• Title/Summary/Keyword: Semi-continuous measurements

Search Result 11, Processing Time 0.036 seconds

Application of Semi-continuous Ambient Aerosol Collection System for Elemental Analysis (대기입자의 원소성분 배출특성연구를 위한 반-연속식 입자채취시스템 적용)

  • Park, Seung-Shik;Ko, Jae-Min;Lee, Dong-Soo
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.28 no.1
    • /
    • pp.39-51
    • /
    • 2012
  • Aerosol slurry samples were collected in 60-min interval using Korean Semi-continuous Elements in Aerosol Sampler (KSEAS) between May 19 and June 6, 2010 at an urban site of Gwangju. The $PM_{2.5}$ samples were collected with a flow rate of 16.7 L/min and particles are grown by condensation of water vapor in a condenser maintained at ${\sim}5^{\circ}C$ after saturation by direct injection of steam. The resulting droplets are collected in a liquid slurry with a airdroplet separator. Concentrations of 16 elements (Al, Fe, Mn, Ca, K, Cu, Zn, Pb, Cd, Cr, Ti, V, Ni, Co, As, Se) in the collected slurry samples were determined off-line by ICP-MS. KSEAS sample analysis encompassed the sampling periods for which 24-hr average elemental species concentrations were calculated for comparison with those derived from 24-hr integrated filter samples. Relationship between elemental species measured by two methods indicated high correlation coefficients (r), mostly greater than r of 0.80. However, we note that concentrations of Al, K, Ca, Mn, and Fe, which are often associated with crustal elemental particles, in the KSEAS samples, were substantially lower (1.4~11 times) than those found in the typical filter-based samples. This discrepancy is probably due to difficulties in transferring insoluble dust particles to the collection vials in the KSEAS. Temporal profiles of elemental concentrations indicate that some transient events in their concentrations are observed over the sampling periods. For the elemental species studied, atmospheric concentrations during the transient events increased by factors of 4 in Mn~80 in Zn, compared to their background levels. Principle component analyses were applied to the hourly KSEAS data sets to identify sources affecting the concentrations of the metal constituents observed. In this study, we conclude that hourly measurements for particle-bound elemental constituents were extremely useful for revealing the short-term variability in their concentrations and developing insights into their sources.

Investigation on a Haze Episode of Fine Particulate Matter using Semi-continuous Chemical Composition Data (준 실시간 화학적 조성자료를 이용한 미세입자 연무 에피소드 규명)

  • Park, Seung-Shik;Kim, Sun-Jung;Gong, Bu-Joo;Lee, Kwon-Ho;Cho, Seog-Yeon;Kim, Jong-Choon;Lee, Suk-Jo
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.29 no.5
    • /
    • pp.642-655
    • /
    • 2013
  • In this study, semi-continuous measurements of $PM_{2.5}$ mass, organic and elemental carbon (OC and EC), black carbon (BC), and ionic species concentrations were made for the period of April 03~13, 2012, at a South Area Supersite at Gwangju. Possible sources causing the high concentrations of major chemical species in $PM_{2.5}$ observed during a haze episode were investigated. The measurement results, along with meteorological parameters, gaseous pollutants data, air mass back trajectory analyses and PSCF (potential source contribution function) results, were used to study the haze episode. Substantial enhancements of OC, EC, BC, $K^+$, $SO{_4}^{2-}$, $NO{_3}{^-}$, $NH{_4}{^+}$, and CO concentrations were closely associated with air masses coming from regions of forest fires in southeastern China, suggesting likely an impact of the forest fires. Also the PSCF maps for EC, OC, $SO{_4}^{2-}$, and $K^+$ demonstrate further that the long-range transport of smoke plumes of forest fires detected over the southeastern China could be a possible source of haze phenomena observed at the site. Another possible source leading to haze formation was likely from photochemistry of precursor gases such as volatile organic compounds, $SO_2$, and $NO_2$, resulting in accumulation of secondary organic aerosol, $SO{_4}^{2-}$ and $NO{_3}{^-}$. Throughout the episode, local wind directions were between 200 and $230^{\circ}C$, where two industrial areas are situated, with moderate wind speeds of 3~5 m/s, resulting in highly elevated concentration of $SO_2$ with a maximum of 15 ppb. The $SO{_4}^{2-}$ peak occurring in the afternoon hours coincided with maximum ambient temperature ($24^{\circ}C$) and ozone concentration (~100 ppb), and were driven by photochemistry of $SO_2$. As a result, the pattern of $SO{_4}^{2-}$ variations in relation to wind direction, $SO_2$ and $O_3$ concentrations, and the strong correlation between $SO_2$ and $SO{_4}^{2-}$ ($R^2=0.76$) suggests that in addition to the impact of smoke plumes from forest fires in the southeastern China, local $SO_2$ emissions were likely an important source of $SO{_4}^{2-}$ leading to haze formation at the site.

Performance Improvement on Plate Girder Bridges Through Continuous Welded Rail (판형교 장대화에 따른 성능 개선)

  • Min, Kyung-Joo;Bahn, Gul-Yong;Ryu, Yeon-Jong
    • Proceedings of the KSR Conference
    • /
    • 2007.05a
    • /
    • pp.1439-1449
    • /
    • 2007
  • The challenging aspect of CWR (continuous welded rail) is the additional axial forces in rails, mainly due to the thermal expansion of steel plate girder and rail itself. It has been found that these axial forces are proportional to girder length, total bridge length and bolt tightening forces. Also these forces are dependent to girder support conditions, types of bearings and their arrangements. With CWR, the authors' previous studies show that performance improvements like noise reduce, fatigue resistances and bearing durability increment can be expected. In addition to these effects, secondary effects due to the semi integral behavior between rail and bridge girder also can be expected. Special bearings which can reduce the absolute maximum axial forces have been developed, and applied to real 100m span bridge. The performance improvements were verified through site measurements and numerical analysis. The purpose of this study is to confirm the expected performance improvement aspects of steel plate girder bridges with CWR. To verify these aspects, girder stiffness changes, rail axial force changes, girder displacements and noise level were thoroughly measured and compared.

  • PDF

Emission Characteristics of Elemental Constituents in Fine Particulate Matter Using a Semi-continuous Measurement System (준 실시간 측정시스템을 이용한 미세입자 원소성분 배출특성 조사)

  • Park, Seung-Shik;Ondov, John M.
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.26 no.2
    • /
    • pp.190-201
    • /
    • 2010
  • Fine particulate matter < $1.8{\mu}m$ was collected as a slurry using the Semicontinuous Elements in Aerosol Sampler with time resolution of 30-min between May 23 and 27, 2002 at the Sydney Supersite, Florida, USA. Concentrations of 11 elements, i.e., Al, As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Se, and Zn, in the collected slurry samples were determined off-line by simultaneous multi-element graphite furnace atomic absorption spectrometry. Temporal profiles of $SO_2$ and elemental concentrations combined with meteorological parameters such as wind direction and wind speed indicate that some transient events in their concentrations are highly correlated with the periods when the plume from an animal feed supplement processing facility influenced the Sydney sampling site. The peaking concentrations of the elemental species during the transient events varied clearly as the plume intensity varied, but the relative concentrations for As, Cr, Pb, and Zn with respect to Cd showed almost consistent values. During the transient events, metal concentrations increased by factors of >10~100 due to the influence of consistent plumes from an individual stationary source. Also the multi-variate air dispersion receptor model, which was previously developed by Park et al. (2005), was applied to ambient $SO_2$ and 8 elements (Al, As, Cd, Cr, Cu, Fe, Pb, and Zn) measurements between 20:00 May 23 and 09:30 May 24 when winds blew from between 70 and $85^{\circ}$, in which animal feed processing plant is situated, to determine emission and ambient source contributions rates of $SO_2$ and elements from one animal feed processing plant. Agreement between observed and predicted $SO_2$ concentrations was excellent (R of 0.99; and their ratio, $1.09{\pm}0.35$) when one emission source was used in the model. Average ratios of observed and predicted concentrations for As, Cd, Cr, Pb, and Zn varied from $0.83{\pm}0.26$ for Pb to $1.12{\pm}0.53$ for Cd.

Preparation of Organic Peltier using Fullerene/Polyaniline (Fullerene과 Polyaniline을 이용한 유기 Peltier소자의 개발)

  • Lee, Chae-Jung;Kim, Joo-Yong
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2007.06a
    • /
    • pp.343-345
    • /
    • 2007
  • Temperature difference between two plates occurs when a current is passed though two semi-conductors that are connected each other at two junctions. The current drives a transfer of heat from one junction to the other. In this study, the thermoelectric module based on th "Peltier effect" was made by combing fullerene and polyaniline. Continuous temperature measurements on both surfaces were performed at room temperature($25.4^{\circ}C$) by an infrared non-contact thermometer. The results showed that cool ing effect of $2.2^{\circ}C$ was attained by 30 seconds, after which the effect was continuously vanished mainly due to electro decomposition.

  • PDF

Semi-continuous Measurements of PM2.5 OC and EC at Gosan: Seasonal Variations and Characteristics of High-concentration Episodes (준실시간 연속관측을 통한 제주 고산 PM2.5 OC와 EC의 계절별 사례별 특성)

  • Han, Jihyun;Bahng, Byungjo;Lee, Meehye;Yoon, Soon-Chang;Kim, Sang-Woo;Chang, Limseok;Kang, Kyeong-Sik
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.29 no.3
    • /
    • pp.237-250
    • /
    • 2013
  • At Gosan ABC superstation in Jeju Island, we measured organic carbon (OC) and elemental carbon (EC) in $PM_{2.5}$ from October 2009 to June 2010 using a Sunset Laboratory Model-4 Semi-Continuous OC/EC Field Analyzer. It employs TOT (Thermal-Optical-Transmittance) method with NIOSH 5040 protocol and enables to continuously monitor OC and EC concentrations with 1-hour time resolution. The mean values of OC and EC for the entire period of measurements were $2.1{\pm}1.4{\mu}g/m^3$ and $0.7{\pm}0.6{\mu}g/m^3$, respectively. The OC/EC ratio was 3 and EC accounted $25{\pm}2.1%$ of total carbon (TC, TC=OC+EC). Although OC and EC showed similar trend in seasonal variation, the ratio of OC to EC was the highest in early summer when temperature was the highest and the air was affected by biomass burning in the southern part of China. In winter, the high OC and EC concentrations were likely influenced by increased coal combustion from residential heating. The high OC and EC concentrations were observed during events such as haze, dust, and the combination of the two. During the haze events, OC and EC were enhanced with increase in $PM_{10}$, $PM_{2.5}$, $SO_2$, and $NO_2$ with broad maxima. When dust occurred, both OC and EC started decreasing after reaching their maxima a couple of hours before $PM_{10}$ maximum. The peak separation of carbonaceous species and aerosol masses with time was more noticeable when haze event was followed by dust plume. These results confirm that OC and EC are key components of haze occurring in the study region.

Comparison of Real Time Water Soluble Organic Carbon Measurements by Two PILS-TOC Analyzers (PILS-TOC를 이용한 실시간 대기 중 수용성 유기탄소 비교 측정)

  • Park, Da-Jeong;Kang, Seokwon;Lee, Taehyoung;Shin, Hye-Jung;Shon, Zang-Ho;Bae, Min-Suk
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.32 no.6
    • /
    • pp.633-641
    • /
    • 2016
  • Two identical Particle Into Liquid Samplers-Total Organic Carbon (PILS-TOC) were operated to measure fine particle Water Soluble Organic Carbon (WSOC) for one week on Feb. in 2016. The dual instrument operations provided validated WSOC concentrations to have a continuous WSOC measurement during the sample analysis period. Both PILS-TOC instruments were operated downstream of an carbon denuder to remove positive adsorption artifacts associated with semi-volatile organic compounds. Comparison of WSOC showed good agreement each other. The linear regression had a coefficient of determination ($r^2$) of 0.92 and a regression slope of 1.01 for the first period. The lower collection efficiency due to lower steam temperature is discussed. In addition, the potential primary source related to WSOC based on the comparison of black carbon (BC) concentrations is explained. The results of good agreement between two PILS-TOC measurements can provide the validation of WSOC cooperations and knowledge regarding the origins of WSOC and their behaviors.

V608 CASSIOPEIAE: A W UMA-TYPE ECLIPSING BINARY WITH TWO POSSIBLE CIRCUMBINARY COMPANIONS

  • Park, Jang-Ho;Lee, Jae Woo
    • Journal of The Korean Astronomical Society
    • /
    • v.55 no.1
    • /
    • pp.1-9
    • /
    • 2022
  • We present the photometric properties of V608 Cas from detailed studies of light curves and eclipse timings. The light curve synthesis indicates that the eclipsing pair is an overcontact binary with parameters of ∆T = 155 K, q = 0.328, and f = 26%. We detected the third light ℓ3, which corresponds to about 8% and 5% of the total systemic light in V and R bands, respectively. Including our 6 timing measurements, a total of 38 times of minimum light were used for a period study. It was found that the orbital period of V608 Cas has varied in some combination of an upward parabola and two periodic variations. The continuous period increase with a rate of +3.99 × 10-7 d yr-1 can be interpreted as a mass transfer from the secondary component to the primary star at a rate of 1.51 × 10-7 M yr-1. The periods and semi-amplitudes of the two periodic variations are about P3 = 16.0 yr and P4 = 26.3 yr, and K3 = 0.0341 d and K4 = 0.0305 d, respectively. The most likely explanation of both cycles is a pair of light-traveling time effects operated by the possible presence of third and fourth components with estimated masses of M3 = 2.20 M and M4 = 1.27 M in eccentric orbits of e3 = 0.66 and e4 = 0.52. Because the contribution of ℓ3 is very low compared to the estimated masses of two circumbinary objects, they can be inferred as very faint compact objects.

Characterization of Aerosol Composition, Concentration, and Sources in Bukhansan National Park, Korea (북한산국립공원 내 초미세먼지 농도 및 화학적 특성)

  • Kang, Seokwon;Kang, Taewon;Park, Taehyun;Park, Gyutae;Lee, Junhong;Hong, Je-Woo;Hong, Jinkyu;Lee, Jaehong;Lee, Taehyoung
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.34 no.3
    • /
    • pp.457-468
    • /
    • 2018
  • To improve understanding of the physico-chemical characteristics of aerosols in the national park and comparing the air pollution between national park and the urban area nearby national park, the aerosol characterization study was conducted in Bukhansan National Park, Seoul, from July through September 2017. Semi-continuous measurements of $PM_{2.5}$ using PILS (Particle Into Liquid System) coupled with IC (Ion Chromatography) and TOC (Total Organic Carbon) analyzer allowed quantification of concentrations of major ionic species($Cl^-$, $SO_4{^{2-}}$, $NO_3{^-}$, $Na^+$, $NH_4{^+}$, $K^+$, $Mg{^{2+}}$ and $Ca{^{2+}}$) and water soluble organic carbon (WSOC) with 30-minute time resolution. The total mass concentration of $PM_{2.5}$ was measured by T640 (Teledyne) with 5-minute time resolution. The black carbon (BC) and ozone were measured with a minute time resolution. The timeline of aerosol chemical compositions reveals a strong influence from urban area (Seoul) at the site in Bukhansan National Park. Inorganic aerosol composition was observed to be dominated by ammoniated sulfate at most times with ranging from $0.1{\sim}32.6{\mu}g/m^3$ (6.5~76.1% of total mass of $PM_{2.5}$). The concentration of ammonium nitrate, a potential indicator of the presence of local source, ranged from below detection limits to $20{\mu}g/m^3$ and was observed to be highest during times of maximum local urban (Seoul) impact. The total mass of $PM_{2.5}$ in Bukhansan National Park was observed to be 10~23% lower than the total mass of $PM_{2.5}$ in urban area (Gireum-dong and Bulgwang-dong, Seoul). In general, ozone concentration in Bukhansan National Park was observed to be similar or higher than urban sites in Seoul, suggesting additional biogenic VOCs with $NO_x$ from vehicle emission were to be precursors for ozone formation in Bukhansan National Park.