• 열처리공학회지
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• 제34권5호
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• pp.211-217
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• 2021

To predict mechanical properties of secondary hardening martensitic steels, a machine learning ensemble model was established. Based on ANN(Artificial Neural Network) architecture, some kinds of methods was considered to optimize the model. In particular, interaction features, which can reflect interactions between chemical compositions and processing conditions of real alloy system, was considered by means of feature engineering, and then K-Fold cross validation coupled with bagging ensemble were investigated to reduce R2_score and a factor indicating average learning errors owing to biased experimental database.

• 한국재료학회지
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• 제29권3호
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• pp.150-154
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• 2019

This study investigates the effect of MnO2 and CuO as acceptor additives on the microstructure and piezoelectric properties of $0.96(K_{0.5}Na_{0.5})_{0.95}Li_{0.05}Nb_{0.93}Sb_{0.07}O_3-0.04BaZrO_3$, which has a rhombohedral-tetragonal phase boundary composition. $MnO_2$ and CuO-added $0.96(K_{0.5}Na_{0.5})_{0.95}Li_{0.05}Nb_{0.93}Sb_{0.07}O_3-0.04BaZrO_3$ ceramics sintered at a relatively low temperature of $1020^{\circ}C$ show a pure perovskite phase with no secondary phase. As the addition of $MnO_2$ and CuO increases, the sintered density and grain size of the resulting ceramics increases. Due to the difference in the amount of oxygen vacancies produced by B-site substitution, Cu ion doping is more effective for uniform grain growth than Mn ion doping. The formation of oxygen vacancies due to B-site substitution of Cu or Mn ions results in a hardening effect via ferroelectric domain pinning, leading to a reduction in the piezoelectric charge coefficient and improvement of the mechanical quality factor. For the same amount of additive, the addition of CuO is more advantageous for obtaining a high mechanical quality factor than the addition of $MnO_2$.

• 소성∙가공
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• 제32권4호
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• pp.173-179
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• 2023

In this study, the age-hardening behavior and tensile properties of a cast AZ91-0.3Ca-0.2Y (SEN9) alloy are investigated and compared with those of a commercial AZ91 alloy. Even after homogenization heat treatment, the SEN9 alloy contains numerous undissolved secondary phases, Al₈Mn₄Y, Al₂Y, and Al₂Ca, which results in a higher hardness value than the homogenized AZ91 alloy. Under aging condition at 200 ℃, both the AZ91 and SEN9 alloys exhibit the same peak-aging time of 8 h, but the peak hardness of the latter (86.8 Hv) is higher than that of the former (83.9 Hv). The precipitation behavior of Mg₁₇Al₁₂ phase during aging significantly differs in the two alloys. In the AZ91 alloy, the area fraction of Mg₁₇Al₁₂ discontinuous precipitates (DPs) increases up to ~50% as the aging time increases. In contrast, in the SEN9 alloy, the formation and growth of DPs during aging are substantially suppressed by the Ca- or Y-containing particles, which leads to the formation of only a small amount of DPs with an area fraction of ~4% after peak aging. Moreover, the size and interparticle spacing of Mg₁₇Al₁₂ precipitates of the peak-aged SEN9 alloy are smaller than those of the peak-aged AZ91 alloy. The homogenized AZ91 alloy exhibits a higher tensile strength than the homogenized SEN9 alloy due to the finer grains of the former. However, the peak-aged SEN9 alloy has a higher tensile elongation than the peak-aged AZ91 alloy due to the smaller amount of brittle DPs in the former.

• 소성∙가공
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• 제33권3호
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• pp.178-184
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• 2024

In this study, we investigated the effects of extrusion ratio and extrusion temperature on the microstructure and tensile properties of extruded Mg-6Al-0.3Mn-0.3Ca-0.2Y (SEN6) alloy. As the extrusion ratio and temperature increase, dynamic recrystallization during extrusion is promoted, leading to the formation of a fully recrystallized microstructure with increased grain size. Additionally, the increases in extrusion ratio and temperature lead to texture strengthening, exhibiting a higher maximum texture intensity. The extruded materials contain three types of secondary phases, i.e., Al₈Mn₄Y, Al₂Y, and Al₂Ca, with irregular or polygonal shapes. The quantity, size, distribution, and area fraction of the second-phase particles are nearly identical between the two materials. Despite its larger grain size, the tensile yield strength of the material extruded at 450 ℃ and an extrusion ratio of 25 (450-25) is higher than that of the material extruded at 325 ℃ and an extrusion ratio of 10 (325-10), which is mainly attributed to the stronger texture hardening effect of the former. The ultimate tensile strength is similar in the two materials, owing to the higher work hardening rate in the 325-10 extrudate. Despite differences in grain size and recrystallization fraction, numerous twins are formed throughout the specimen during tensile deformation in both materials; consequently, the two materials exhibit nearly the same tensile elongation.

• 한국건설순환자원학회논문집
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• 제11권4호
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• pp.307-315
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• 2023

이 연구에서는 CO₂ 반응경화 시멘트인 CSC와 일반 시멘트인 OPC의 혼합비율에 따라 모르타르 시험체를 제작하고 1차 양생온도 및 2차양생 CO₂ 압력을 제어하여 역학적 특성과 탄산화 특성에 대해 평가하였다. 모든 양생조건에서 CSC 비율이 높을수록 역학적 특성이 감소하는 것으로 나타났다. 1차 양생온도가 60 ℃인 경우가 20 ℃인 경우보다 더 높은 역학적 특성을 나타냈으며 탄산화 침투 깊이 또한 더 큰 것으로 나타났다. 2차 CO₂ 양생의 양생압력과 휨 강도는 반비례하였으나 압축강도는 비례하는 관계로 나타났다. 이는 과도한 탄산화가 오히려 역학적 특성을 감소하는 것에 기인한 것과 휨 강도가 압축강도에 비해 이러한 특성에 더 민감하기 때문인 것으로 판단된다. 다만, 제한 양생조건에 대한 평가결과로 향후 시험조건을 확장하여 면밀한 검토가 필요하다.

• 한국재료학회지
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• 제14권7호
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• pp.451-456
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• 2004

Thermal creep properties of the zirconium tube which was developed for high burnup application were evaluated. The creep test of cladding tubes after various final heat treatment was carried out by the internal pressurization method in the temperature range from $350^{\circ}C to 400^{\circ}C$ and from 100 to 150 MPa in the hoop stress. Creep tests were lasted up to 900days, which showed the steady-state secondary creep rate. The creep resistance of zirconium claddings was higher than that of Zircaloy-4. Factors that affect creep resistance, such as final annealing temperature, applied stress and alloying element were discussed. Tin as an alloying element was more effective than niobium due to solute hardening effect of tin. In case of advanced claddings, the optimization of final heat treatment temperature as well as alloying element causes a great influence on the improvement of creep resistance.

• 열처리공학회지
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• 제19권1호
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• pp.3-9
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• 2006

The phase changes, nitride precipitation and hardness variations of 14%Cr-6.7Ni-0.65Mo-0.26Nb-0.05V-0.03C super martensitic stainless steel were investigated after nitrogen permeation heat treatment at a temperature range between $1050^{\circ}C$ and $1150^{\circ}C$. The nitrogen-permeated surface layer was transformed into austenite. The rectangular type NbN, NbCrN precipitates and fine round type precipitate were coexisted in the surface austenite layer, while the interior region that was free from nitrogen permeation kept the martensitic phase. The hardness of surface austenite showed 280 Hv, while the interior region of martensite phase represented 340 Hv. When tempering the nitrogen-permeated steel at $450^{\circ}C$, a maximum hardness of 433 Hv was appeared, probably this is attributed to the secondary hardening effect of the precipitates. The nitrogen concentration decreased gradually with increasing depth below the surface after showing a maximum of 0.3% at the outmost surface. The strong affinity between nitrogen and Cr enabled the substitutional element Cr to move from interiors to the surface when nitrogen diffuse form surface to the interior. Corrosion resistance of nitrogen permeated steel was superior to that of solution-anneaed steel in the solution of 1N $H_2SO_4$.

• 열처리공학회지
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• 제26권1호
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• pp.7-13
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• 2013

Vacuum heat treatment(indirect heating method) has long exposure time at high temperature and low quenching rate. Contrarily salt bath heat treatment (direct heating method) has short exposure time at high temperature and fast cooling rate. With these different features of processes, mechanical properties such as hardness, tensile strength and impact strength of products show very different results. In this study, Salt bath heat treated products showed higher tensile strength and impact strength than vacuum heat treated products but hardness was not much different. These lower mechanical properties of vacuum heat treated products are due to differences in heat process and secondary hardening with high temperature tempering process. Consequently, It indicates that salt bath heat treatment is better way than vacuum heat treatment for product to have high mechanical properties.

• 대한조선학회논문집
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• 제48권3호
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• pp.189-199
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• 2011

Austenite stainless steel(ASS), aluminum alloy and nickel steel alloy are the most widely used in many cryogenic applications due to superior mechanical properties at low temperature. The Face-Centered Cubic(FCC) and Hexagonal Close-Packed(HCP) materials are used for the primary and secondary insulation barrier of Liquefied Natural Gas(LNG) carrier tank and various kinds of LNG applications currently. In this study, tensile tests of ASS, aluminum alloy and nickel steel alloy were carried out for the acquisition of quantitative mechanical properties under the cryogenic environment. The range of thermal condition was room temperature to $-163^{\circ}C$ and strain rate range was 0.00016/s to 0.01/s considering the dependencies of temperatures and strain rates. The comprehensive test data were analyzed in terms of the characteristics of mechanical behavior for the development of constitutive equation and its application.

• KSTLE International Journal
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• 제1권1호
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• pp.12-20
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• 2000

Nano-wear and friction of carbon overcoated laser-textured and mechanically-textured computer hard disk were characterised after contact start/stop (CSS) wear test. Various analytical and mechanical testing techniques were employed to study the changes in topography, roughness, chemical elements, mechanical properties and friction characteristics of the coating arising from the contact start/stop wear test These techniques include: the atomic force microscopy (AFM), the continuous nano-indentation test, the nano-scratch test, the time-of-flight secondary ion mass spectroscopy (TOF-SIMS) and the auger electron spectroscopy (AES). It was shown that the surface roughness of the laser-textured (LT) bump and mechanically textured (MT) Bone was reduced approximately am and 7nm, respectively, after the CSS wear test. The elastic modulus and hardness values increased after the CSS test, indicating straining hardening of the top coating layer, A critical load was also identified fer adhesion failure between the magnetic layer and the Ni-P layer, The TOF-SIMS analysis also revealed some reduction in the intensity of C and $C_2$$F_59$, confirming the wear of lubricant elements on the coating surface.