• 제목/요약/키워드: Segregation effect

검색결과 233건 처리시간 0.026초

Ge를 첨가한 Nb$_3$Sn 초전도 선에서의 교류손실 및 미세조직 변화 (Influence of Ge addition on AC loss and micro-structure in $Nb_{3}Sn$ wires)

  • 하도우;이남진;오상수;하홍수;송규정;권영길;류강식
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
    • /
    • pp.104-107
    • /
    • 2001
  • In order to investigate the effect of Ge addition to the Cu matrix on the microstructure and the critical current density, four kinds of internal tin processed Nb$_3$Sn strands with pure Cu and Cu 0.2, 0.4, 0.6 wt % Ge alloys were drawn to 0.8 mm diameter. The microstructure and critical current of internal tin processed Nb$_3$Sn wires that were heat treated at temperatures ranging from 68$0^{\circ}C$ to 74$0^{\circ}C$ for 240h were investigated. The Ge addition to the matrix did not make workability worse. A Ge rich layer in the Cu-Ge matrix suppressed the growth of the Nb$_3$Sn layer and promoted grain coarsening. The greater the Ge content in the matrix, the lower the net Jc result after Nb$_3$sn reaction heat treatment. There was no significant variation in Jc observed with heat treatment temperature ranging from 68$0^{\circ}C$ to 74$0^{\circ}C$. The values of AC loss of Ge added wires were decreased to 40 % compare with no addition wire. Low AC loss was due to segregation of Ge rich layer in the Cu-Ge matrix. If Ge added wire with thin Nb filaments were fabricated, slow diffusion rate of Sn would be overcome and decreased AC loss that is weak Point of internal tin method.

  • PDF

12% Cr 로터강의 강도 개선에 관한 연구 (Study on the Improvement of Strength for 12% Chromium Steel Rotor)

  • 장윤석;오세욱
    • 한국해양공학회지
    • /
    • 제3권2호
    • /
    • pp.125-137
    • /
    • 1989
  • To check technical improvement in the soundness and strength of 12% Cr steel rotor, a 25 tons of rotor with 65 tons of ingot was made in real size and was cut to pieces to take test samples, and the various mechanical tests such as impact, tensile, creep, and fatigue were carried out. The strengths are compared with those of 1% Cr-Mo-V rotor of same size. Microstructures of the samples are examined and reviewed. The results can be summarized as follows. 1) Fracture appearance transition temperatures are 80.deg. C at the center part and 60.deg. C near surface of 12% Cr rotor, and 8.deg. C near surface of 1% Cr-Mo-V rotor. 2) Comparative rapid softening occurs at higher temperatures above 600.deg. C for 12% Cr steel and 550.deg. C for 1% Cr-Mo-V steel in tension tests. 3) Fatigue crack propagation rate of 12% Cr steel is almost same as that of 1% Cr-Mo-V steel at the same corresponding surface part of the rotors. The crack growth rate of center part of 12% Cr rotor is faster than near surface part of the rotor, and the crack growth rate at the load condition of R=0.04 is slower than that of the load condition of R=0.5 for both 12% Cr steel and 1% Cr-Mo-V steel. 4) Crack growth rate of radial direction near surface of 12% Cr rotor is faster than that of transverse direction at the same part because of the difference in residual stresses. 5) Both creep and fatigue strengths of 12% Cr steel are superior to those of 1% Cr-Mo-V steel and the difference is thought the effect of climb and glide controlled creep by solid solution of alloying elements and dispersion of carbides.

  • PDF

12% Cr 로터강의 강도 개선에 관한 연구 (Study on the Improvement of Strength for 12% Chromium Steel Rotor)

  • 장윤석;오세욱
    • 한국해양공학회지
    • /
    • 제3권2호
    • /
    • pp.625-625
    • /
    • 1989
  • To check technical improvement in the soundness and strength of 12% Cr steel rotor, a 25 tons of rotor with 65 tons of ingot was made in real size and was cut to pieces to take test samples, and the various mechanical tests such as impact, tensile, creep, and fatigue were carried out. The strengths are compared with those of 1% Cr-Mo-V rotor of same size. Microstructures of the samples are examined and reviewed. The results can be summarized as follows. 1) Fracture appearance transition temperatures are 80.deg. C at the center part and 60.deg. C near surface of 12% Cr rotor, and 8.deg. C near surface of 1% Cr-Mo-V rotor. 2) Comparative rapid softening occurs at higher temperatures above 600.deg. C for 12% Cr steel and 550.deg. C for 1% Cr-Mo-V steel in tension tests. 3) Fatigue crack propagation rate of 12% Cr steel is almost same as that of 1% Cr-Mo-V steel at the same corresponding surface part of the rotors. The crack growth rate of center part of 12% Cr rotor is faster than near surface part of the rotor, and the crack growth rate at the load condition of R=0.04 is slower than that of the load condition of R=0.5 for both 12% Cr steel and 1% Cr-Mo-V steel. 4) Crack growth rate of radial direction near surface of 12% Cr rotor is faster than that of transverse direction at the same part because of the difference in residual stresses. 5) Both creep and fatigue strengths of 12% Cr steel are superior to those of 1% Cr-Mo-V steel and the difference is thought the effect of climb and glide controlled creep by solid solution of alloying elements and dispersion of carbides.

주강의 유화물 형태와 편석에 대한 연구 (II) (Fe-Mn-S 합금의 유화물 형태에 미치는 Mn/S비의 영향) (Morphology and Segregation of Sulfide Inclusions in Cast Steels (II) (Influence of [Mn/S] Ratios on the Morphology of Sulfide Inclusions in Fe-Mn-S Alloys))

  • 박흥일;김지태;김우열
    • 한국주조공학회지
    • /
    • 제29권6호
    • /
    • pp.270-276
    • /
    • 2009
  • After casting button-type small ingots of ternary Fe-Mn-S alloys which had three different Mn/S ratios (1, 5 and 70) in a vacuum arc furnace, the effect of the ratio on the sulfide formation was investigated. In case of the Mn/S ratio of 1, if alloy composition was located in an iron-rich corner on a Fe-Mn-S ternary phase diagram, only duplex MnS-FeS sulfide films were observed in the grain boundary. If the alloy composition was located in the miscibility gap area of the phase diagram, primary globular dendritic sulfides and dendritic sulfide slags were generated within the grain and tubular monotectic sulfides were also detected in the grain boundary. When the Mn/S ratio was 5, if the alloy composition was in the iron-rich corner, only bead-like sulfides were generated. On the other hand, if the composition was in the miscibility gap area, globular dendritic sulfides and dendritic sulfide slags were generated in the form of primary sulfide inclusions and rod-like eutectic sulfides were observed in the grain boundary. Especially, if the contents of Mn and S increased more in the miscibility gap area of the phase diagram, primary globular sulfides containing iron intrusions were observed. In case of Mn/S ratio of 70, if the contents of Mn and S was decreased in the Fe corner of the phase diagram, only bead-like sulfides were observed in the grain boundary. Despite the composition was outside the miscibility gap area of the phase diagram, if the contents of Mn and S increased, clusters of fine sulfide particles as well as fine spherical primary monophase sulfides were observed in the grain boundary.

Durability assessment of self-compacting concrete with fly ash

  • Deilami, Sahar;Aslani, Farhad;Elchalakani, Mohamed
    • Computers and Concrete
    • /
    • 제19권5호
    • /
    • pp.489-499
    • /
    • 2017
  • Self-Compacting Concrete (SCC) is a new technology capable to flow without segregation or any addition of energy which leads to efficient construction and cost savings. In this study, the effect of replacing the Ordinary Portland Cement (OPC) with Fly Ash (FA) on the strength, durability of the concrete was investigated experimentally, and carbon footprint and cost were also assessed. Four different replacement FA ratios (0%, 20%, 40% and 60%) were used to create four SCC mixes. Standard test methods were used to determine the workability, strength, and durability of the SCC mixes including resist chloride ion penetration, water permeability, water absorption, and initial surface absorption. The axial cube compressive strength tests were performed on the SCC mixes at 1, 7, 14, 28 and 35 days. Replacing the OPC with FA had a significant positive impact on chloride iron penetration resistance and water absorption but had a considerable negative impact on the compressive strength. The SCC mix with 60% FA had 36.7% and 15.8% enhancement in the resistance to chloride ion penetration and water absorption, respectively. Evaluation of the carbon footprint and the cost of each SCC mixes showed the $CO_2$ emissions mixes 1, 2, 3 and 4 were significantly reduced by increasing the FA content from 0% to 60%. Compared with the control mix, the cost of all mixes increased when the FA content increased, but no significant differences were seen between the estimated costs of all four mixes.

콘크리트용 블리딩저감제의 개발 및 실용성 검토 (Development and Analysing the Practical Use of Bleeding Reduction Agent for Concrete)

  • 한천구;황인성;신동인
    • 콘크리트학회논문집
    • /
    • 제15권2호
    • /
    • pp.217-224
    • /
    • 2003
  • 블리딩은 재료분리의 일종으로 콘크리트 구조물의 품질을 향상시키기 위해서는 손쉬운 블리딩 저감방안이 요구되고 있다. 그러나, 지금까지 알려진 블리딩 저감대책으로는 재료의 고품질화 및 배합비를 조정하는 등의 방법 외에는 손쉬운 해결책이 없는 실정이었다. 그러므로, 본 연구에서는 콘크리트의 블리딩을 효과적으로 저감할 수 있는 증점제 Type 블리딩저감제의 개발과 그 실용성을 검토한 것으로, 실험결과는 다음과 같다. 즉, 블리딩저감제의 개발은 MC 증점제 : 소포제 : 유동화제를 1 : 0.004 : 0.2의 비율로 혼합하면 가능한 것으로 밝혀졌고. 또한, 개발된 블리딩저감제는 혼입률 증가에 따라 굳지 않은 콘크리트의 유동성, 공기량 및 경화 콘크리트의 압축강도, 내동해성 등 제반 품질은 변동 없고, 블리딩의 저감효과는 우수한 것으로 나타나, 실무에서 콘크리트용 블리딩저감제로 유효하게 활용할 수 있음이 밝혀졌다.

Bridgman 결정성장시 장입 주괴와 도가니 사이의 틈이 용액이 초기농도에 미치는 영향 (The effect of gap between ingot and crucible on the distribution of initial melt concentration in Bridgman crystal growth)

  • Seung-Mo Chung;Man-Sug Kang;Zin-Hyoung Lee
    • 한국결정성장학회지
    • /
    • 제4권2호
    • /
    • pp.169-177
    • /
    • 1994
  • 결정성장된 시편의 농도분포를 제어하기 위해서는 초기융액의 농도를 균일하게 하여야 한다. 용질농도가 초기융액에 있어서 균일하지 않다면, 성장된 시편에 예측한 것과 다른 거시편석이 발생할 수 있다. 위 쪽의 온도가 높은 온도 구배를 갖고 아래로부터 응고를 진행시키는 Bridgman 방법으로 Al-Cu 합금을 성장시키는 경우, 성장된 시편의 어용질 농도분포가 초기응고 부분이 높고 을고가 진행됨에 따라 감소하는 경향을 갖는 것으로 관찰되었다. 이런 현사은 주괴가 녹으면서 도가니와 주괴의 틈으로 스며나온 Cu의 농도가 높은 융액이 주괴가 완전히 녹은 후의 대류에 의해 아래부분에 축적됨으로 발생했다. Al-Mg 합금의 경우 도가니와 주괴의 틈으로 스며나온 Mg의 농도가 높은 융액이 주괴가 완전히 녹은 후의 대류에 의해 떠오르면서 용질 농도분포가 성장중에 최소값을 가지는 것으로 나타났다. 이러한 거시편석을 억제하기 위하여, 균질화 처리 또는 도가니와 주괴의 틈을 없게 함으로 균일한 농도의 초기유액을 얻었다.

  • PDF

로터 장착 건식 미분 분리기의 작동원리 규명 및 파라미터 연구 - II. CFD 해석 (INVESTIGATION OF THE OPERATIONAL PRINCIPLE AND PARAMETRIC STUDY ON A DRY PASTE SEPARATOR EQUIPED WITH A ROTOR -II. CFD ANALYSIS)

  • 박성욱;강양수;강상모;서용권
    • 한국전산유체공학회지
    • /
    • 제20권4호
    • /
    • pp.81-92
    • /
    • 2015
  • Construction waste mainly consists of concrete aggregates of various size. Improper handling of concrete waste would be a major environmental problem whereas its recycling would be both economically useful and environmentally friendly. Bigger concrete aggregates are crushed and converted to medium and fine particles to make them recyclable. An apparatus to separate the concrete aggregates by their size is thus needed for their effective recycling. In this work, segregation of concrete particles in air flows from a newly designed rotary separator having three stages of blades is simulated using a commercial software, ANSYS-CFX. Both 2-D and 3-D models with 360, 240 and 180 blades in each stage are considered. Fundamental mechanism of separation of particles(pase) and the effect of design parameters such as particle size, rotor speed, air flow rate etc. on the performance of the separator are investigated. Critical size of particles that can be separated by the developed separator is also presented in this work. Simulation results are overall in good agreement with data predicted from the theoretical model previously reported in the companion paper.

니켈기 초내열합금의 파형 결정립계 구조가 보론 편석과 재현 열영향부 액화균열거동에 미치는 영향 (Effects of Serrated Grain Boundary Structures on Boron Enrichment and Liquation Cracking Behavior in the Simulated Weld Heat-Affected Zone of a Ni-Based Superalloy)

  • 홍현욱;최준우;배상현;윤중근;김인수;최백규;김동진;조창용
    • Journal of Welding and Joining
    • /
    • 제31권3호
    • /
    • pp.31-38
    • /
    • 2013
  • The transition of serrated grain boundary and its effect on liquation behavior in the simulated weld heat-affected zone (HAZ) have been investigated in a wrought Ni-based superalloy Alloy 263. Recently, the present authors have found that grain boundary serration occurs in the absence of adjacent coarse ${\gamma}^{\prime}$ particles or $M_{23}C_6$ carbides when a specimen is direct-aged with a combination of slow cooling from solution treatment temperature to aging temperature. The present study was initiated to determine the interdependence of the serration and HAZ property with a consideration of this serration as a potential for the use of a hot-cracking resistant microstructure. A crystallographic study indicated that the serration led to a change in grain boundary character as special boundary with a lower interfacial energy as those terminated by low-index {111} boundary planes. It was found that the serrated grain boundaries are highly resistant to boron enrichment, and suppress effectively grain coarsening in HAZ. Furthermore, the serrated grain boundaries showed a higher resistance to susceptibility of liquation cracking. These results was discussed in terms of a significant decrease in interfacial energy of grain boundary by the serration.

ZrO2(Y2O3)계 세라믹스의 소결성과 전기전도도에 대한 M2O3의 영향(III) : ZrO2-Y2O3-Ln2O3계 세라믹스 (Effect of M2O3 on the Sinterbility and Electrical Conductivity of ZrO2(Y2O3) System(III) : Ceramics of the ZrO2-Y2O3-Ln2O3 System)

  • 오영제;정형진;이희수
    • 한국세라믹학회지
    • /
    • 제24권2호
    • /
    • pp.123-132
    • /
    • 1987
  • Yttria-stabilized zirconia with erbia-lanthana were investigated with respect to the amount of Ln2O3 (Ln; Er, La) addition in the range of 0.5∼5 mol% to the base composition of 8 mol% yttriazirconia. Following analysis and measurement were adopted for the characterization of synthesizes of solid electrolyte; phase transformation, lattice parameter, crystallite size, relative density, chemical composition and SEM/EDS. Electrical conductivity by two-probe method versus temperature from 350$^{\circ}C$ to 800$^{\circ}C$ and frequency in the range of 5Hz∼13MHz by complex impedance method was also conducted together with the determination of oxygen ion transference number by EMF method for the evaluation of their electrical properties. The results were as followsing; Electrical conductivity were decreased with increase in Ln2O3 content, but their activation energies increased. In the case of La2O3 addition, espicially, its electrical conductivity was decreased owing to the segregation of second phases at the grain-boundary. Grain-boundary conductivity of the specimen contained 0.5 mol% Er2O3 exhibited a maximum conductivity among thecompositions experimented. However, their bulk conductivities decreased in both case. Oxygen ion transference number was also reduced with decrease in oxygen partial pressure. For example, in the case of Er2O3 addition it retained value in the range of 0.97∼0.94 abvove 4.74${\times}$10-2in oxygen partial pressure. With the increase in the quantities of the evaporation of additive components, the crystallite size of stabilized zirconia decreased, and their relative density also reduced owing to the formation of porosity in their matrices. In the case of La2O3 the sinterbility was improved in the limited amount of addition up to 0.5 mol%, in the same range of addition the strength of sintered bodies were improved perhaps owing to the precipitation of metastable tetragonal phase in the fully stabilized zirconia.

  • PDF