• 제목/요약/키워드: Sensor electrode

검색결과 763건 처리시간 0.033초

Sensing Characteristics of Tyrosinase Immobilized and Tyrosinase, Laccase Co-immobilized Platinum Electrodes

  • Quan, De;Kim, You-Sung;Shin, Woon-Sup
    • Bulletin of the Korean Chemical Society
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    • 제25권8호
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    • pp.1195-1201
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    • 2004
  • Tyrosinase was covalently immobilized on platinum electrode according to the method we developed for laccase (Bull. Korean Chem. Soc. 2002, 23(7), 385) and p-chlorophenol, p-cresol, and phenol could be detected with sensitivities of 334, 139 and 122 nA/ ${\mu}M$ and the detection limits of 1.0, 2.0, and 2.5 ${\mu}M$, respectively. The response time ($t_{90\%}$) is 3 seconds for p-chlorophenol, and 5 seconds for p-cresol and phenol. The optimal pHs of the sensor are in the range of 5.0- 6.0. This sensor can tolerate at least 500 times repeated injections of p-chlorophenol with retaining 80% of initial activity. In case of tyrosinase and laccase co immobilized platinum electrode, the sensitivities are 560 nA/ ${\mu}M$ for p-phenylenediamine (PPD) and 195 nA/ ${\mu}M$ for p-chlorophenol, respectively. The sensitivity of the bi-enzyme sensor for PPD increases 70% compared to that of only laccase immobilized one, but the sensitivity for p-chlorophenol decreases 40% compared to that of only tyrosinase immobilized one. The sensitivity increase for the bi-enzyme sensor for PPD can be ascribed to the additional catalytic function of the co-immobilized tyrosinase. The sensitivity decrease for p-chlorophenol can be explained by the “blocking effect” of the co-immobilized laccase, which hinders the mass transport through the immobilized layer. If PPD was detected with the electrode that had been used for p-chlorophenol, the sensitivity decreased 20% compared to that of the electrode that had been used only for PPD. Similarly, if p-chlorophenol was detected with PPD detected electrode, the sensitivity also decreased 20%. The substrate-induced conformation changes of the enzymes in a confined layer may be responsible for the phenomena.

자동차 배기가스용 NOx센서의 감도향상를 위한 새로운 산화물 감지물질과 변형된 혼합전위 센서의 개발 (The development of new oxide materials and modified mixed potential sensing method for highly sensitive NOx sensor)

  • 박진수;윤병영;박종욱
    • 센서학회지
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    • 제17권1호
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    • pp.61-68
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    • 2008
  • The sensing characteristics of new oxide sensing materials, NiO, NiO-YSZ and CuO, were evaluated at the temperature of $700^{\circ}C$ in 10 % $O_2$containing atmosphere. Through simultaneous response to $NO_2$ and NO, the sensing mechanism of oxide electrode was studied and the relation of EMF and NO/$NO_2$ concentrations was elucidated. Moreover, for highly sensitive NOx sensor, modified mixed potential sensor which has at least two oxide electrodes was proposed.

집중 소자를 이용한 표면 탄성파 장치 기반의 용량 성 센서 보정 및 이를 이용한 초정밀 간극 측정 (Calibration of SAW Based Capacitive Sensor Using Lumped Component and High Precision Gap Measurement)

  • 김재근;고병한;박영필;박노철
    • 정보저장시스템학회논문집
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    • 제8권1호
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    • pp.16-21
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    • 2012
  • SAW device is widely used as filters, sensors, actuators in various technologies. And capacitive sensor is tremendously used to measure pressure, gap, etc. The application of SAW device as signal conditioner of capacitive sensor reduces noise level and enables high precision measurement. The response increase of SAW based capacitive sensor is produced just before the two capacitive electrode contacts by the existence of parasitic resistance of capacitive electrode. In this paper, we analyze the effects of parasitic resistance and propose the calibrating method using lumped component and execute the high precision gap measurement using calibrated system. And xx nm resolution and yy ${\mu}m$ stroke was attained.

철근콘크리트에 매립된 철근의 부식 모니터링에 관한 실험적 연구 (An Experimental Study on the Monitoring of Corrosion of Rebar Embedded in Reinforced Concrete)

  • 박장현;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2019년도 춘계 학술논문 발표대회
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    • pp.262-263
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    • 2019
  • In this study, a sensor for detecting corrosion of rebar embedded in reinforced concrete structures was fabricated and its performance was verified. In order to monitor the open circuit potential(OCP) of the rebar embedded in reinforced concrete, a concrete embedded solid electrode was constructed as a sensor using MnO2. The OCP of the rebar could be observed using a sensor and a data logger. The decrease of the OCP to -510mV (vs.MnO2) or less was judged to be corrosion of the rebar. Since it is a solid-mediated sensor, it is more stable and durable than an electrode using an aqueous solution, and it is considered that the corrosion state of the rebar can be monitored for a long period of time.

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패브리페로 간섭계를 이용한 광섬유 전압센서의 구현 (Voltage Sensor using Fiberoptic Fabry-Perot Interferometry)

  • 김정익;전진홍;김광수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.236-238
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    • 2002
  • A noble fiberoptic voltage sensor system utilizing an interferometric transducer has been introduced for high voltage measurement. The sensor system employs a fiberoptic Fabry-Perot interferometric strain sensor to convert voltage to displacement in an auxiliary movable electrode. The operating mechanism is based on the fact that the electrostatic force acting on the electrode system by the applied voltage results in strain variation on the Fabry-Perot interferometry. The experiment results show that the proposed voltage sensor has the potential to be extended to very high voltage system with appropriate auxiliary electrodes.

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Electrochemical Determination of Chemical Oxygen Demand Based on Boron-Doped Diamond Electrode

  • Dian S. Latifah;Subin Jeon;Ilwhan Oh
    • Journal of Electrochemical Science and Technology
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    • 제14권3호
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    • pp.215-221
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    • 2023
  • A rapid and environment-friendly electrochemical sensor to determine the chemical oxygen demand (COD) has been developed. The boron-doped diamond (BDD) thin-film electrode is employed as the anode, which fully oxidizes organic pollutants and provides a current response in proportion to the COD values of the sample solution. The BDD-based amperometric COD sensor is optimized in terms of the applied potential and the solution pH. At the optimized conditions, the COD sensor exhibits a linear range of 0 to 80 mg/L and the detection limit of 1.1 mg/L. Using a set of model organic compounds, the electrochemical COD sensor is compared with the conventional dichromate COD method. The result shows an excellent correlation between the two methods.

Thallium(Ⅰ)-Selective Membrane Potentiometric Sensor Based on Dibenzyldiaza-18-Crown-6

  • Khayatian, Gholamreza;Shariati, Satar;Salimi, Abdollah
    • Bulletin of the Korean Chemical Society
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    • 제24권4호
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    • pp.421-425
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    • 2003
  • A new thallium(Ⅰ) selective electrode based on dibenzylidaza-18-crown-6 as mambrane carrier was successfully prpared. The electrode exhibitis a near-Nernstian response for $ T1^+$ ions over a wide concentration range from $1.0×10^{15}-1.0×10^{-1}$M at 25℃, and was found to be selective, precise and useable within the pH range 4.0-11.0. The electrode was successfully used as an indicator electrode in potentiometric titration of thallium ions.

Sodium Ion-Selective Membrane Electrode Based on Dibenzopyridino-18-Crown-6

  • Tavakkoli, Nahid
    • Bulletin of the Korean Chemical Society
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    • 제25권10호
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    • pp.1474-1476
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    • 2004
  • A sodium ion- selective electrode based on dibenzopyridino-18-crown-6 as membrane carrier was successfully prepared. The electrode exhibits a Nernstian response for $Na^+$ ions within the concentration range of $1.0\;{\times}\;10^{-4}-1.0\;{\times}\;10^{-1}$ M. The response time of the sensor is 20 s. The sodium ion-selective electrode exhibited comparatively good selectivities with respect to alkali, alkaline earth and some transition metal ions.

Effect of Ag Powder Sources on the Patterning of PDP Electrodes

  • Woo, Chang-Min;Kim, Soon-Hak;Hur, Young-June;Kim, Duck-Gon;Song, Gab-Duk;Lee, Yoon-Soo;Cho, Ho-Young;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.953-955
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    • 2006
  • In this work we compared different sources of composition of Ag powders obtained by dry and wet process on the photolithographic patterning of PDP electrode and resistance of sintered Ag electrode. It was found that 90 : 10 wt% ratio of Ag powder made by dry and wet processes gave optimum result both on the PDP electrode pattern and resistance of PDP electrode after sintering.

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다중벽 탄소나노튜브 습도센서의 제작과 응답특성 (Fabrication and Response Characteristics of Multi-walled Carbon Nanotube Film Humidity Sensor)

  • 박찬원
    • 산업기술연구
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    • 제34권
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    • pp.39-43
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    • 2014
  • This paper represents a highly porous MWCNT film electrode with interconnected open pores and demonstrated the possibility of using an MWCNT network film as the top electrode for polyimide capacitive humidity sensors. Polyimide humidity sensors with MWCNT electrodes exhibited about 6 times faster response than equivalent Cr electrode sensors. This result may be due to their percolated pore structures, which make water molecules accessible to all polyimide surfaces. The much faster response times of MWCNT electrode sensors is attributed to the percolated pore network, which allows more water molecules to be accessible to polyimide surfaces.

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