• Title/Summary/Keyword: Second phase particle

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Effect of Al Content on Phase Transformation of Rapidly Solidified Binary Ti-Al Alloys

  • Oh, Chang-Sup;Kim, Sang-Wook;Han, Chang-Suk
    • Korean Journal of Materials Research
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    • v.27 no.1
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    • pp.8-11
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    • 2017
  • Binary Ti-Al alloys containing 50 to 60 atomic percent aluminum are rapidly solidified by hammer anvil method under an argon atmosphere. Constituent phases in each alloy are identified by X-ray diffractometry and microstructures of the alloys are investigated using a transmission electron microscope. In alloys with aluminum content between 50 and 54 percent, a second phase exists besides TiAl(${\gamma}$); this second phase is identified as $Ti_3Al$(${\alpha}2$). The ${\alpha}2$ phase is observed in two types of morphology. One is as fine lamellar alternating with ${\gamma}$ and the other is as a particle. It is concluded that the existence of a metastable phase with the morphologies stated above should arise from a higher quenching rate attained by the hammer anvil method as compared to the conventional roll or splat-quench method. Implications of the above observation are discussed with respect to the phase relations in the Ti-Al binary system; these implications are still controversial in many respects.

Geographical Group-based FastSLAM Algorithm for Maintenance of the Diversity of Particles (파티클 다양성 유지를 위한 지역적 그룹 기반 FastSLAM 알고리즘)

  • Jang, June-Young;Ji, Sang-Hoon;Park, Hong Seong
    • Journal of Institute of Control, Robotics and Systems
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    • v.19 no.10
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    • pp.907-914
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    • 2013
  • A FastSLAM is an algorithm for SLAM (Simultaneous Localization and Mapping) using a Rao-Blackwellized particle filter and its performance is known to degenerate over time due to the loss of particle diversity, mainly caused by the particle depletion problem in the resampling phase. In this paper, the GeSPIR (Geographically Stratified Particle Information-based Resampling) technique is proposed to solve the particle depletion problem. The proposed algorithm consists of the following four steps : the first step involves the grouping of particles divided into K regions, the second obtaining the normal weight of each region, the third specifying the protected areas, and the fourth resampling using regional equalization weight. Simulations show that the proposed algorithm obtains lower RMS errors in both robot and feature positions than the conventional FastSLAM algorithm.

A Case Study of Paraffin Double-walled Microencapsulation Preparation Using Acrylic Polymer and Melamine Polymer for Thermal Energy Storage

  • Nguyen, Hang Vo-Minh;Kim, Chae-Hyun;Kim, Jong-Kuk
    • Journal of the Korean Solar Energy Society
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    • v.39 no.5
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    • pp.65-78
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    • 2019
  • In this study, we investigated the paraffin encapsulation using double-walled encapsulation technique. The first encapsulation used methyl methacrylic acid as the main component in acrylic polymer and the second encapsulation used melamine polymer. Particles size and distribution of the capsules were analyzed using scanning electron microscopy. In the first encapsulation, the stable capsules were obtained at 67% of phase change material ratio to methyl methacrylic acid monomer and the size of the capsule was from 0.2 to $0.3{\mu}m$. In the second encapsulation, the size of the capsules was almost the same with those capsules prepared in the first encapsulation. The particle size of single wall and double wall was about $0.3{\mu}m$. As a result of the encapsulation of paraffin using double-walled encapsulation technique, it was confirmed that the particle size was determined in the process of encapsulating using the acrylic polymer at the first wall material, and the physical and thermal stability of the capsules were imparted using melamine at the secondary wall material.

Prototype-based Classifier with Feature Selection and Its Design with Particle Swarm Optimization: Analysis and Comparative Studies

  • Park, Byoung-Jun;Oh, Sung-Kwun
    • Journal of Electrical Engineering and Technology
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    • v.7 no.2
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    • pp.245-254
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    • 2012
  • In this study, we introduce a prototype-based classifier with feature selection that dwells upon the usage of a biologically inspired optimization technique of Particle Swarm Optimization (PSO). The design comprises two main phases. In the first phase, PSO selects P % of patterns to be treated as prototypes of c classes. During the second phase, the PSO is instrumental in the formation of a core set of features that constitute a collection of the most meaningful and highly discriminative coordinates of the original feature space. The proposed scheme of feature selection is developed in the wrapper mode with the performance evaluated with the aid of the nearest prototype classifier. The study offers a complete algorithmic framework and demonstrates the effectiveness (quality of solution) and efficiency (computing cost) of the approach when applied to a collection of selected data sets. We also include a comparative study which involves the usage of genetic algorithms (GAs). Numerical experiments show that a suitable selection of prototypes and a substantial reduction of the feature space could be accomplished and the classifier formed in this manner becomes characterized by low classification error. In addition, the advantage of the PSO is quantified in detail by running a number of experiments using Machine Learning datasets.

Effect of pH Variation on the Properties of the Hydroxyapatite Precipitates and Powder Prepared by the Wet Method (습식법으로 제조한 수산화아파타이트 침전입자와 분말의 특성에 미치는 pH변화의 영향)

  • 신용규;정형진;김병호
    • Journal of the Korean Ceramic Society
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    • v.26 no.2
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    • pp.157-166
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    • 1989
  • The effect of pH variation in starting solution on the characteristics of hydroxyapatite precipitates and powder prepared by the wet method was investigated. Hydroxyapatite precipitates was agglomerated, the average agglomerated particle size was decreased in the range from 2 to 6${\mu}{\textrm}{m}$ with increasing pH values in starting solution. The aspect ratio of rod-shaped hydroxyapatite particle was rapidly increased at pH 11 and 11.5. The maximum specific surface area, 91.1$m^2$/g, was at pH 10.5. Dried powder prepared at high pH values contained more minutes CO2 than that prepared at low pH values. The poor crystallinity was maintained up to $600^{\circ}C$ regardless of the pH values in starting solutions. However, the second phase or high crsytalline hydroxypatite phase appeared above 80$0^{\circ}C$. In pH 9.5 and pH 10, $\beta$-whitlockite transformed to $\alpha$-whitlockite at 120$0^{\circ}C$, while in pH 10.5-11.5, hydroxyapatite phase was maintained up to 120$0^{\circ}C$.

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Core-Shell Polymerization with Hydrophilic Polymer Cores

  • Park, Jong-Myung
    • Macromolecular Research
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    • v.9 no.1
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    • pp.51-65
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    • 2001
  • Two-stage emulsion polymerizations of hydrophobic monomers on hydrophilic seed polymer particles were carried out to make core-shell composite particles. It was found that the loci of polymerization in the second stage were the surface layer of the hydrophilic seed latex particles, and that it has resulted in the formation of either eccentric core-shell particles with the core exposed to the aqueous phase or aggregated nonspherical composite particles with the shell attached on the seed surface as many small separated particles. The driving force of these phenomena is related to the gain in free energy of the system in going from the hydrophobic polymer-water interface to hydrophilic polymer-water interface. Thermodynamic analysis of the present polymerization system, which was based on spreading coefficients, supported the likely occurrence of such nonspherical particles due to the combined effects of interfacial free energies and phase separation between the two polymer phases. A hypothetical pathway was proposed to prepare hydrophilic core-hydrophobic shell composite latex particles, which is based on the concept of opposing driving and resistance forces for the phase migration. It was found that the viscosity of the monomer-swollen polymer phase played important role in the formation of particle morphology.

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Estimation of Mechanical Properties for Particle Dispersed Composites (입자 분산 복합재료의 기계적 성질 추정)

  • Tak Jin Moon;Dae Soon Im
    • Journal of the Korean Chemical Society
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    • v.26 no.6
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    • pp.414-420
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    • 1982
  • The mechanical properties of nickel particle polyethylene composites were estimated by using a finite element method. Two steps were carried out in this analysis; the first step was to consider an unit model composed of spherical cell in the center of the matrix and the second step was to consider a total model composed of unit model. Two phase and three phase models were used, since another third phase were observed between matrix and nickel particle. Finite element method permits the calculation of the stress and displacement, assuming the arbitrary loads. Elastic modulus, Poisson's ratio and stress distribution of composites were obtained from this output. Comparison of the calculation by finite element method and the experimental results for Ni-filled polyethylene showed good agreement in tensile properties.

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A Numerical Study on Various Energy and Environmental System (II) (에너지${\cdot}$환경 제반 시스템에 관한 수치해석적 연구(II))

  • Jang D. S.;Park B. S.;Kim B. S.;Lee E. J.;Song W. Y.
    • 한국전산유체공학회:학술대회논문집
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    • 1996.05a
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    • pp.58-67
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    • 1996
  • This paper describes some computational results of various energy and environmental systems using Patankar's SIMPLE method. The specific topics handled in this study are jet bubbling reactor for flue gas desulfurization, cyclone-type afterburner for incineration, 200m tall stack for 500 MW electric power generation, double skin and heat storage systems of building energy saving for the utilization of solar heating, finally turbulent combustion systems with liquid droplet or pulverized coal particle. A control-volume based finite-difference method with the power-law scheme is employed for discretization. The pressure-velocity coupling is resolved by the use of the revised version of SIMPLE, that is, SIMPLEC. Reynolds stresses are closed using the standard $k-{\varepsilon}$ and RNG $k-{\varepsilon}$ models. Two-phase turbulent combustion of liquid drop or pulverized coal particle is modeled using locally-homogeneous, gas-phase, eddy breakup model. However simple approximate models are incorporated for the modeling of the second phase slip and retardation of ignition without consideration of any detailed particle behavior. Some important results are presented and discussed in a brief note. Especially, in order to make uniform exit flow for the jet bubbling reactor, a well-designed structure of distributor is needed. Further, the aspect ratio in the double skin system appears to be one of important factors to give rise to the visible change of the induced air flow rate. The computational tool employed in this study, in general, appears as a viable method for the design of various engineering system of interest.

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Wet Chemical Preparation of Li-rich LiMn$_2$O$_4$ Spinel by Oxalate Precipitation (Oxalate 침전을 이용한 Li-과량 LiMn$_2$O$_4$ Spinel의 습식합성가 분말 특성)

  • 이병우;김세호
    • Journal of the Korean Ceramic Society
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    • v.36 no.7
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    • pp.698-704
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    • 1999
  • Li rich Li1+xMn2-xO4(x=0.07) spinel powders were prepared by an oxalate precipitation of wet chemical methods at temperature lower than $600^{\circ}C$. The FTIR results showed that the powders prepared at $600^{\circ}C$ had high degree of crystal quality comparing with the spinel powders prepared by solid state reaction at 75$0^{\circ}C$ which was the lowest synthesis temperature of the solid state reaction method. The particle size of powders prepared by the oxalate precipitation at $600^{\circ}C$ was smaller than 0.2${\mu}{\textrm}{m}$ and the specific surface area was 11.01 m2/g A heat treatment over 90$0^{\circ}C$ formed second phase in the precipitates. It was shown that there were phase transitions at temperatures. T1,T2 and T2. The transitions involved weight loss and gain during heating and cooling. The low temperature synthesis below $600^{\circ}C$ avoided the second phase formation and the prepared powders showed improved compositional and physical properties for secondary lithium battery applications.

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Microstructure and Thermal Behaviors of Droplets During the Formation of Particle Reinforced Metal Matrix Composites by Spray Casting Process (분사주조에 의한 입자강화 금속기지 복합재료의 제조시 액적의 열적거동과 미세조직에 대한 고찰)

  • Kim, Myung-Ho;Bae, Cha-Hurn;Jeong, Hae-Young;Park, Heung-Il
    • Journal of Korea Foundry Society
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    • v.12 no.4
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    • pp.326-334
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    • 1992
  • Particle-reinforced metal matrix composites via the Osprey spray casting process were fabricated by injecting second phase particles of $Al_2O_3$(<$40{\mu}m$) and W($6{\mu}m$) into the spray of Cu droplets, and the thermal behaviors of the composite droplets during flight were considered theoretically on the basis of mixing modes between the Cu droplets and the reinforced particulates injected. It was found that the W-injected spray is comprised of particle-embedded droplets, and the $Al_2O_3-injected$ spray comprises particle-attached droplets. From the predicted results of the thermal behaviors of the composite droplets and preforms produced, it is concluded that the thermal behaviors of the composite droplets during flight, and during the subsequent deposition are strongly influenced by its mixing modes between the reinforced particulates and Cu droplets during flight.

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