submergence of BIO-CLOD. Whereas the reactor in which BIO-CLOD was submerged showed an ammonia removal rate of 48% and high $H_2S$ and MMC removal rates exceeding 98% in 24 hours, the reactor in which BIO-CLOD was not submerged showed an ammonia removal rate of 45%, an $H_2S$ removal rate of 71%, and an MMC removal rate of 84% in 24 hours indicating the possibility of removal of malodor using BIO-CLOD. A nitrification was shown in which ammonia concentrations decreased over time while nitrate nitrogen concentrations increased and sulfur based malodor components were oxidation decomposed indicating that BIO-CLOD had effects to increase sulfate concentrations in the solution and that sulfate concentration increases and atmospheric $H_2S$ removal rates were correlated with each other. With regard to decreases in organic matter in reactor effluents, BIO-CLOD did not affect in a short period of time and when reactors were operated with HRT 12 hours and HRT 24 hours, HRT 12 hours was considered desirable in terms of economy.

• Journal of Environmental Science International
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• v.20 no.5
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• pp.589-598
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• 2011

Milyanggang mid-watershed is located in downstream of Nakdong river basin. The pollutants from that watershed have an direct effect on Nakdong river water quality and it's control is important to manage a water quality of Nakdong river. A target year of Milyanggang mid-watershed water environment management plan is 2013. To predict a water quality at downstream of Milyang river, we have investigated and forecasted the pollutant source and it's loading. There are some plan to construction the sewage treatment plants to improve the water quality of Milyang river. Those are considered on predicting water quality. As results, it is shown that the population of Milyanggang mid-watershed is 131,857 and sewerage supply rate is 62.2% and the livestock is 1,775.300 in 2006. It is estimated that the population is 123,921, the sewerage supply rate is 75.5% in 2013. The generated loading of BOD and TP is 40,735 kg/day and 2,872 kg/day in 2006 and discharged loading is 11,818 kg/day and 722 kg/day in 2006 respectively. Discharged loadings were forecasted upward 1.0% of BOD and downward 2.7% of TP by 2013. The results of water quality prediction of Milyanggang 3 site were 1.6 mg/L of BOD and 0.120 mg/L of TP in 2013. It is over the target water quality at that site in 2015 about 6.7% and 20.0% respectively. Consequently, there need another counterplan to reduce the pollutants in that mid-watershed by 2015.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.3
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• pp.162-166
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• 2011

Phosphorous contaminated in the effluent from sewage treatment plants can cause the eutrophication in surface water bodies. In this study, a powder of titanium oxysulfate-sulfuric acid made of ion-exchange materials was immobilized in an alginate gel and this material was examined to evaluate its phosphorous removal efficiency. Equilibrium and kinetic studies were carried out to quantify the adsorption capacity and time dependent removal rate of phosphorous. Adsorption isotherms and kinetic parameters were obtained for the entrapped titanium beads with three different methods. Equilibrium data were analyzed using Langmuir adsorption isotherm model and found to be well fitted to the model. The maximum adsorption capacity for phosphorous by the titanium bead synthesized with the solution method was 92.26 mg/g. Kinetic data followed a pseudo-second-order kinetic model. Due to the low production cost and high adsorption capacity, the titanium bead synthesized by the solution method has a potential to be utilized for the cost-effective removal of phosphorous from wastewater.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.6
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• pp.451-459
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• 2014

The development and reduction scheme under implementation plan of TMDLs were performed in the Jinwi watershed including 8 cities (Gunpo, Yongin, Suwon, Anseong, Osan, Uiwang, Pyeongtaek and Hwaseong) since 2012. Progress of the annual development schemes was faster than the reduction schemes in most of the cities during the planning period. Main load reduction methods included establishment and enlargement of sewage treatment plants, resources of livestock excretions, and introduction of best management practices of non-point source pollution. Especially, reduction load using recycling and composting of livestock excretions comprised 34.1% of all reduction load. It is necessary to implement methodical development and reduction scheme for making of successful performance of TMDLs and water quality improvement in the Jinwi watershed.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.2
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• pp.84-93
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• 2013

The aims of this study were to investigate and confirm the occurrence and distribution patterns of perfluorinated compounds (PFCs) in Nakdong River basin (mainstream and its tributaries). 7 (PFOS, PFHpA, PFOA, PFNA, PFDA, PFUnDA and PFDoDA) out of 11 PFCs were detected in 29 sampling sites and PFOA and PFHpA were predominant compounds in upstream, but PFUnDA, PFDoDA and PFOS were predominant compounds in middle stream of Nakdong River basin. The total concentration levels of PFCs on February 2009 and on August 2009 in surface water samples ranged from 4.3. to 1168.2 ng/L and 16.4 to 627.8 ng/L, respectively. The highest concentration level of PFCs in the mainstream and tributaries in Nakdong River were Goryeong and Jincheon-cheon, respectively. The sewage treatment plants (STPs) along the river affect the PFCs levels in river and the PFCs levels decreased with downstream because of dilution effects.

• Journal of Wetlands Research
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• v.23 no.4
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• pp.296-306
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• 2021

Elasticity is a statistical technique that interprets the changing pattern of another variable according to a change in one variable as a quantitative numerical value and provides more information than correlation analysis and is widely used in climate change research. In this study the elasticity was calculated and sensitivity analysis was performed using air temperature and water quality data of the major tributaries of the Nakdong River. In addition the confidence interval for the elasticity was calculated using the T-Test and the validity of the elasticity was examined. The strength of elasticity shows high strength in the order of summer>fall>spring>winter and the direction shows regional characteristics with both negative and positive elasticity. After performing hierarchical cluster analysis on monthly observation data they were classified into 5 clusters and the characteristics of each cluster were visually analyzed using a parallel coordinate graph. The direction and intensity of the air temperature elasticity show regional characteristics due to the relatively high population density and complex influencing factors such as sewage treatment plants, small-scale livestock houses and agricultural activities. In the case of TP it shows great regional variability according to the circulation of nutrients in the ecosystem caused by algae growth and death according to temperature changes. Since the air temperature elasticity of the major tributaries of the Nakdong River is over weak and is valid at the significance level of 5%, it was analyzed that there is a change in water quality according to the air temperature change.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.7
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• pp.708-718
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• 2020

Offensive odor is recognized as a social environmental problem due to its olfactory effects. Ammonia(NH₃), hydrogen sulfide(H₂S) and benzene(C₆H₆) are produced from various petrochemical plants, public sewage treatment plants, public livestock wastes, and food waste disposal facilities in large quantities. Therefore efficient decomposition of offensive odor is needed. In this study, the removal efficiency of atmospheric-pressure plasma operating at an ambient condition was investigated by evaluating the concentrations at upflow and downflow between the plasma reactor. The decomposition of offensive odor using plasma is based on the mechanism of photochemical oxidation of offensive odor using free radical and ozone(O₃) generated when discharging plasma, which enables the decomposition of offensive odor at ordinary temperature and has the advantage of no secondary pollutants. As a result, all three odor substances were completely decontaminated within 1 minute as soon as discharging the plasma up to 500 W. This result confirms that high concentration odors or mixed odor materials can be reduced using atmospheric-pressure plasma.

• Journal of Wetlands Research
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• v.25 no.2
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• pp.99-110
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• 2023

Non-point source (NP) pollutants in an agricultural landuse are discharged from a large area compared to those in other land uses, and thus effective source control measures are needed. To develop appropriate control measures, it is necessary to quantify discharge load of each source and evaluate the degree of water quality improvement by implementing different options of the control measures. This study used Hydrological Simulation Program-FORTRAN (HSPF) to quantify pollutant discharge loads from different sources and effects of different control measures on water quality improvements, thereby supporting decision making in developing appropirate pollutant control strategies. The study area is the Gyeseong river watershed in Changnyeong county, Gyeongsangnam-do, with agricultural areas occupying the largest proportion (26.13%) of the total area except for the forest area. The main pollutant sources include chemical and liquid fertilizers for agricultural activities, and manure produced from small scale livestock facilities and applied to agriculture lands or stacked near the facilities. Source loads of chemical fertilizers, liquid fertilizers and livestock manure of small scale livestock facilities, and point sources such as municipal wastewater treatment plants (WWTPs), community WWTPs, private sewage treament plants were considered in the HSPF model setup. Especially, NITR and PHOS modules were used to simulate detailed fate and transport processes including vegitation uptake, nutrient deposition, adsorption/desorption, and loss by deep percolation. The HSPF model was calibrated and validated based on the observed data from 2015 to 2020 at the outlet of the watershed. The calibrated model showed reasonably good performance in simulating the flow and water quality. Five Pollutants control scenarios were established from three sectors: agriculture pollution management (drainge outlet control, and replacement of controlled release fertilizers), livestock pollution management (liquid fertilizer reduction, and 'manure management of small scale livestock facilities) and private STP management. Each pollutant control measure was further divided into short-term, mid-term, and long-term scenarios based on the potential achievement period. The simulation results showed that the most effective control measure is the replacement of controlled release fertilizers followed by the drainge outlet control and the manure management of small scale livestock facilities. Furthermore, the simulation showed that application of all the control measures in the entire watershed can decrease the annual TN and TP loads at the outlet by 40.6% and 41.1%, respectively, and the annual average concentrations of TN and TP at the outlet by 35.1% and 29.2%, respectively. This study supports decision makers in priotizing different pollutant control measures based on their predicted performance on the water quality improvements in an agriculturally dominated watershed.

• Journal of the Korean Wood Science and Technology
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• v.48 no.4
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• pp.472-487
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• 2020

With the emergence of abnormal climate due to the rapid industrialization, the importance of water quality management and management costs are increasing every year. In Korea, for the management of total phosphorus and total nitrogen, the major materials causing the water quality pollution, coagulants are injected in sewage treatment plants to process organic compounds. However, if the coagulant is injected in an excessive amount to PAC (Poly Aluminium Chloride), a secondary pollution problem might occur. As such, a study on the applicability of natural material-based coagulant is being conducted in Korea. Thus, this study aimed to evaluate the applicability of a mixed coagulant developed by analyzing water quality pollutants T-P, T-N as well as their turbidity, in order to derive the optimum mixing ratio between PAC and torrefied wood flour for the primary settling pond effluent. Under the condition where the content of PAC (10%) and torrefied wood flour is 1%, T-P showed the maximum removal efficiency of 92%, and T-N showed approximately 22%. This indicates that removal of T-N which includes numerous positively charged organic compounds that are equivalent to mixed coagulant is not well accomplished. Turbidity showed the removal efficiency of approximately 91%. As such, 1% of torrefied wood flour was determined to be the optimum addition. As a result of analyzing the removal efficiency for organic compounds by reducing PAC concentration to 7%, T-P showed a high maximum removal efficiency of 91%, T-N showed 32%, and turbidity showed the maximum of 90%. In addition, a coagulation process is performed by using the mixed coagulant based on 1% content of torrefied wood flour produced in this study by performing a coagulation performance comparative experiment with PAC (10%). As a result, PAC concentration was reduced to 30-50%, a similar performance with other coagulants in market was secured, PAC injection amount was reduced that an economic effect can be achieved, and it is considered to perform a stable water treatment that reduces the secondary pollution problem.

• Korean Journal of Environmental Agriculture
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• v.36 no.3
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• pp.154-160
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• 2017

BACKGROUND:This study was carried out to establish an efficient sample preparation for the simultaneous determination of bisphenols (BPs) in river water samples using gas chromatography-mass spectrometry (GC-MS). Sample preparation was examined with conventional extraction methods, such as solid-phase extraction (SPE) and liquid-liquid extraction (LLE), and their efficiency was compared with validation results, including linearity of calibration curve, method detection limit (MDL), limit of quantification (LOQ), accuracy, and precision. METHODS AND RESULTS:The BPs (bisphenol A, BPA; bisphenol B, BPB; bisphenol C, BPC; bisphenol E, BPE; bisphenol F, BPF; bisphenol S, BPS) were analyzed using GC-MS. The range of MDLs by SPE and LLE methods was $0.0005{\sim}0.0234{\mu}g/L$ and $0.0037{\sim}0.2034{\mu}g/L$, and that of LOQs was $0.0015{\sim}0.0744{\mu}g/L$ and $0.0117{\sim}0.6477{\mu}g/L$, respectively. The calibration curve obtained from standard solution of $0.004{\sim}4.0{\mu}g/L$ (SPE) and $0.016{\sim}16{\mu}g/L$ (LLE) showed good linearity with $r^2$ value of 0.9969 over. Accuracy was 93.2~108% and 97.4~120%, and precision was 1.7~4.6% and 0.7~6.5%, respectively. The values of MDL and LOQ resulted from the SPE method were higher than those from the LLE method, particularly those values of BPA were highest among the BPs. Based on the results, the SPE method was applied to determine the BPs in river water samples. Water samples were collected from mainstream, tributary and sewage wastewater treatment plants (SWTPs) in the Yeongsan river basin. The concentration of BPB, BPC, BPE, BPF and BPS were not detected in all sites, whereas BPA was ranged $0.0095{\sim}0.2583{\mu}g/L$, which was $0.0166{\sim}0.0810{\mu}g/L$ for mainstreams, $0.0095{\sim}0.2583{\mu}g/L$ for tributaries, $0.0352{\sim}0.1217{\mu}g/L$ for SWTPs. CONCLUSION: From these results, the SPE method was very effective for the simultaneous determination of BPs in river water samples using GC-MS. We provided that it is a convenient, reliable and sensitive method enough to monitor and understand the fate of the BPs in aquatic ecosystems.