• Journal of Korean Society of Water and Wastewater
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• 제30권6호
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• pp.635-643
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• 2016

Gas hydrate (GH)-based desalination process have a potential as a novel unit desalination process. GHs are nonstoichiometric crystalline inclusion compounds formed at low temperature and a high pressure condition by water and a number of guest gas molecules. After formation, pure GHs are separated from the remaining concentrated seawater and they are dissociated into guest gas and pure water in a low temperature and a high pressure condition. The condition of GH formation is different depending on the type of guest gas. This is the reason why the guest gas is a key to success of GH desalination process. The salt rejection of GH based desalination process appeared 60.5-93%, post treatment process is needed to finally meet the product water quality. This study adopted reverse osmosis (RO) as a post treatment. However, the test about gas rejection by RO process have to be performed because the guest gas will be dissolved in a GH product (RO feed). In this research, removal potential of dissolved gas by RO process is performed using lab-scale RO system and GC/MS analysis. The relation between RO membrane characteristics and gas removal rate were analyzed based on the GC/MS measurement.

• Korean Chemical Engineering Research
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• 제55권6호
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• pp.762-766
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• 2017

Energy recovery device (ERD) is used to save energy consumption in seawater reverse osmosis processes. However, small-scale ERDs (<$100m^3/d$) are hardly observed in seawater desalination market. In South Korea, most of seawater desalination plants for drinking water production are small-scaled and have been operated in island areas or on ships. Thus, the effect of ERDs for these small-scale SWRO processes should not be neglected. In this work, the small-scale SWRO processes are designed and analyzed in terms of energy consumption with/without ERD. The realistic efficiencies of high pressure pumps are considered for the energy analyses. The unit cost of electricity depending on the application place (e.g., inland and island areas, on ships) is investigated to calculate the energy cost for unit water production in various SWRO applications classified by plant capacity, application place, and the installation of ERD. As a result, the energy cost can be saved up to $1,640.4KRW/m^3$ when ERD is applied, and the saving effect increases at smaller plants on ships. In conclusion, the development of small-scale ERDs are necessary because small-scale SWRO processes are dominant in Korean seawater desalination market, and the electricity saving effect becomes higher at smaller-scaled system.

• Journal of Korean Society of Water and Wastewater
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• 제33권6호
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• pp.437-446
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• 2019

Reverse osmosis seawater desalination facilities can extend the cleaning cycle and replacement time of the reverse osmosis membrane by pretreatment process. Selection of pretreatment process depends on water quality. It was attempted in this study to select approriate pretreatment process for the Masan bay, which was high in particles and organic content. For this purpose, performances of pretreatment processes such as filter adsorber (FA), pore controllable fiber (PCF), and ultrafiltration (UF) were compared based on the silt density index (SDI). The SDI value of the filtrate should be less than 3. The study results showed that UF can produce the filtrate quality satisfying the requirement. However, the transmembrane pressure (TMP) of UF increased quickly, reaching 0.6 bar within 4 days. In order to secure stable operation, FA and PCF were combined with UF. The study results showed that combination of PCF and UF was able to extend the filtration duration (more than 2 months) until to reach TMP of 0.6 bar.

• Journal of Korean Society of Water and Wastewater
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• 제33권4호
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• pp.281-289
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• 2019

Desalination plants are generally studied with higher operating costs compared to water supply facilities. This study was conducted to reduce the cost of water production and to preserve existing water resources. Therefore, the purpose of this study was to utilize the control valves to increase maximum efficiency, thereby reducing the power of the pumps and operating costs. Specific energy consumption was shown to reduce the process operating power by up to 1.7 times from 6.17 to $3.55kWh/m^3$ based on seawater reverse osmosis 60 bar. In addition, the water intake process was divided into pre, inter, and post-according to the use method of blasting, and the water treatment process was divided into pre, inter, and post blending. In order to reduce power consumption, the blending process was combined to operate the facility, which resulted in the reduction of power consumption in the order post > pre-inter> inter blending.

• Environmental Engineering Research
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• 제16권4호
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• pp.227-230
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• 2011

Seawater desalination technology is a complicated and expensive process. Besides salt removal from seawater, thesignificant problem that needs to be solved is boron removal. Boron removal is difficult so it is a considerable challenge for the desalination process. The main technology of this process is reverse osmosis (RO). RO can remove salt and boron more effectively than other technologies. In a conventional seawater desalination process, coagulant is utilized for pre-treatment but it is difficult to remove boron through this stage. In this study, a coagulant called Mineral Cluster was examined for boron removal. Therefore, Mineral Cluster can be considered a potential coagulant for boron removal in seawater desalination technology.

• Journal of the Korean Recycled Construction Resources Institute
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• 제9권2호
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• pp.216-222
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• 2021

This is an experiment to complement new ways of using concentrated water discharged from the seawater desalination plant. In this study, metakaolin, which has excellent chloride ion immobilization effect, was used as the main binder, and 10% and 20% of calcium oxide were substituted with the activator. In addition, tap-water(TW) and reverse osmosis brine water(RW) were used as mixed water. As a result of the experiment, the mixture using RW showed higher compressive strength than TW. It also showed low water absorption and high density. In the mixture using RW as mixed water, a hydration reaction substance called Friedel's salt could be observed. Considering the corrosion problem of steel, RW is considered to be applicable to products such as non-reinforced concrete, brick, and curb stone. Through this study, it is thought that it is meaningful to propose a new application method other than the ocean release of RW.

• Journal of Korean Society on Water Environment
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• 제20권5호
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• pp.447-451
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• 2004

The various pretreatment processes were evaluated to remove organic pollutants of weathered oil contaminated seawater(WOCS) for reverse osmosis desalination process, Biodegradation, coagulation, ultrafiltration, advanced oxidation processes and granular activated carbon filtration were used to evaluate the potential of organic pollutants removal in WOCS. Dissolved Organic Carbon(DOC) was almost not removed by biodegradation in WOCS. DOC was removed by 25% and 10% with the addition of $FeCl_3$ and PAC in WOCS, respectively. The removal efficiency using ultrafiltration(WOCS 500) was about 20% of DOC and 40% of $E_{260}$, respectively. In AOP application of WOCS, the removal of organic materials was improved up to 60% by the combination of $UV/O_3$ compared to UV process. However, 98% of DOC in woes could be removed by granular activated carbon filtration. It is revealed that activated carbon filtration is the best process for the pretratment of DOC removal.

• Proceedings of the Membrane Society of Korea Conference
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• 한국막학회 1996년도 제5회 산학협동 심포지움 (먹는 물과 막분리공정)
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• pp.121-145
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• 1996

Due to more stringent regulations in drinking water, membrane separation has been playing an increasingly important role. Seawater desalination by reverse osmosis is a typical example and has been used world-wide. Although the existing technology based on coagulation and media filtration is well established and reliable technology, with the advance of industrial and agricultural activities it is difficult for this technology to remove contaminants such as nitrate and synthetic organic chemicals. To meet the drinking water standards and produce higher quality water, several membrane filtration research programs have been initiated which include Japanese MAC21 and New MAC21 projects. In this paper, potable water application of reverse osmosis (RO) and nanofiltration(NF) and their case histories will be explained in more detail.

• Membrane Journal
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• 제25권4호
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• pp.301-309
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• 2015

Importance of pretreatment for seawater desalination is growing rapidly. Proper selection of pretreatment is critical for the successful, long-term operation in the seawater desalination plant such as seawater reverse osmosis (SWRO). The purposes of seawater pretreatment are to remove particulate, colloidal materials, organic, inorganic materials, microorganisms and their by-products present in the seawater, and thus to improve the performance of seawater desalination systems. However, pretreatment is most challenging for designing and operating seawater desalination plants because of fluctuations of water qualities, site specifications and wide ranges of target materials present in the seawater to be treated. In addition, it is also becoming evident increasingly that microscopic algae are a major cause of operational problems, for example, membrane fouling which is long-standing problem in SWRO process. Pretreatment strategies prior to the operation of seawater desalination technologies should be even more complicated by algae blooms and release of their harmful by-products in marine environment. This paper reviews the roles of various pretreatment methods in seawater desalination process. Benefits and drawbacks are described, which should be taken into account in future studies on selecting pretreatment for seawater desalination process.

• Prospectives of Industrial Chemistry
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• 제14권6호
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• pp.9-20
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• 2011

전 세계는 물 부족 문제를 해결하기 위한 대체수자원 개발에 다양한 노력을 기울이고 있으며, 그 중에 해수 담수화 기술이 가장 주목받고 있다. 특히 역삼투 방식의 해수담수화기술은 기존 증발식에 비해 에너지 소비량이 적기 때문에 매년 10% 이상의 높은 성장률을 기록하고 있다. 그러나 역삼투 방식의 해수담수화는 지표수를 이용하는 시스템에 비해 상당히 많은 에너지를 필요로 한다. 따라서 에너지 효율을 높이기 위한 다양한 공정 개발이 시도되고 있으며, 그 중에 대표적인 기술이 삼투현상을 이용한 FO (Forward Osmosis)와 PRO (Pressure Retarded Osmosis) 공정이다. 본 논문에서는 역삼투막을 이용한 해수담수화 기술의 현황과 한계를 살펴보고, 현 해수담수화공정을 보완할 기술로써 FO와 PRO 공정개발에 관한 최근 연구 동향과 이러한 신기술의 상용화에 필수적으로 요구되는 막에 대한 개발 현황을 살펴보았다.