• Title/Summary/Keyword: Semi-conductivity

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The Development of Fully Coupled SWAT-MODFLOW Model (I) Model Development (완전 연동형 SWAT-MODFLOW 결합모형 (I) 모형의 개발)

  • Kim, Nam-Won;Chung, Il-Moon;Won, Yoo-Seung
    • Journal of Korea Water Resources Association
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    • v.37 no.6
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    • pp.499-507
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    • 2004
  • In this study, the fully coupled SWAT-MODFLOW model is developed by using the type of embedment MODFLOW in SWAT. Since SWAT model has semi distributed features, its groundwater component can't consider distributed parameters such as hydraulic conductivity, storage coefficient and spatially variable natures such as distribution of groundwater heads and pumping rate and so forth. The main purpose of this study is to overcome these limitations. This linkage is completed considering the interaction between stream network and aquifer to reflect boundary flow. To correspond HRU in SWAT to grid in MODFLOW, HRU-GRID conversion tool using DEM is newly suggested. As groundwater recharge of MODFLOW can be estimated accurately by SWAT model, the reliability of groundwater discharge and total runoff of watershed could be greatly enhanced.

Optimized Decomposition of Ammonia Borane for Controlled Synthesis of Hexagonal Boron Nitride Using Chemical Vapor Deposition

  • Han, Jaehyu;Kwon, Heemin;Yeo, Jong-Souk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.285-285
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    • 2013
  • Recently, hexagonal boron nitride (h-BN), which is III-V compound of boron and nitride by strong covalent sp2 bonds has gained great interests as a 2 dimensional insulating material since it has honeycomb structure with like graphene with very small lattice mismatch (1.7%). Unlike graphene that is semi-metallic, h-BN has large band gap up to 6 eV while providing outstanding properties such as high thermal conductivity, mechanical strength, and good chemical stability. Because of these excellent properties, hBN can potentially be used for variety of applications such as dielectric layer, deep UV optoelectronic device, and protective transparent substrate. Low pressure and atmospheric pressure chemical vapor deposition (LPCVD and APCVD) methods have been investigated to synthesize h-BN by using ammonia borane as a precursor. Ammonia borane decomposes to polyiminoborane (BHNH), hydrogen, and borazine. The produced borazine gas is a key material that is a used for the synthesis of h-BN, therefore controlling the condition of decomposed products from ammonia borane is very important. In this paper, we optimize the decomposition of ammonia borane by investigating temperature, amount of precursor, and other parameters to fabricate high quality monolayer h-BN. Synthesized h-BN is characterized by Raman spectroscopy and its absorbance is measured with UV spectrophotometer. Topological variations of the samples are analyzed by atomic force microscopy. Scanning electron microscopy and Scanning transmission Electron microscopy are used for imaging and analysis of structures and surface morphologies.

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An Integrated Surface Water-Groundwater Modeling by Using Fully Combined SWAT MODFLOW Model (완전연동형 SWAT-MODFLOW 모형을 이용한 지표수-지하수 통합 유출모의)

  • Kim, Nam Won;Chung, Il Moon;Won, Yoo Seung
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.5B
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    • pp.481-488
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    • 2006
  • This paper suggests a novel approach of integrating the quasi-distributed watershed model SWAT with the fully-distributed groundwater model MODFLOW. Since the SWAT model has semi distributed features, its groundwater components hardly considers distributed parameters such as hydraulic conductivity and storage coefficient. Generating a detailed representation of groundwater recharge, head distribution and pumping rate is equally difficult. To solve these problems, the method of exchanging the characteristics of the hydrologic response units (HRUs) in SWAT with cells in MODFLOW by fully combined manner is proposed. The linkage is completed by considering the interaction between the stream network and the aquifer to reflect boundary flow. This approach is provisionally applied to Gyungancheon basin in Korea. The application demonstrates a combined model which enables an interaction between saturated zones and channel reaches. This interaction plays an essential role in the runoff generation in the Gyungancheon basin. The comprehensive results show a wide applicability of the model which represents the temporal-spatial groundwater head distribution and recharge.

A Study on Improvement of Marine Clay through the Leaching Effect of Electrolyte Reaction in Electrode (전극의 전기분해 용출을 통한 해성점토의 개량에 관한 연구)

  • Han, Sang-Jae;Kim, Soo-Sam;Kim, Jong-Yun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.2C
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    • pp.89-98
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    • 2006
  • In this study, the iron and aluminium electrode was put in marine clay which was taken from south coast in Korea to increase the undrained shear strength by inducing the densification and cementation between clay particles and precipitation which was developed by electrode decomposition. For raising the cementation rate and reducing treatment time, high electric current( 2.5A) was applied in each electrode at semi-pilot scale soil box with marine clay. After the tests, the undrained shear strength was measured at designated points using cone penetration test device and sampling was conducted simultaneously in order to measure water content, pH and electric conductivity which would be the key for configuring the cementation effects indirectly. The iron electrode decomposition test results show that the water content adjacent to anode section decreased in 35% and increased in 13% at cathode section. The measured shear strength however, was increased considerably comparing to initial shear strength because of cementation effect between iron ions and soil particles. In case of aluminium electrode decomposition test, the distribution of measured shear strength and degree of improvement were more homogeneous than iron electrode decomposition test.

Mineralogical and Physico-chemical Properties of Fine fractions Remained after Crushed Sand Manufacture (국내 화강암류를 이용한 일부 인공쇄석사 제조과정에서 생기는 스러지의 광물.물리화학적 특성)

  • Yoo, Jang-Han;Ahn, Gi-Oh;Jang, Jun-Young
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.4 s.50
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    • pp.355-361
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    • 2006
  • Artificially crushed sands occupy approximately 30 percent of the total consumption in South Korea. The demand for the crushed sands is expected to rise in the future. Most manufacturers use granitic rocks to produce the crushed sands. During the manufacturing process, fine fractions (i.e., sludges or particles smaller than 63 microns) are removed through the process of flocculation. The fine fraction occupies about 15% of the total weight. The sludges are comprised of quartz, feldspars, calcite, and various kinds of clay minerals. Non-clay minerals occupy more than 75 percent of the sluges weight, according to the XRD semi-quantification measurement. Micas, kaolinites, chlorite, vermiculite, and smectites occur as minor constituents. The sludges from Jurassic granites contain more kaolinites and $14{\AA}$-types than those from the Cretaceous ones. The chemical analysis clearly shows the difference between the parent rocks and the sludges in chemical compositions. Much of colored components in the sludges was accumulated as the weathering products. Particle size analysis results show that the sludges can be categorized as silt loam in a sand-silt-clay triangular diagram. This result was for her confirmed by the hydraulic conductivity data. In South Korea, the sludges remained after crushed sand production are classified as an industrial waste because of their impermeability, and which is caused by their high silt and clay fractions.

Studies on the Measurement of Thermal Properties of Kochujang (고추장의 열(熱) 특성(特性) 측정(測定)에 관(關)한 연구(硏究))

  • Chun, Jae-Kun;Mok, Chul-Kyoon;Chang, Kyu-Seob
    • Korean Journal of Food Science and Technology
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    • v.11 no.3
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    • pp.157-161
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    • 1979
  • The apparatus and method that permit rapid and continuous determination of thermal conductivity and diffusivity of Kochujang, Korean native semi-solid food, are presented. 1. The thermal conductivities of Kochujang are $0.3517\;kcal/mh^{\circ}C$ at $25^{\circ}C$, $0.3957\;kcal/mh^{\circ}C$ at $50^{\circ}C$ and $0.4221\;kcal/mh^{\circ}C$ at $100^{\circ}C$. Thermal diffusivity of Kochujang is $0.1000\;cm^2/min$ at $50^{\circ}C$, specific heat and density are $0.573\;kcal/kg^{\circ}C$, $1,220\;kg/m^3$, respectively. 2. There exists 6.04% discrepancy between the measured value and the calculated one from specific heat and density values.

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Groundwater evaluation in the Bokha watershed of the Namhan River using SWAT-MODFLOW (SWAT-MODFLOW를 활용한 남한강 복하천유역의 지하수 모의 평가)

  • Han, Daeyoung;Lee, Jiwan;Jang, Wonjin;Kim, Seongjoon
    • Journal of Korea Water Resources Association
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    • v.53 no.11
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    • pp.985-997
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    • 2020
  • SWAT (Soil and Water Assessment Tool)-MODFLOW (Modular Groundwater Flow) is a coupled model that linking semi-distributed watershed hydrology with fully-distributed groundwater behavior. In this study, the groundwater simulation results of SWAT and SWAT-MODFLOW were compared for Bokhacheon watershed in Namhan river basin. The models were calibrated and validated with 9 years (2009~2017) daily streamflow (Q) data of Heungcheon (HC) water level gauge station and the daily groundwater level observation data of Yulheon (YH). For SWAT, the groundwater parameters of GW_DELAY, GWQMN, and ALPHA_BF affecting baseflow and recession phase were treated. The SWAT results showed the coefficient of determination (R2) of 0.7 and Nash-Sutcliffe model efficiencies (NESQ, NSEinQ) for Q and 1/Q with 0.73 and -0.1 respectively. For SWAT-MODFLOW, the spatio-temporal aquifer hydraulic conductivity (K, m/day), specific storage (Ss, 1/m), and specific yield (Sy) were applied. The SWAT-MODFLOW showed R2, NSEQ, and NSEinQ of 0.69, 0.74, and 0.51 respectively. The SWAT-MODFLOW considerably enhanced the low flow simulation with the help of aquifer physical information. The total streamflow of SWAT and SWAT-MODFLOW were 718.6 mm and 854.9 mm occupying baseflow of 342.9 mm and 423.5 mm respectively.

Growth and Optical Conductivity Properties for BaAl2Se4 Single Crystal Thin Film by Hot Wall Epitaxy (Hot Wall Epitaxy(HWE)법에 의한 BaAl2Se4 단결정 박막 성장과 광전도 특성)

  • Jeong, Junwoo;Lee, Kijung;Hong, Kwangjoon
    • Journal of Sensor Science and Technology
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    • v.24 no.6
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    • pp.404-411
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    • 2015
  • A stoichiometric mixture of evaporating materials for $BaAl_2Se_4$ single crystal thin films was prepared from horizontal electric furnace. To obtain the single crystal thin films, $BaAl_2Se_4$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the Hot Wall Epitaxy (HWE) system. The source and substrate temperatures were $610^{\circ}C$ and $410^{\circ}C$, respectively. The crystalline structure of the single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction (DCXD). The carrier density and mobility of $BaAl_2Se_4$ single crystal thin films measured from Hall effect by van der Pauw method are $8.29{\times}10^{-16}cm^{-3}$ and $278cm^2/vs$ at 293 K, respectively. The temperature dependence of the energy band gap of the $BaAl_2Se_4$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g(T)=3.4205eV-(4.3112{\times}10^{-4}eV/K)T^2/(T+232 K)$. The crystal field and the spin-orbit splitting energies for the valence band of the $BaAl_2Se_4$ have been estimated to be 249.4 meV and 263.4 meV, respectively, by means of the photocurrent spectra and the Hopfield quasicubic model. These results indicate that the splitting of the ${\Delta}so$ definitely exists in the ${\Gamma}_5$ states of the valence band of the $BaAl_2Se_4/GaAs$ epilayer. The three photocurrent peaks observed at 10 K are ascribed to the $A_1$-, $B_1$-exciton for n =1 and $C_{31}$-exciton peaks for n=31.

Numerical analysis of melt migration and solidification behavior in LBR severe accident with MPS method

  • Wang, Jinshun;Cai, Qinghang;Chen, Ronghua;Xiao, Xinkun;Li, Yonglin;Tian, Wenxi;Qiu, Suizheng;Su, G.H.
    • Nuclear Engineering and Technology
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    • v.54 no.1
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    • pp.162-176
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    • 2022
  • In Lead-based reactor (LBR) severe accident, the meltdown and migration inside the reactor core will lead to fuel fragment concentration, which may further cause re-criticality and even core disintegration. Accurately predicting the migration and solidification behavior of melt in LBR severe accidents is of prime importance for safety analysis of LBR. In this study, the Moving Particle Semi-implicit (MPS) method is validated and used to simulate the migration and solidification behavior. Two main surface tension models are validated and compared. Meanwhile, the MPS method is validated by the L-plate solidification test. Based on the improved MPS method, the migration and solidification behavior of melt in LBR severe accident was studied furthermore. In the Pb-Bi coolant, the melt flows upward due to density difference. The migration and solidification behavior are greatly affected by the surface tension and viscous resistance varying with enthalpy. The whole movement process can be divided into three stages depending on the change in velocity. The heat transfer of core melt is determined jointly by two heat transfer modes: flow heat transfer and solid conductivity. Generally, the research results indicate that the MPS method has unique advantage in studying the migration and solidification behavior in LBR severe accident.

Growth and optical conductivity properties for MnAl2S4 single crystal thin film by hot wall epitaxy method (Hot Wall Epitaxy(HWE)법에 의한 MnAl2S4 단결정 박막 성장과 광전도 특성)

  • You, Sangha;Lee, Kijeong;Hong, Kwangjoon;Moon, Jongdae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.6
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    • pp.229-236
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    • 2014
  • A stoichiometric mixture of evaporating materials for $MnAl_2S_4$ single crystal thin films was prepared from horizontal electric furnace. To obtain the single crystal thin films, $MnAl_2S_4$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the Hot Wall Epitaxy (HWE) system. The source and substrate temperatures were $630^{\circ}C$ and $410^{\circ}C$, respectively. The crystalline structure of the single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction (DCXD). The temperature dependence of the energy band gap of the $MnAl_2S_4$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g(T)=3.7920eV-5.2729{\times}10^{-4}eV/K)T^2/(T+786 K)$. In order to explore the applicability as a photoconductive cell, we measured the sensitivity (${\gamma}$), the ratio of photocurrent to dark current (pc/dc), maximum allowable power dissipation (MAPD) and response time. The results indicated that the photoconductive characteristic were the best for the samples annealed in S vapour compare with in Mn, Al, air and vacuum vapour. Then we obtained the sensitivity of 0.93, the value of pc/dc of $1.10{\times}10^7$, the MAPD of 316 mW, and the rise and decay time of 14.8 ms and 12.1 ms, respectively.