• 제목/요약/키워드: Separation Behavior

검색결과 657건 처리시간 0.029초

Rheological behavior during the phase separation of thermoset epoxy/thermoplastic polymer blends

  • Kim, Hongkyeong;Kookheon Char
    • Korea-Australia Rheology Journal
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    • 제12권1호
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    • pp.77-81
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    • 2000
  • Rheological behavior of thermoset/thermoplastic blends of epoxy/polyethersulphone (PES) was monitored during curing of the epoxy resin. During the isothermal curing of the mixture, a fluctuation in viscosity just before the abrupt viscosity increase was observed. This fluctuation is found to be due to the phase separation of PES from the matrix epoxy resin during the curing. The experimentally observed viscosity fluctuation is simulated with a simple two phase suspension model in terms of the increase in domain size. The viscosity profiles obtained experimentally at different isothermal curing temperatures are in good agreement with the predictions from the simple model taking into account the viscosity change due to the growth of PES domain and the network formation of the epoxy matrix.

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The Effects of Intramolecular Interactions of Random Copolymers on the Phase Behavior of Polymer Mixtures

  • Kim, M. J.;J. E. Yoo;Park, H. K.;Kim, C. K.
    • Macromolecular Research
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    • 제10권2호
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    • pp.91-96
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    • 2002
  • To explore the effects of intramolecular interactions within the copolymer on the phase separation behavior of polymer blends, copolymers having two different types of intramolecular interactions, i.e., intramolecular repulsion and intramolecular attraction were prepared . In this study, poly(styrene-co-methylmethacrylate) (P(S-MMA)) having intramolecular repulsion caused by positive interaction between styrene and MMA and poly(styrene-co-ethyl-methacrylate) (P(S-EMA)) and poly(styrene-co-cyclohexylmethacrylate) (P(S-CHMA)) having intramolecular attraction caused by negative interaction between styrene and methacrylate were blended with tetramethyl poly-carbonate (TMPC). The phase behavior of blends was examined as a function of copolymer composition and blend composition. TMPC formed miscible blends with styrenic copolymers containing less than certain amount of methacrylate. The phase separation temperature of TMPC blends with copolymer such as P(S-MMA) and P(S-EMA), first increases with methacrylate content, goes through a maximum and then decreases just prior to the limiting content of methacrylate for miscibility, while that of TMPC blends with P(S-CHMA) always decreases. The calculated interaction energy for TMPC-P(S-EMA) pair is negative and monotonically increases with EMA content of the copolymer. Such behavior contradicted the general notion that systems with more favorable energetic interactions have higher LCST, The detailed inspection of the lattice-fluid theory related to the phase behavior was performed to explain such behavior.

환경문제에서의 재활용 행동 증진을 위한 행동분석적 실험 연구 - 환경적 변화와 프롬트의 효과를 중심으로- (A behavioral approach to increase recycling behavior: An examinination of effect of environmental alteration and prompts)

  • 오세진;양병화;현보성;황혜연
    • 한국환경교육학회지:환경교육
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    • 제14권1호
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    • pp.19-31
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    • 2001
  • This study examined the effect of environmental alteration and prompts on recycling behavior. An A-B-BC with a control condition design was employed. Subjects in this study were college students, professors, and employees at a university building. After a baseline phase, environmental alteration was I effect in the next phase and both environmental alteration and prompts were in effect in the final phase for the control condition. The environmental alteration consisted of providing four separation containers for the paper cups, cans recyclable paper, and the disposable on each floor in the building. The prompts consisted of providing the information about the importance of environmental preservation and how to separate the materials in the appropriate containers using an information board and pamphlets. The dependent variables were (1) the number of cans collected in can container, (2) the number of paper cups collected in cup container, (3) the rate of correct separation of cans, (4) the rate of correct separation of paper cups, and (5) the weight of disposable. The rates of correct separations of cans and paper cups were obtained by calculating the percentage of thenumber of recyclable cans and paper cups in the corresponding containers. The results indicated that environmental alteration had positive effects on all the dependent variables. Also, when the prompts were added to the environmental alteration, the incremental effect of the prompts was demonstrated. The implications and limitations of theses findings were discussed and the direction of future studies was also proposed.

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SALS를 이용한 고분자용액의 상전환 기구에 관한 연구 : C1-C4 알콜의 첨가에 따른 상분리 거동에 미치는 효과와 투과 특성 (The study of phase inversion of polymer solutions using small angle light scattering (SALS): The effect of addition of alcohol (C1-C4) on phase separation behavior and hydraulic permeation)

  • Kang, Jong-Seok;Lee, Young-Moo
    • 한국막학회:학술대회논문집
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    • 한국막학회 2002년도 춘계 총회 및 학술발표회
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    • pp.81-85
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    • 2002
  • Small angle light scattering and field emission scanning electron microscope have been used to quantify the kinetics of liquid-liquid separation behavior during water vapor(RH52%[$\pm$3%] at 27$^{\circ}C$) quenching (non-solvent induced phase separation, NIPS) of polysulfone/NMP/Alcohol and CPVC/THF/Alcohol, respectively. Time dependence of the position of the light scattering maximum was observed at polysufone dope solutions, confirming spinodal secomposition (SD). while CPVC dope solutions showed a decreased scattered light intensity with a increased q-valuel, indicating nucleation & growth (NG). For the each system, domain growth rate in the intermediate and late stage of phase separation decreased with increasing the number of carbon of alcohol used as additive (non-solvent). Also, in the early stage for SD, the scattering intensity with time was in accordance with Cahns linear theory of spinodal decomposition,[1-3] regardless of types of non-solvent additive.

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스플릿 타입 분리장치의 수학적 동적 분리 거동 모델링 (Mathematical separation behavior modeling for the split-type separation device)

  • 황대현;한재흥;이응조;김동진
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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    • pp.423-425
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    • 2017
  • 많은 우주 발사체와 로켓에 분리가 필요한 순간에 작동하는 파이로 분리장치는 높은 신뢰도 및 에너지를 갖는다는 장점을 가져 널리 활용되어 왔다. 그 중 high-explosive 타입의 분리장치에서 발생하는 충격과 파편은 발사체 내부 탑재 장비에 치명적 손상을 야기 할 수 있고, 이러한 문제를 해결하기 위해 압력 카트리지 방식의 저충격 분리장치가 개발되어 왔다. 본 연구에서는 저충격 분리장치중 하나인 스플릿 타입 파이로락에 대하여 연소상태와 파이로락을 구성하는 4개의 독립적 내부 부품의 분리 거동을 모사하는 수학적 모델을 설립하고, 실험 결과와 비교를 통해 검증을 수행하였다.

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Maternal Social Separation of Adolescent Rats Induces Hyperactivity and Anxiolytic Behavior

  • Kwak, Hyong-Ryol;Lee, Jae-Won;Kwon, Kwang-Jun;Kang, Chang-Don;Cheong, Il-Young;Chun, Wan-Joo;Kim, Sung-Soo;Lee, Hee-Jae
    • The Korean Journal of Physiology and Pharmacology
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    • 제13권2호
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    • pp.79-83
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    • 2009
  • Exposure to early stressful adverse life events such as maternal and social separation plays an essential role in the development of the nervous system. Adolescent Sprague-Dawley rats that were separated on postnatal day 14 from their dam and litters (maternal social separation, MSS) showed hyperactivity and anxiolytic behavior in the open field test, elevated plus-maze test, and forced-swim test. Biologically, the number of astrocytes was significantly increased in the prefrontal cortex of MSS adolescent rats. The hyperactive and anxiolytic phenotype and biological alteration produced by this MSS protocol may provide a useful animal model for investigating the neurobiology of psychiatric disorders of childhood-onset diseases, such as attention deficient hyperactive disorder.

Chronic administration of ketamine ameliorates the anxiety- and aggressive-like behavior in adolescent mice induced by neonatal maternal separation

  • Shin, Sang Yep;Baek, Nam Jun;Han, Seung Ho;Min, Sun Seek
    • The Korean Journal of Physiology and Pharmacology
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    • 제23권1호
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    • pp.81-87
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    • 2019
  • Ketamine has long been used as an anesthetic agent. However, ketamine use is associated with numerous side effects, including flashbacks, amnesia, delirium, and aggressive or violent behavior. Ketamine has also been abused as a cocktail with ecstasy, cocaine, and methamphetamine. Several studies have investigated therapeutic applications of ketamine, demonstrating its antidepressant and anxiolytic effects in both humans and rodents. We recently reported that neonatal maternal separation causes enhanced anxiety- and aggressive-like behaviors in adolescent. In the present study, we evaluated how acute and chronic ketamine administration affected the behavioral consequences of neonatal maternal separation in adolescent mice. Litters were separated from dams for 4 hours per day for 19 days beginning after weaning. Upon reaching adolescence (post-natal day 35-49), mice were acutely (single injection) or chronically (7 daily injections) treated with a sub-anesthetic dose (15 mg/kg) of ketamine. At least 1 h after administration of ketamine, mice were subjected to open-field, elevated-plus maze, and resident-intruder tests. We found that acute ketamine treatment reduced locomotor activity. In contrast, chronic ketamine treatment decreased anxiety, as evidenced by increased time spent on open arms in the elevated-plus maze, and remarkably reduced the number and duration of attacks. In conclusion, the present study suggests that ketamine has potential for the treatment of anxiety and aggressive or violent behaviors.

경사면 위에서 작은 정다각형 부품의 구름 거동 (The Rolling Behavior of a Small Regular Polygonal Part on an Inclined Plane)

  • 한인환
    • 대한기계학회논문집A
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    • 제30권11호
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    • pp.1461-1471
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    • 2006
  • This paper presents the mathematical model for rolling behaviors of a small regular polygonal part on an inclined plane. Throughout the numerical analysis performed with the simulation program which has been experimentally validated, it is shown that the number of edges of the rolling polygonal part can be a measure for the energy dissipation rather than the coefficient of friction. The appropriate slope angle has been found to be around 20 degree for roughness-separation as well as shape-separation of polygonal parts which have small number of edges. In additions, the vibratory motion applied to the inclined plane is able to cause mixed parts to be separated more effectively according to the shape or the roughness. Finally, a couple of parts separation methods based on the analysis results are presented, and are validated through the numerical simulation.

Analysis of Double-Stranded DNA Fragments by Capillary Electrophoresis Using Entangle Polymer Solutions in Uncoated Fused Silica Capillary Columns

  • Lee, Jong-Jin;Lee, Kong-Joo
    • BMB Reports
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    • 제31권4호
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    • pp.384-390
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    • 1998
  • DNA fragments (51-587 bp) were separated by capillary electrophoresis using entangled polymer, hydroxyethylcellulose, in uncoated fused silica capillary columns. The factors affecting the separation of DNA fragments with hydroxyethylcellulose media were evaluated, i.e., the concentration of buffer and entangled polymer, effects of additives (methanol, ethidium bromide, EDTA), temperature, and injection methods. Maximum performance was obtained by adding 5% methanol in 0.5% hydroxyethylcellulose solution at $30^{\circ}C$. Addition of methanol in polymer media increased the resolution of small size DNA fragments (< 100 bp). On the other hand, addition of ethidium bromide and EDTA, which are commonly used in conventional DNA separation, reduced the resolution of DNA fragments in the polymer solution. It turns out that the separation behavior of DNA in entangled polymer is more sensitive to the running condition compared to that in polyacrylamide gel-filled capillary, but the reproducibility of DNA separation in entangled polymer is reliable.

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Flexible Nonlinear Learning for Source Separation

  • Park, Seung-Jin
    • Journal of KIEE
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    • 제10권1호
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    • pp.7-15
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    • 2000
  • Source separation is a statistical method, the goal of which is to separate the linear instantaneous mixtures of statistically independent sources without resorting to any prior knowledge. This paper addresses a source separation algorithm which is able to separate the mixtures of sub- and super-Gaussian sources. The nonlinear function in the proposed algorithm is derived from the generalized Gaussian distribution that is a set of distributions parameterized by a real positive number (Gaussian exponent). Based on the relationship between the kurtosis and the Gaussian exponent, we present a simple and efficient way of selecting proper nonlinear functions for source separation. Useful behavior of the proposed method is demonstrated by computer simulations.

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