• 제목/요약/키워드: Self-Patterning

검색결과 115건 처리시간 0.031초

우포늪 범람에 의한 먼지벌레류(딱정벌레목, 딱정벌레과)의 다양성과 종조성 변화 (Change of Carabid Beetle (Coleoptera, Carabidae) Diversity and Species Composition after Flooding Events in Woopo Wetlands)

  • 도윤호;장민호;김동균;주기재
    • 생태와환경
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    • 제40권2호
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    • pp.346-351
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    • 2007
  • Change of carabid beelte (Coleoptera, Carabidae) diversity and population structures in Woopo Wetlands (Changneung-Gun, Gyeungsangnam-Do, S. Korea) were investigated after flooding events. During the investigation period, 11 species belonging to five genera were identified. Dolichus halensis halensis(Schaller), Chlaenius (Ch.) pallipes Gebler, Ch. (Ilaenchus) naeviger Morawitz, and Pheropsophus (Stenaptinus) jessoensis Morawitz were the predominant species in Woopo Wetlands. Floods occurred twice, August and September in 2004. After the flooding events, species diversity decreased and species assemblage structures changed dramatically. Changes of the diversity and species assemblage structures were more evident in August then in September, because water level was much higher and inundation period was longer than September. A non-linear patterning algorithm of the Self-Organizing Map (SOM) was applied to discover the relationship between flooding events and carabid beetles community dynamics. Although abundance of the majority species decreased after the flooding events, that of the predominant species increased. Further detailed studies on species distribution and emigration patterns will likely bring a new insight in understanding of the adaptation mechanism of carabid beetles in wetlands.

Oligothiophene-based Semi-Conducting Nanostructures: from Solution to Solid-State Aggregates

  • Leclere, Ph.;Surin, M.;Lazzaroni, R.;Feast, W.J.;Schenning, A.P.H.J.;Meijer, E.W.
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.304-304
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    • 2006
  • The possibility to develop optoelectronic devices with improved properties by controlling the degree of organization at the molecular level of organic materials has been driving the design of new ${\pi}-conjugated$ systems. In particular, the organization by self-assembling processes (${\tilde{\Box}}{\d{\Box}}}$ interactions, hydrogen bonding) of well-defined oligomeric systems such as disubstituted oligothiophene derivatives has been demonstrated as a promising approach to conjugated materials with a high degree of structural order of the constituent building blocks. The self-organization of conjugated building blocks in solution or on surfaces, leading to the construction of nanoscopic and mesoscopic architectures, represents a starting point for the construction of molecular electronics or even circuits, through surface patterning with nanometer-sized objects.

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노년기 예방검진에서 사회경제적 불평등 (Socioeconomic Inequalities in Preventive Services among the Elderly: Results from Medical Checkup, Cancer Check, and BP Check)

  • 천희란;김일호
    • Journal of Preventive Medicine and Public Health
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    • 제40권5호
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    • pp.404-410
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    • 2007
  • Objectives: Due to the assumptions of homogeneity as well as challenges in the socioeconomic position of the elderly, they have been relatively neglected in studies of health inequalities. Therefore, this study was conducted to investigate the social inequalities in preventive services among elderly men and women. Methods: Data were obtained from a nationally representative sample of 342 men and 525 women aged 65 and over collected during the 2001 National Health and Nutrition Examination Survey. Age adjusted proportions and logistic regression were used to identify the social patterning of preventive services among elderly Koreans using various social position indicators. Results: The findings of this study generally supported the presence of social gradients in preventive services among the Korean elderly. The likelihood of using the service becomes progressively higher with social position. Educational level, income, and self-rated living status were significantly associated with increased medical checkups and cancer checks. In addition, logistic regression detected educational inequalities only among older women receiving BP checks. After being stratified based on health status and chronic disease status, social disparities still existed when educational level and self-rated living status were considered. Among unhealthy individuals, place of residence was observed as a barrier to medical checkups. Conclusions: This study demonstrated strong and consistent associations between socioeconomic position and preventive services among the elderly in Korea. The results indicate that public health strategies should be developed to reduce the barriers to preventive services encountered by the elderly.

SC1 세척공정을 이용한 고품질 Poly(3,4-ethylenedioxythiophene) 전극 패턴 어레이의 개발 (Development of High-Quality Poly(3,4-ethylenedioxythiophene) Electrode Pattern Array Using SC1 Cleaning Process)

  • 최상일;김원대;김성수
    • 통합자연과학논문집
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    • 제4권4호
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    • pp.311-314
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    • 2011
  • Application of self-assembled monolayers (SAMs) to the fabrication of organic thin film transistor has been recently reported very often since it can help to provide ohmic contact between films as well as to form simple and effective electrode pattern. Accordingly, quality of these ultra-thin films is becoming more imperative. In this study, in order to manufacture a high quality SAM pattern, a hydrophobic alkylsilane monolayer and a hydrophilic aminosilane monolayer were selectively coated on $SiO_2$ surface through the consecutive procedures of a micro-contact printing (${\mu}CP$) and dip-coating methods under extremely dry condition. On a SAM pattern cleaned with SC1 solution immediately after ${\mu}CP$, poly(3,4-ethylenedioxythiophene) (PEDOT) source and drain electrode array were very selectively and nicely vapour phase polymerized. On the other side, on a SC1-untreated SAM pattern, PEDOT array was very poorly polymerized. It strongly suggests that the SC1 cleaning process effectively removes unwanted contaminants on SAM pattern, thereby resulting in very selective growth of PEDOT electrode pattern.

주사슬에 말로네이트기를 가지는 신규 폴리에스테르의 합성과 광분해 특성을 이용한 형광 이미지 패터닝 (Synthesis of Novel Network Polyesters Containing Malonate Group in Main Chain and Their Fluorescence Image Patterning via Photodegradation)

  • 정선주;곽기섭;정인태;이동호;노형진;윤근병
    • 폴리머
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    • 제32권1호
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    • pp.56-62
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    • 2008
  • Diol과 diacid 단량체들의 다양한 조합으로 2단계 축합중합으로 가교구조를 가지는 세 종류의 신규 폴리에스테르를 새롭게 합성하였다. 이들 고분자 필름은 $240^{\circ}C$에서 수 시간 고온 열처리하면, 주사슬에 의한 금지 전이에도 불구하고, 가시영역에서 흡수를 나타내었으며 330 nm 이상의 파장에서 여기시키면 청색에서 근적외선에 이르는 넓은 범위에서 발광을 나타내었다. 신규 폴리에스테르의 발광 현상은 주사슬에 포함된 말로네이트기가 고온 열처리를 통해 자기축합 형태의 Knoevenagel 반응을 일으켜 분자 내 공역구조를 형성하기 때문이다. 또한 이들 고분자의 열적 특성은 가지화도 차이에 의한 화학적 가교정도에 따라 현저한 차이를 보였을 뿐 아니라 광분해 현상도 관찰되었다. 필름 상태에서 강한 자외선을 조사하여 말로네이트기의 분해반응을 유도하고, 이를 이용한 형광 이미지 패터닝을 수행한 결과, 고해상도의 이미지 패턴을 얻을 수 있었다.

실리콘 결정면을 이용한 LCD-BLU용 도광판의 미세산란구조 형성 (Micro-patterning of light guide panel in a LCD-BLU by using on silicon crystals)

  • 최가을;이준섭;송석호;오차환;김필수
    • 한국광학회지
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    • 제16권2호
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    • pp.113-120
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    • 2005
  • LCD-BLU(liquid crystal device-back light unit)에 사용되는 도광판의 미세 산란패턴을 만드는 새로운 방법으로서, 실리콘 웨이퍼의 비등방 식각에 의해 자연적으로 형성되는 3차원 결정면 구조를 이용하는 방법을 제안하였다. 실리콘 3차원 결정면을 갖는 도광판과 프리즘 시트의 원판을 설계 및 제작하였고, casting 공정을 통해 PDMS 재질로 복제된 도광판을 제작하여 특성을 분석하였다. 측정 결과, 기존 인쇄형 도광판에 비해 실리콘피라미드 패턴의 도광판이 $10\%$ 증가된 정면 휘도 효율을 가질 수 있음을 실험적으로 검증하였다.

표면 플라즈몬 현미경을 이용한 자기조립 단분자막의 이미징 (Imaging of self-assembled monolayers by surface plasmon microscope)

  • 표현봉;신용범;윤현철;양해식;김윤태
    • 한국광학회지
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    • 제14권1호
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    • pp.97-102
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    • 2003
  • 이차원 표면 플라즈몬의 공명 흡수와 포토 마스크를 이용하여 11-MUA(11-Mercaptoundecanoic acid)와 11-MUOH(11-Mercaptoundecanol) 둥으로 이루어진 자기조립 단분자막(Self-Assembled Monolayer; SAM)의 다채널 영상을 얻었다. 통상의 Photoresist를 이용한 리토그래피 대신에 Thiol bonding의 광산화를 이용하여 패터닝 과정을 줄이고, 백색광 및 대역통과 필터(λ$_{0}$=633nm)를 이용하여 입사광으로써 레이저를 사용할 때 나타나는 간섭무늬를 줄였다. 이로부터 나타나는 이차원 영상의 명암을 정량적으로 보정하면 수 나노미터(nm) 두께의 변화를 측정할 수 있다. 또한 표면 플라즈몬 공명법은 국소화된 근접장 (소산장)을 이용하는 방법으로서, 통상 많이 이용되는 형광법 등에서 나타나는 광탈색(Photobleaching)이나 소광(Quenching) 현상이 없이 시료의 처리가 간단하고, 영상 신호의 시간에 따른 변화가 극히 적으며, 실시간으로 신호의 변화를 측정할 수 있다는 장점이 있다.

High-Performance Single-Crystal Organic Nanowire Field-Effect Transistors of Indolocarbazole Derivatives

  • 박경선;정진원;성명모
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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    • pp.368-368
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    • 2012
  • We report solution-processed, high-performance single-crystal organic nanowire transistors fabricated from a novel indolocarbazole (IC) derivative. The direct printing process was utilized to generate single-crystal organic nanowire arrays enabling the simultaneous synthesis, alignment and patterning of nanowires using molecular ink solutions. Using this method, single-crystal organic nanowires can easily be synthesized by self-assembly and crystallization of organic molecules within the nanoscale channels of molds, and these nanowires can then be directly transferred to specific positions on substrates to generate nanowire arrays by a direct printing process. These new molecules are particularly suitable for p-channel organic field-effect transistors (OFETs) because of the high level of crystallinity usually found in IC derivatives. Selected area diffraction (SAED) and X-ray diffraction (XRD) experiments on these solution-processed nanowires showed high crystallinity. Transistors fabricated with these nanowires gave a hole mobility as high as 1.0 cm2V-1s-1 with nanowire arrays with the direct printing process.

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Liquid Crystal Droplet Patterns to Monitor Catalase Activity at Femtomolar Levels

  • Yoon, Stephanie;Jang, Chang-Hyun
    • Bulletin of the Korean Chemical Society
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    • 제35권9호
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    • pp.2704-2710
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    • 2014
  • Catalase (CAT) decomposes hydrogen peroxide that is toxic to the body. In this study, simple and sensitive detector has been developed for observing catalase activity using liquid crystal droplet system. Microscale LC droplet patterns are formed by spreading aldehyde-doped nematic liquid crystal on pre-treated glass slides. When hydrogen peroxide is added, aldehyde is oxidized and amphiphiles are formed. Dodecanoates cause the pattern to transit from bright to dark as they self-assemble to form a carboxyalte monolayer at the interface. When a drop of pre-incubated CAT and hydrogen peroxide mixture is placed onto the pattern, bright fan-shape is observed. This planar optical appearance indicates that catalase has decomposed hydrogen peroxide. Compared to the detectors that have been previously developed, this system is more sensitive with detection limit of 1fM. This research suggests further studies to be on LC droplet patterning to develop highly sensitive and methodologically simple sensors for various chemicals.

Nanopatterning of Proteins Using Composite Nanomold and Self-Assembled Polyelectrolyte Multilayers

  • Kim, Sung-Kyu;Kim, Byung-Gee;Lee, Ji-Hye;Lee, Chang-Soo
    • Macromolecular Research
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    • 제17권4호
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    • pp.232-239
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    • 2009
  • This paper describes the simple nanopatterning of proteins on polyelectrolyte surfaces using microcontact printing with a nanopatternable, hydrophilic composite nanomold. The composite nanomold was easily fabricated by blending two UV-curable materials composed of Norland Optical Adhesives(NOA) 63 and poly(ethylene glycol) dimethacrylate(PEG-DMA). NOA 63 provided stable nanostructure formation and PEG-DMA induced high wettability of proteins in the nanomold. Using the composite mold and functionalized surface with polyelectrolytes, the fluorescent, isothiocyanate-tagged, bovine serum albumin(FITC-BSA) was successfully patterned with 8 nm height and 500 nm width. To confirm the feasibility of the protein assay on a nanoscale, a glycoprotein-lectin assay was successfully demonstrated as a model system. As expected, the lectins correctly recognized the nano-patterned glycoproteins such as chicken ovalbumin. The simple preparation of composite nanomold and functionalized surface with a universal platform can be applied to various biomolecules such as DNA, proteins, carbohydrates, and other biomolecules on a nanoscale.