• Title/Summary/Keyword: Semi-aqueous

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Ion Exchange Modeling in ETA and NH$_3$ Aqueous Solutions (ETA 및 암모니아 수용액에서 이온교환 모델링)

  • 안현경;김상대;이인형
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.4 no.3
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    • pp.307-311
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    • 2003
  • The test did for the determine the optimized ratio of cation to anion in mixed ion exchange demineralizers. Binary, ternary, quaternary, and quinary cation and anion adsorption was performed to develop a comprehensive experimental data set from small-volume batch tests to obtain the selectivity coefficients of many cations and anions. The quantitative run time might be estimated by such ion exchange models as semi-empirical mass action and surface complexation models. The demineralizer can be used longer by increasing the ratios of cation to anion exchange resins in the bed.

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Study of Methane Storage through Structure Transition of Gas Hydrate (가스하이드레이트 구조 변형을 통한 메탄 저장에 관한 연구)

  • Lee, Ju-Dong;Lee, Man-Sig;Kim, Young-Seok
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.54-57
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    • 2006
  • Structure H formation experiments were conducted in a semi-batch stirred vessel using methane as the small guest substance and neohexane(NH), tert-butylmethylether(TBME) and methylcyclohexane(MCH) as the large molecule guest substance (LMGS). The results indicate that the rates of gas uptake and induction times are generally dependent on the magnitude of the driving force. When tert-butyl methyl ether is used as the LMGS rapid hydrate formation, much smaller induct ion time and rapid decomposition can be achieved. Liquid-liquid equilibrium (LLE) data for the above LMGS with water have been measured under atmospheric pressure at 275.5, 283.15K, and 298.15K. It was found that TBME is the most water soluble followed by NM and MCH. The solubility of water in the non-aqueous liquid was found to increase in the following order: MCH

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Space Charge Effects at Doped Ⅲ-Ⅴ Compound Semiconductor Interfaces (Doping된 Ⅲ-Ⅴ族 化合物 半導體 界面에서 空間電荷效果)

  • Chun, Jang-Ho
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.27 no.2
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    • pp.93-97
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    • 1990
  • Interfacil charge approximations and structures at doped semiconductor interfaces were proposed. Rectifying phenomena at the III-V compound semiconductor (p-GaP, p-InP, n-GaAs)/$CsNO_3$ aqueous electrolyte interfaces were qualitatively analyzed in terms of their cyclic current-voltage characteristics. The current-voltage characteristic curves, the ion adsorption and potential barrier processes at the semiconductor interfaces were verified using continuous cyclic voltammetric methods. The pn or np junction structures and the related rectifying types at the doped semi-condudtor-electrolyte inferfaces are determined by the space charges.

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Propylene Epoxidation Using Ti-MCM-22 Catalyst (Ti-MCM-22 촉매를 이용한 프로필렌 에폭시화반응)

  • Yang, Seung-Tae;Ban, Han-Ju;Kim, Se-Young;Ahn, Wha-Seung
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.665-668
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    • 2008
  • Propylene epoxidation by $H_2O_2$ (30% aqueous) as oxidant was studied in a semi-batch reactor using Ti-MCM-22 catalyst: Effects of reaction temperature, pressure, catalyst loading, solvent, and $H_2O_2$ concentration on $H_2O_2$ conversion (limiting reagent) were investigated. Product inhibition by propylene oxide was confirmed. Ti-MCM-22 maintained virtually the same catalytic performance over the 5 repeated cycles.

Effect of ethylenediamine tetra acetic acid additive on the nucleation kinetics and growth aspects of L-arginine phosphate single crystals

  • Kumar, R.Mohan;Babu, D.Rajan;Ravi, G.;Jayavel, R.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.4
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    • pp.153-156
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    • 2003
  • Pure and Ethylenediaminetetraacetic acid (EDTA) doped L-arginine phosphate (LAP) single crystals were grown from the aqueous solution by temperature lowering method. The effect of EDTA additive on the solubility and metastable zone width of LAP solution has been investigated. Addition of EDTA has enhanced the metastable zone width of LAP and hence bulk crystals could be grown. The growth rate along the [100] direction increases with EDTA additive. Powder X-ray diffraction and FTIR studies reveal the absence of EDTA in the lattice of LAP, This reveals that the addition of EDTA to LAP doesn't influence the crystallinity. However, the transmittance and NLO properties significantly increase with EDTA additive and hence bulk LAP crystals are useful for laser fusion experiments.

Development of Cleaning System of Electronic Components for the Remanufacturing of Laser Copy Machine (레이저 복합기의 재제조공정을 위한 전자부품 세정시스템의 개발)

  • Bae, Jae-Heum;Chang, Yoon-Sang
    • Clean Technology
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    • v.18 no.3
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    • pp.287-294
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    • 2012
  • In this study, performances of two cleaning methods were analyzed and a cleaning system was designed to develop a cleaning process of electronic components to remanufacture old laser copy machine. First, plasma cleaning as a dry cleaning method was executed to test cleaning ability. In cleaning of printed circuit board (PCB) by plasma, some damages were found near the metal parts, and considering the productivity, this method was not adequate for the cleaning of electronic components. With 4 different cleaning agents, ultrasonic cleaning tests were executed to select an optimal cleaning agent, aqueous agents showed superior cleaning performance compared to semi-aqueous and non-aqueous agents. Cleaning with aqueous cleaning agent A and 28 kHz ultrasonic frequency can be completed in 30 sec to 1 min. Finally, an ultrasonic cleaning system was constructed based on the pre-test results. Optimal cleaning conditions of 40 kHz and $50^{\circ}C$ were found in the field test. The productivity and economic efficiency in remanufacturing of laser copy machine are expected to increase by adapting developed ultrasonic cleaning system.

Pattern of Molecular Aggregation of Ginsenosides in Aqueous Solution (수용액(水溶液)에서 인삼배당체(人蔘配糖體)의 분자결합양상(分子結合樣相))

  • Park, Hoon;Lee, Mee-Kyoung;Park, Qwi-Hee
    • Applied Biological Chemistry
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    • v.29 no.2
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    • pp.198-206
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    • 1986
  • For the information on micellization at each ginsenoside level aqueous solution of purified saponin of Panax ginseng root was dialyzed through dialysis tubing (MW 12,000) or eluted through Bio-Gel P-2 (MW 200-2,000) and analysed for ginsenosides by high performance liquid chromatography. Ginsenosides can be classified into three groups depending upon molecular aggregation pattern and spatial arrangement of hydrophilic parts in molecule. Group I that is large micelle former(aggregation number: above 10) and one side hydrophilic part (HP) includes $ginsenoside\;Rb_1$, $Rb_2$, Rc and Rd (diols). Group II thai is small micelle former (aggregation number:>10-1) and semi-two sales HP includes $Rg_2$, Rf (triol) and $Rg_3$ (diol). Group III that is no micelle former (aggregation number: 1) and two sides HP includes Re and $Rg_1$ (triol).

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The Gelation Studies of PAA Polyelectrolytes in Aqueous Media (폴리 아크릴산 고분자전해질의 수용액 속에서의 겔화에 관한 연구)

  • Sohn, Jeong-In
    • Applied Chemistry for Engineering
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    • v.5 no.3
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    • pp.443-450
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    • 1994
  • Polyelectrolytes of various ionization degrees, which are prepared by neutralization of poly(acrylic acid)(PAA), were crosslinked by ethylane glycol diglycidyl ether(EGDE) in aqueous solution. $C_{gel}$, the minimum polymer concentration at which gelation occurs, was higher than expected. $C_{gel}$ was comparable with that of neutral polymer. This is considered to be due to the size contraction of polyelectrolyte, which comes from ionic strength increase as polymer concentration is increased. $C_{gel}$ is low when molecular weight of the sample becomes high. It reveals that polyelectrolyte is crosslinked in coil form not in extended rod form. This behavior is similar to the crosslinking of neutral polymers. Polyelectrolytes of partially ionized sample generally follow the behavior of fully ionized polyelectrolyte. Polyelectrolyte with added salt was also studied. Considering the pH dependence of EDGE reactivity it was difficult to compare the system which differs in pH significantly.

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Pseudo-Binary Diffusion Coefficients of Organic Aroma Component - I. The Diffusion Coefficient of Benzaldehyde in Aqueous Sugar Solution - (유기방향물질의 의사 2성분계 확산계수 - 제1보 : 설탕수용액중 Benzaldehyde의 확산계수 -)

  • Kang, An-Soo;Lee, Tae-Hee
    • Korean Journal of Food Science and Technology
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    • v.14 no.4
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    • pp.315-323
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    • 1982
  • The measurement of cell constant in a diaphragm-cell method is the most important factor. In order to get the correct cell constant, the diffusion coefficients of potassium chloride were measured, at various concentration and temperature of potassium chloride solution, and at the stirring rate in the cell. The pseudo-binary diffusion coefficients of organic aroma component (benzaldehyde) in sugar solution has been measured at various concentration and temperature with the cell constant obtained above. Experimental results were compared and discussed with the semi-empirical epuations from literatures. And, especially, the diffusion coefficient of benzaldehyde, $D_{ba}$ for a small solute diffusing in a viscous solvent of larger molecules is proportional to the -0.82 power of the viscosity of aqueous sugar solution, ${\mu}$ at constant temperature, $D_{ba}{\mu}^{0.82}=constant$.

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Evaluation of Advanced Oxidation Processes by Catalytic Ozonation with Mn-doped GAC (망간담지촉매를 이용한 오존/촉매 고급산화공정 평가)

  • Song, Seung-Ju;Oh, Byung-Soo;Na, Seung-Jin;Lee, Eung-Taek;Kang, Joon-Wun
    • Journal of Korean Society on Water Environment
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    • v.20 no.2
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    • pp.176-182
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    • 2004
  • The purpose of this study was to investigate the heterogeneous catalytic ozonation of oxalic acid by manganese (Mn) doped-granular activated carbon (GAC). In order to observe the effect of the amount of Mn doped on GAC, catalysts were manufactured by varying the impregnated Mn concentration. In this paper, the following had labeled all sorts kinds of Mn-doped GAC were labeled with suitable names according to the amount (mM) of the concentration of dipping solution: They were each named as 'Mn20', 'Mn50', 'Mn100' and 'Mn200'. These experiments were performed in a batch reactor (0.5 L) and a semi-batch reactor (1 L) and Mn-free GAC was used as a blank catalyst. The ozone decay properties of each manufactured catalyst were firstly investigated to find out the reactivity between the aqueous ozone and the catalysts. Oxalic acid removal by catalytic ozonation was then performed to demonstrate the oxidative efficiencies of each catalyst.