• 제목/요약/키워드: Sequential degradation

검색결과 85건 처리시간 0.026초

아드만탄 기반의 새로운 설포네이트 폴리카보네이트 난연제 성능 연구 (Performance of a Novel Sulfonate Flame Retardant Based on Adamantane for Polycarbonate)

  • Guo, Jianwei;Wang, Yueqin;Feng, Lijuan;Zhong, Xing;Yang, Chufen;Liu, Sa;Cui, Yingde
    • 폴리머
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    • 제37권4호
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    • pp.437-441
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    • 2013
  • A novel sulfonate flame retardant, 1,3,5,7-tetrakis(phenyl-4-sodium sulfonate)adamantane (FR-A), was successfully synthesized from 1-bromoadamantane in sequential four-step reactions involving Fiedel-Crafts phenylation, sulphonation, hydrolysis, and neutralization. The success of synthesis was confirmed by FTIR spectra, $^1H$ NMR spectra, elemental analyses and mass spectra. The effect of FR-A on the flame retardacy of polycarbonate (PC) has been studied. Limiting oxygen index (LOI) and thermogravimetric analysis (TGA) showed that this novel sulfonate flame retardant had effective flame retardancy on polycarbonate (PC). With a small amount (0.08 wt%) of FR-A, the flame retardancy of PC was improved obviously, which got to UL 94 V-0 rating. TGA and DTA curves demonstrated that the additive raised the degradation rate of PC by promoting the quick formation of an insulating carbon layer on the surface, and confirmed that the flame retardant mechanism of PC/FR-A system was similar to potassium diphenylsulfone sulfonate (KSS).

중복 패리티 이미지 제거를 통한 RAID 5에서의 패리티 로킹 기법 성능 개선 (Performance Improvement of Parity Logging Scheme in RAID 5 by Eliminating Redundant Parity Image)

  • 길준호;이민영;이진호;박명순
    • 한국정보처리학회논문지
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    • 제2권4호
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    • pp.543-553
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    • 1995
  • RAID 5는 높은 성능과 신뢰성을 가지고 다양한 응용 분야에서 사용되지만 쓰기 작업시 성능이 저하되는 문제를 가지고 있다. 이러한 문제를 완화하기 위하여 패리티 로깅(parity logging) 기법이 제시된 바있다. 패리티 로깅 기법은 디스크로의 작은 크 기의 임의의 블럭 단위 접근들을 큰 크기의 순차적인 트랙 단위 접근으로 변환하여 디스크 처리 시간을 줄이는 방법이다. 본 논문에서는 패리티 로깅 기법에서 디스크 버 퍼의 패리티 이미지 중복 저장을 제거하여 패리티 갱신 오버헤드를 줄이는 방법을 설 명하고 그에 대한 간략한 분석 모델과 시률레이션 결과를 제시하였다.

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The Microcosm study for evaluating biobarrier application on sequential degradation of TCE products by Gasoline-Degradaing Mixed Culture

  • Lee, Jae-Sun;Lee, Si-Jin;Lee, Young-Kee;Chang, Soon-Woong
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2003년도 생물공학의 동향(XIII)
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    • pp.440-444
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    • 2003
  • 본 연구에서는 난분해성 물질인 액상의 TCE가 영가철 표면에서 반응시 완전히 분해가 되지 않은 상태에서 생성되어지는 부산물인 Cis-DCE와 VC의 톨루엔 분해균주에 의한 처리 가능성을 회분식 실험으로 관찰하였다. 각각 2ppm의 Cis-DCE와 VC에 톨루엔 균주를 주입한 결과 1차기질로 톨루엔을 사용하고 그후에 Cis-DCE와 VC를 제거 하는 것으로 나타났다. 또한 동시에 주입시 1차기질로 톨루엔을 사용하는 것은 동일하나 VC를 먼저 사용하고 그후에 Cis-DCE를 제거하며 제거 속도 또한 줄여드는 것으로 나타났다.

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삼각형 격자를 갖는 순차 회전 배열 안테나의 설계 (Design of Sequentially-Rotated Array Antenna with Triangular Lattice)

  • 진경수;정치현;박병우
    • 한국전자파학회논문지
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    • 제11권7호
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    • pp.1282-1290
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    • 2000
  • 모서리-절단 사각형 패치를 격자 형태로 배열하고 순차 회전 기법을 이용하여 위성방송수신 대역에서 동작하는 LHCP 원형 편파 안테나를 설계한다. 삼각형 격자 현태의 순차 회전 기법을 사용한 안테나는 축비 대역폭, 교차 편파 특성등을 개선하는 효과가 있으며, 급전 선로에 의한 방사를 최소로 하여 방사 패턴에 미치는 영향을 줄일 수 있다. 설계된 안테나는 $\Phi$45$^{\circ}$평면에서 DBS 배열 안테나의 부엽 준위 규격(-27dB)과 교차 편파 준위(-20dB)를 만족하고 있다.

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수소흡수-방출 사이클에 의한 Zr0.9Ti0.1Cr0.7Fe1.3 합금의 수소화 반응 특성의 변화 (The Changes of the Hydrogenation Properties of Zr0.9Ti0.1Cr0.7Fe1.3 Alloy Upon the Pressure Induced Hydriding-Dehydriding Cycling)

  • 이존하;이재영
    • 한국수소및신에너지학회논문집
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    • 제2권1호
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    • pp.29-37
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    • 1990
  • The effect of pressure cycling of $Zr_{0.9}Ti_{0.1}Cr_{0.7}Fe_{1.3}$ on the hydrogenation properties was investigated using the P-C-Isotherm curves and hydrogen absorption rate curves in the isotherm condition. The reversible hydrogen absorption capacity was decreased about 45 % after 3300 cycles. In the case of activated sample, the rate controlling steps of hydriding reaction changed from the surface reaction to the hydrogen diffusion process through hydride phase sequentially as reaction proceeded. After 3300 cycles, the sequential change of rate controlling step was same as activated one. However, the hydrogen absorption rate significantly decreased. It is suggested that the degradation of $Zr_{0.9}Ti_{0.1}Cr_{0.7}Fe_{1.3}$ can be interpreted with the formation of $ZrFe_3$ phase at the particle surface.

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Effect of Rotary Drum on the Speciation of Heavy Metals during Water Hyacinth Composting

  • Singh, Jiwan;Kalamdhad, Ajay S.
    • Environmental Engineering Research
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    • 제18권3호
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    • pp.177-189
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    • 2013
  • Studies were carried out on the speciation of heavy metals (Zn, Cu, Mn, Fe, Ni, Pb, Cd, and Cr) during rotary drum composting of water hyacinth (Eichhornia crassipes) for a period of 20 days. Five different proportions of cattle manure, water hyacinth and sawdust were prepared for composting. This study concluded that, rotary drum was very efficient for the degradation of organic matter as well as for the reduction of mobility and bioavailability of heavy metals during water hyacinth composting. The results from the sequential extraction procedure of heavy metals shows that rotary drum composting changed the distribution of five fractions of Zn, Cu, Mn, Fe, Ni, Pb, Cd, and Cr. The highest reduction in the bioavailability factors of Pb and Cd was observed during the process. The total concentration of Cu, Cr, and Cd was very low compared to the other metals (Zn, Mn, Fe, Ni, and Pb); however, the percentage of exchangeable and carbonate fractions of these metals was similar to other metals. These results confirmed that the bioavailability of metals does not depend on the total concentration of metals. From this study, it can be concluded that the addition of an appropriate proportion of cattle manure significantly reduced the mobile and easily available fractions (exchangeable and carbonate fractions) during water hyacinth composting in rotary drum.

Isolation and Characterization of Mucinase Complex Secreted from Vibrio parahaemolyticus

  • Jun, In-Joon;Kim, Yoon-Hee;Kim, Min-Jeong;Hwang, Ho-Soon;Lee, Tae-Ho;Cha, Jae-Ho
    • Journal of Microbiology and Biotechnology
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    • 제13권5호
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    • pp.731-737
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    • 2003
  • Mucinase complex from V. parahaemolyticus ATCC 17802 was purified 6-fold with 0.4% yield by two sequential steps of Q-Sepharose and Superdex 200HR column chromatographies. Partially purified mucinase complex showed at least 8 times higher mucin-degrading activity than the culture filtrates. The mucinase complex also showed gelatin-and-casein-hydrolyzing activities, which demonstrates that the protein is a complex compound containing several proteases. The optimum pH and temperature of partially purified mucinase complex for mucin degradation was 8.0 and $35^{\circ}C$, respectively. The partially purified mucinase complex showed high cytotoxic activity on vero cells when examined by MTT assay and microscopic observations. Cytotoxicity was significantly increased in proportion to the concentration of the mucinase complex. Mouse experiments revealed that the jejunum, ileum. and large intestinal tissues were damaged by the injection of the mucinase complex. In particular, the reduction of the goblet cells in the large intestine was remarkable. Collectively, these data suggest that the mucinase complex partially purified from V. parahaemolyticus ATCC 17802 contributes to the adhesion and invasion of V. parahaemolyticus into the host intestinal tract.

Development of High Aperture Ratio 2.1” QVGA LTPS (Low Temperature Poly Si) LCD Using SLS (Sequential Lateral Solidification) Technology

  • Kang, Myung-Koo;Lee, Joong-Sun;Park, Jong-Hwa;Zhang, Lintao;Joo, Seung-Yong;Kim, Chul-Ho;Kim, Il-Kon;Kim, Sung-Ho;Park, Kyung-Soon;Yoo, Chun-Ki;Kim, Chi-Woo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
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    • pp.1033-1034
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    • 2005
  • High resolution 2.1” QVGA LTPS LCD (190ppi) having high aperture ratio of 65% could be successfully developed using state-of-the-art SLS technology and active/gate storage structure. Cost effective P-MOS 6-Mask structure was used. Full gate and transmission gate circuits are integrated in the panel. The high aperture ratio was obtained by using active/gate capacitance structure, which can reduce storage capacitance area. The aperture ratio was increased to 65% from 49% of conventional gate/data capacitance structure. The brightness was increased from 180cd to 270cd without any degradation of optical properties such as contrast ratio, flicker or crosstalk.

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부분방전 해석 방법으로 PSA(Pulse Sequence Analysis)의 문제점에 대한 고찰 (Some Considerations on the Problems of PSA(Pulse Sequence Analysis) as a Partial Discharge Analysis Method)

  • 김정태;이호근
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.327-330
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    • 2004
  • Because of its effectiveness for the PD(partial discharge) pattern recognition, PSA(Pulse Sequence Analysis) has been considered as a new analytic method instead of conventional PRPDA(Phase Resolved Partial Discharge Analysis). However, PSA has a big problem that can misanalyze patterns in case of data missing resulting from poor sensitivity because it analyses the correlation between sequential pulses, which leads to hesitate to apply it to on-site. Therefore, in this paper, the problems of PSA such as data missing and noise adding cases were investigated. For the purpose, PD data obtained from various defects including noise adding data were used and analysed, The result showed that both cases can cause fatal errors in recognizing PD patterns. In case of the data missing, the error depends on the kinds of defect and the degree of degradation. Also, it could be noticed that the error due to adding noises was larger than that due to some data missing.

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복합재 압력용기의 확률 섬유 강도 (Probabilistic Fiber Strength of Composite Pressure Vessel)

  • 황태경;홍창선;김천곤
    • Composites Research
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    • 제16권6호
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    • pp.1-9
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    • 2003
  • 본 논문에서는 웨이블 분포 함수를 이용한 확률 파손 해석을 통해 복합재 압력 용기의 섬유 강도를 예측하였다. 그리고 섬유 강도의 크기 효과를 확인하고 해석의 타당성을 입증하기 위하여 섬유 인장 시편, 한 방향 복합재 시편과 복합재 압력 용기를 이용만 강도 시험이 수행되었다. 해석적 방법으로 웨이블 최약 링크 파손 모델과 다단계 연속 파손 모델을 이용하였고, 해석 결과를 상호 비교하였다. 크기 효과에 의해, 시편의 부피가 증가함에 따라 섬유 인장 강도가 감소하는 경향을 나타내었다. 해석을 통해 예측한 한 방향 복합재 시편과 복합재 압력 용기의 후프 층 섬유 강도 분포는 시험 값과 좋은 일치를 보였다. 섬유 강도의 크기 효과는 소재와 제작 공정 변수의 함수로서, 다른 소재 및 제작 공정에 대해서는 다른 크기 효과를 보이게 된다.