• Journal of Electrochemical Science and Technology
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• v.11 no.4
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• pp.379-383
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• 2020

The novel voltammetry using a semi-circular potential wave for quasi-reversible charge transfer system on electrode is theoretically investigated. Compared with conventional voltammetry based on linear sweep such as linear sweep voltammetry (LSV), semi-circular potential sweep voltammetry (SCV) may decrease the charging current outside the center of potential range and increase the faradaic current at the midpoint due to variable scan rate. In this paper, we investigate the system based on macroelectrode where simple 1 dimensional (1 D) diffusion system is valid with various charge transfer rate constant (k₀). In order to observe the amplification at midpoint, voltammetric response with different midpoint ranging from -200 mV to 200 mV are studied. SCVs shows both the shift of peak potential and the amplification of peak current for quasi-reversible electrode reaction while only higher peak current is observed for reversible reaction. Moreover, the higher current at midpoint enable the amplification of current at low overpotential region which may assist the determination of onset potential as a figure-of-merit in electrocatalyst.

• Bulletin of the Society of Naval Architects of Korea
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• v.23 no.4
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• pp.25-34
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• 1986

A two-dimensional linear method has been developed for the motion and the second-order steady force arising from the hydrodynamic coupling between waves and currents in the presence of a body of arbitrary shape. Interaction between the incident wave and current in the absence of the body lies in the realm beyond our interest. A Fredholm integral equation of the second kind is employed in association with the Haskind's potential for a steadily moving source of pulsating strength located in or below the free surface. The numerical calculations at the preliminary stage showed a significant fluctuation of the hydrodynamic forces on the surface-piercing body. The problem is approximately solved by using the asymptotic Green function for $U^2{\rightarrow}0$. The original Green function, however, is applied for the fully submerged body. Numerical calculations are made for a submerged and for a half-immersed circular cylinder and extensively for the mid-ship section of a Lewis-form. Some of the results are compared with other analytical results without any available experimental data. The current has strong influence on roll motion near resonance. When the current opposes the waves, the roll response are generally negligible in the low frequency region. The current has strong influence on roll motion near resonance. When the current opposes the wave, the roll response decreases. When the current and wave come from the same direction, the roll response increases significantly, as the current speed increases. The mean drift forces and moment on the submerged body are more affected by current than those on the semi-immersed circular cylinder or on the ship-like section in the encounter frequency domain.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.2 s.173
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• pp.496-505
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• 2000

A semi-infinite parallel crack propagated with constant velocity in two bonded anisotropic strip under anti-plane clamped displacement is analyzed. Using Fourier integral transform a Wiener-Hopf equation is derived. By solving this equation the asymptotic stress and displacement fields near the crack tip are determined, where the results give the more general expression applicable to the extent of the anisotropic material having one plane of elastic symmetry for the parallel crack. The dynamic stress intensity factor and energy release rate are also obtained as a closed form, which are the results applicable to the problem both of dynamic and static crack under the same geometry as this study. The stress intensity factor approaches zero at the critical crack velocity which is less than the shear wave velocity, but in typical case of isotropic or orthotropic material agrees with the velocity of shear wave. Also a circular shear stress around crack tip is considered, from which the stress is shown to be approximately symmetric about the horizontal axis. Referring to the maximum stress criteria, it could be shown that a brenched crack is formed by crack growth as crack velocity increases.