• Title/Summary/Keyword: Self diffusion

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A study on the spray characteristics of a coaxial nozzle by LDV measurement (LDV계측에 의한 동축노즐의 분무특성 연구)

  • 윤석주;노병준
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.6
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    • pp.1613-1620
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    • 1990
  • For the purpose of the study on the spray characteristics of a coaxial nozzle, the measurement of the velocity and size of droplets, concentration, and the statistical correlation coefficient between the fluctuation of the velocity and that of the corresponding drop diameter have been carried out. Various method of simultaneous measurement of velocity and drop size have been developed from LDV techniques. The technique used here belongs to the method that supposed by Yule, Holve and Self. It has the advantages of making use of a standard LDV apparatus to which minor modifications have been brought, photomultiplier is equipped with a slit instead of a pinhole and observed the measuring volume at an angle of 90.deg.. The voltage supplied by the photomultiplier has undergone an appropriate analog and digital processing. The experimental results give a good idea of the two phase flow organization and can be helpful to find a drop diffusion model when suitable data are imput.

Molecular Theory of Plastic Deformation (II). Applications (소성변형의 분자론 (제2보). 응용)

  • Kim, Chang Hong;Ree Taikyue
    • Journal of the Korean Chemical Society
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    • v.21 no.5
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    • pp.339-352
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    • 1977
  • The authors' theory developed in the preceding Paper 1 was applied to plastic deformation of ceramics, metals, alloys and single crystals. For polycrystalline substances, the flow mechanisms due to dislocation movement and grain boundary movement appear together or separately according to the experimental conditions whereas for single crystals, only the mechanism of dislocation movement appears. The parameters appearing in the flow equations $({\alpha}_{d1},\;1/{\beta}_{d1})and\;({\alpha}_{gj}/X_{gj},\;1/{\beta}_{gj})$ (j = 1 or 2), and the activation enthalpies ${\Delta}H_{k1}^{\neq}$ (k = d or g) were determined and tabulated. Here, the subscript d1 indicates the first kind of dislocation flow units and gj expresses the jth kind of grain boundary flow units. The predictions of the theory were compared with experiment with good agreement. Concerning the activation enthalpies, it was found that ${\Delta}H_{d1}^{\neq}$ 〉{\Delta}H_{g1}^{\neq}$ and that the former agrees with the activation enthalpy for bulk self-diffusion whereas the latter agrees with the activation enthalpy for grain boundary self-diffusion. These facts support the adequacy of the authors' theory which is considered as a generalized theory of plastic deformation.

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Basal slip (0001)1/3<1120> dislocation in sapphire ($\alpha$-Al$_2$O$_3$) single crystals Part I : recombination motion (사파이어($\alpha$-Al$_2$O$_3$) 단결정에 있어 basal slip (0001)1/3<1120>전위 Part I : 재결합거동)

  • Yoon, Seog-Young
    • Korean Journal of Materials Research
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    • v.11 no.4
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    • pp.278-282
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    • 2001
  • The recombination motion of Partial dislocations on basal slip (0001) 1/3<1120> in sapphire ($\alpha$-Al$_2$$O_3$) single crystals was investigated using the four-point bending test with the prism plane (1120) samples. These bending experiments were carried but in the temperature range from $1200^{\circ}C$ to $1400^{\circ}C$ at various engineering stresses 90MPa, 120MPa, and 150MPa. During these tests it was shown that an incubation time was needed for basal slip to be activated. The activation energy for the incubation time was 5.6-6.0eV in the temperature range from $1200^{\circ}C$ to $1400^{\circ}C$. The incubation time is believed to be related to recombination of climb dissociated partial dislocations via self-climb. In addition, these activation energies are nearly same as those for oxygen self-diffusion in $Al_2$$O_3$ (approximately 6.3 eV). Thus, the recombination of the two partial dislocations would be possibly controlled by oxygen diffusion on the stacking fault between the partials.

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Sizes and Structures of Micelles of Cationic Octadecyl Trimethyl Ammonium Chloride and Anionic Ammonium Dodecyl Sulfate Surfactants in Aqueous Solutions

  • Kim, Hong-Un;Lim, Kyung-Hee
    • Bulletin of the Korean Chemical Society
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    • v.25 no.3
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    • pp.382-388
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    • 2004
  • The sizes and structures of micelles formed in aqueous solutions of cationic octadecyl trimethyl ammonium chloride (OTAC) and anionic ammonium dodecyl sulfate (ADS) surfactants were investigated using smallangle neutron scattering (SANS), self-diffusion coefficients by pulsed-gradient spin-echo (PGSE) NMR, and dynamic light scattering (DLS) methods. SANS and DLS data indicate that their structures are spherical at concentrations as high as 300 mM. As the total surfactant concentration increases, the peaks of SANS spectra shift to higher scattering vector and become sharper, indicating that the intermicellar distance decreases and its distribution becomes narrower. This is due to more compact packing of surfactant molecules at high concentrations. The intermicellar distance of around 100 ${\AA}$ above 200 mM corresponds approximately to the diameter of one micelle. The sizes of spherical micelles are 61 ${\AA}$ and 41 ${\AA}$ for 9 mM OTAC and 10 mM ADS, respectively. Also the self-diffusion coefficients by PGSE-NMR yield the apparent sizes 96 ${\AA}$ and 31 ${\AA}$ for micelles of 1 mM OTAC and 10 mM ADS, respectively. For ADS solutions of high concentrations (100-300 mM), DLS data show that the micelle size remains constant at $25{\pm}2{\AA}$. This indicates that the transition in micellar shape does not take place up to 300 mM, which is consistent with the SANS results.

Studies on the Micelle Formation of Nonionic Surfactant(1) -1NMR Self-Diffusion and Proton Relaxation of Polyoxyethylene Alkyl Ether- (계면활성제 수용액의 미셀형성(제1보) - Polyoxyethylene Alkyl Ether의 자기확산과 프로톤 이완 -)

  • Choi, Seung-Ok;Jeong, Hwan-Kyeong;Lee, Jin-Hee;Nam, Ki-Dae
    • Applied Chemistry for Engineering
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    • v.9 no.6
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    • pp.822-828
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    • 1998
  • Binary system of water and polyoxyethylene dodecyl ether, $C_{12}H_{25}(OCH_2CH_2)nOH$, have been studied by $^1H$ NMR techniques. For n=5($C_{12}EO_5$) and n=8($C_{12}EO_8$), the self-diffusion coefficients of nonionic surfactants in the isotropic phase($L_1$) have been measured by using pulsed field gradient technique for a range of temperature and concentrations. In addition the line widths of the different proton signals have been monitored, and samples of some liquid crystalline characteristic were also studied. Dramatic Broadening of the methylene signals of the alkyl($C_{12}H_{25}$) chain is observed as the hexagonal liquid crystalline phase is approached in the $C_{12}EO_5-$water system, while only small broadening is observed in the $C_{12}EO_8-$water system. It was shown that there was a growth of $C_{12}EO_5$ micelles to rods with increasing concentrations, while the $C_{12}EO_8-$ micelles at low temperature remain small in the concentration range. The self-diffusion coefficients of the surfactants decrease rapidly with increasing concentration until a minimum is reached after which there is slow increase. The location of the minimum point occurs at lower concentrations the temperature is close to the cloud point, where the system separate into two isotropic phase. In the line width studies, broadening is found at a certain temperature interval when the concentration is increased in the $C_{12}EO_5$ system. The results indicate that the surfactant aggregates grow in size at the cloud point is approached. The aggregates seem to be flexible and probably not to be of a definite shape close to the cloud point. In the $C_{12}EO_8$ system, the micelles are much less affected by an increase in temperature and micellar growth can't be unambiguously established. The methylene signals of the ethylene oxide moieties consistantly show narrower $^1H$ signals, showing that in the aggregates they are less ordered than the chain methylenes. The various changes in aggregate size and shape are correlated with the stability ranges of the isotropic and liquid crystalline phases according to phase diagrams from the literature. Both aggregate size and phase structure are in qualitative agreement with concentration based on the effective shape of the molecules at different temperature and concentration.

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Self-healing Performance Evaluation of Cement Mortar with Inorganic Additives Based on Clinker Binder (클링커 바인더 기반 무기계 혼합재를 활용한 시멘트 모르타르의 치유성능 평가)

  • Jung-Il, Suh;Yoon-Suk, Choi;Byung-Sun, Park;Kwang-Myong, Lee
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.561-568
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    • 2022
  • In this study, the mechanical properties and self-healing performance of cement mortar containing clinker binder, calcium sulfoaluminate(CSA), and sodium sulfate(Na2SO4) were evaluated. The mechanical properties of cement mortar were investigated by measuring compressive strength and flexural strength, and the healing performance was evaluated through hydrostatic water permeability test and gas diffusion test. In addition, the healing products precipitated in the cracks were visually observed through an optical microscope and a scanning electron microscope(SEM). As a result, the incorporation of the clinker binder-based inorganic additives improved the initial and 28-day strength by about 20 %. Depending on the healing performance evaluation method, there was a difference in the healing rate, and the healing rate showed a tendency to be underestimated. Nevertheless, CaCO3 was precipitated as the main healing product inside the 0.3 mm crack when the inorganic additives were mixed with cement mortar, improving the self-healing performance.

A Study on Improvement of Halftoning using Random Space Filling Curve (무작위 공간 채움 곡선을 이용한 하프토닝의 개선 방안)

  • Jho, Cheung-Wonn
    • Journal of Digital Convergence
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    • v.12 no.1
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    • pp.415-421
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    • 2014
  • In this paper, we proposed problem and improvement of halftoning using random space filling curve. Random space filling curve is developed as a solution for shortcoming which space filling curve has self-similarity. It is used to reduce regular pattern can be occurred in constant brightness area in order that randomness apply to scanning path. But there is a problem that some area along scanning path can show too bright result in halftoning using random space filling curve. In this paper, we analyzed cause of problem and proposed single pixel error diffusion as a solution method. This method can avoid over-accumulated error and show better result in halftoning.

Exploring Factors Influencing Usage Intention of Chatbot - Chatbot in Financial Service (챗봇 사용 의도에 영향을 미치는 요인 탐색 - 금융 서비스에서의 챗봇)

  • Lee, Min Kyu;Park, Heejun
    • Journal of Korean Society for Quality Management
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    • v.47 no.4
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    • pp.755-765
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    • 2019
  • Purpose: Chatbots are widely diffusing across various industries to substitute human manpower in the industry. However as researchers only develop technology that is applied to chatbot, the diffusion is slow in progress. The purpose of this study is to propose useful implications to accelerate diffusion of chatbots across industries by analyzing the perception of customers. To achieve the research purpose this study analyzes causal effect relationship between characteristics of chatbot character, service quality, individual difference, and intention to use chatbot. Methods: This study developed a survey that contains various questionnaires for each construct based on literature review. Data collected through survey was tested for convergent validity and discriminant validity and further analyzed the relationship using PLS-SEM method to verify hypotheses. Results: Trustworthiness of the chatbot character, ease of use, application design, responsiveness, customization, assurance, inertia, and previous experience have significant influence on forming user satisfaction, consumer trust, and intention to use. The others, likability, appropriateness, technology anxiety, and need for interaction were not significant in this research. Conclusion: Although the constructs of the research model was significant in previous literatures, some do not have significant effect on intention to use chatbots. Based on the results, chatbot managers will be able to develop chatbot systems which are more appealing to users and more academic researchers will focus on analyzing user perception and intention.

An Experimental Study of Verification for PEMFC's 1-Dimensional Simulation (PEMFC 1차원 시뮬레이션 검증을 위한 실험적 연구)

  • Moon, Cheor-Eon;Ahn, Seong-Yool;Yang, Jang-Sik;Choi, Gyung-Min;Kim, Duck-Jool
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.191-195
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    • 2007
  • In this study, we estimated the performance of PEMFC's unit cell as changing operating temperature in different inlet humidity condition at cathode side but anode dry, and tried to match experimental results with 1-dimensional simulation. We used $Nafion^{\circledR}112$ membrane and a self-manufactured PEMFC with active area of $25cm^{2}$ was used in this study. The range of operating temperature was $40{\sim}70^{\circ}C$ and oxygen through bubbled humidity chamber was supplied $0{\sim}80$% humidity condition as changing water temperature in humidity chamber. For figuring out governing equations, represent water contents in electrolyte membrane, the linear forward difference method was applied about time progress and quadratic central difference method was used about space progress. It was assumed that pressure terms were linearly changed due to thin electrolyte membrane. In low operating temperature condition, $40{\sim}60^{\circ}C$, increasing temperature rarely effected cell performance but we can see performance drop at $70^{\circ}C$. By modifying Henrry's constant and/or diffusion coefficient, the modified one-dimensional model was accomplished for calculation.

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Low-power Routing Algorithm using Routing History Cache for Wireless Sensor Network (RHC(Routing History Cache)를 사용한 저전력 소모 라우팅 알고리즘)

  • Lee, Doo-Wan;Jang, Kyung-Sik
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.13 no.11
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    • pp.2441-2446
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    • 2009
  • Wireless Sensor Network collects a data from the specific area and the control is composed of small sensor nodes. Like this sensors to after that is established at the beginning are operated with the battery, the operational duration until several years must be continued from several months and will be able to apply the resources which is restricted in efficiently there must be. In this paper RHC (rounting history cache) applies in Directed Diffusion which apply a data central concept a reliability and an efficiency in data transfer course set. RHC algorithms which proposes each sensor node updated RHC of oneself with periodic and because storing the optimization course the course and, every event occurrence hour they reset the energy is wasted the fact that a reliability with minimization of duplication message improved.