• 제목/요약/키워드: Se/metal ratio

검색결과 54건 처리시간 0.023초

Potential and Significance of Ammonium Production from Helicobacter pylori

  • KI, Mi-Ran;Yun, Soon-Kyu;Choi, Kyung-Min;Hwang, Se-Young
    • Journal of Microbiology and Biotechnology
    • /
    • 제13권5호
    • /
    • pp.673-679
    • /
    • 2003
  • Glutamine and urea, abundant in body fluids or plasma, yield net ammonium ions upon hydrolysis by ${\gamma}-glutamyl$ transpeptidase (${\gamma}-GTP$) and urease, respectively, and these two enzymes are largely produced from Helicobacter pylori. To investigate bacterial potential of ammonium production, we first quantified those in whole-cell systems and found that the relative ratio of their amounts varied greatly, especially with pH values and the cell's aging. During the H. pylori cultivation, the ratio appeared to be inversely proportional to each other, showing a progressive increase of the ${\gamma}-GTP$ with decreasing of the urease. Under the urease-defective conditions due to low pH or coccoids, the bacterial cells still possessed a considerable amount of ${\gamma}-GTP$, which was found exclusively in the external compartment, therefore, the cell's ammonium production was found to be solely dependent upon glutamine, and the external ammonium concentration was constant without any contribution of urea concentration. Such ammonium constancy would definitely have an adverse effect on the host, because of its absolute requirement for vacuolar degeneration by H. pylori VacA, maximized at approximately 10 mM $NH_4Cl$. It was also found that, by using the metal-saturated membrane vesicles, ammonium ions were likely to be involved in the pH-dependent cation-flux across the H. pylori membrane, where the role of ${\gamma}-GTP$ in ammonium homeostasis around cells was suggested, especially under the hostile conditions against H. pylori.

발변전용 피뢰기의 구조 및 ZnO 바리스터 소자의 전기적 특성 (Structure of Station Class Lightning Arresters and Electrical Characteristics of ZnO Varistor Blocks)

  • 조한구;한세원;이운용;윤한수;최인혁
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
    • /
    • pp.1158-1161
    • /
    • 2004
  • This paper presents structural characteristics of station class lightning arresters and electrical characteristics of manufactured ZnO varistor blocks which are usable in those arresters. Three types of station class lightning arresters were investigated and those are a ceramic arrester, a FRP tube type polymer arrester, and a FRP rod type polymer arrester. Each arrester has merits and demerits with structural characteristics. In general, polymer arresters were made of silicon rubber for housing materials, FRP tube or rod for mechanical strength, ZnO blocks for electrical characteristics, and metal parts for electrical contact and the silicon rubber, the housing materials, was directly injected to the arrester module which was assembly composed of electrodes, ZnO blocks and FRP tube or rod, and to prevent the nonlinear electric fields distribution on upper parts of arresters, the grade ring was adopted to the upper electrodes. The reference voltage, nonlinear coefficient, residual voltage, and voltage ratio of manufactured ZnO varistors are 4.90kV, 50, 9.54kV, 1.94, respectively. Compared to designed electrical characteristics, the reference voltage was low for 600v and the voltage ratio was slightly high. However, the characteristics of discharge withstand was so excellent that the mechanical destruction does not occur at the impulse current of $8/20{\mu}s$ 10kA for 100 times.

  • PDF

중금속 안정화제의 반응 매개변수 결정 및 중금속 안정화 효율성 평가 (Determining Kinetic Parameters and Stabilization Efficiency of Heavy Metals with Various Chemical Amendment)

  • 오세진;김성철;김태희;연규훈;이진수;양재의
    • 한국토양비료학회지
    • /
    • 제44권6호
    • /
    • pp.1063-1070
    • /
    • 2011
  • 본 연구는 수용액 내 존재하는 Cd, Pb을 다양한 화학적 안정화제를 이용하여 안정화 효율성을 평가하였다. 연구에 사용한 안정화제는 중금속 이온과의 반응특성 별로 석회물질, 광물질 등으로 구분하여 문헌조사를 바탕으로 5종을 선정하여 사용했다. 안정화 효율성 평가방법은 용액 내 중금속 함량을 단계적으로 제조하여 안정화 효율성, 반감기 및 반응속도 산정 및 반응 후 안정화제의 반응생성물 확인의 순으로 진행했다. 안정화 효율성 평가결과 석회물질 ($CaCO_3$)을 다량 함유하여 기본적으로 pH를 8이상으로 교정하는 안정화제의 경우 처리량에 상관없이 대부분 불용화되는 것으로 나타났으며, 낮은 산도교정 물질은 50% 수준의 효율성을 갖는 것으로 나타났다. 또한, 효율성이 크게 나타난 물질을 대상으로 반응속도상수 (K)를 산출한 결과 Cd의 경우 처리량에 따라 증가하였지만, Pb의 경우 초기에 반응속도가 빠르게 일어나 처리량에 따른 평가는 불가능 하였다. 다량의 중금속 이온과 반응시킨 안정화제의 표면관찰을 통한 생성물 검정 결과 SEM 사진으로 반응 전 후의 생성물 확인을 간접적으로 확인하였다. 또한, SEM-EDS 분석결과 반응 후 물질 표면에서 Cd과 Pb의 성분 검출을 확인하였다. 그리고 XRD 분석을 통해 효율성이 좋았던 물질에서 Cd과 Pb 성분의 검출이 확인되어 수용액 상에 이온형태로 존재하는 중금속의 복원에 안정화제를 이용한 저감은 효율적일 것으로 판단된다.

준 실시간 측정시스템을 이용한 미세입자 원소성분 배출특성 조사 (Emission Characteristics of Elemental Constituents in Fine Particulate Matter Using a Semi-continuous Measurement System)

  • 박승식
    • 한국대기환경학회지
    • /
    • 제26권2호
    • /
    • pp.190-201
    • /
    • 2010
  • Fine particulate matter < $1.8{\mu}m$ was collected as a slurry using the Semicontinuous Elements in Aerosol Sampler with time resolution of 30-min between May 23 and 27, 2002 at the Sydney Supersite, Florida, USA. Concentrations of 11 elements, i.e., Al, As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Se, and Zn, in the collected slurry samples were determined off-line by simultaneous multi-element graphite furnace atomic absorption spectrometry. Temporal profiles of $SO_2$ and elemental concentrations combined with meteorological parameters such as wind direction and wind speed indicate that some transient events in their concentrations are highly correlated with the periods when the plume from an animal feed supplement processing facility influenced the Sydney sampling site. The peaking concentrations of the elemental species during the transient events varied clearly as the plume intensity varied, but the relative concentrations for As, Cr, Pb, and Zn with respect to Cd showed almost consistent values. During the transient events, metal concentrations increased by factors of >10~100 due to the influence of consistent plumes from an individual stationary source. Also the multi-variate air dispersion receptor model, which was previously developed by Park et al. (2005), was applied to ambient $SO_2$ and 8 elements (Al, As, Cd, Cr, Cu, Fe, Pb, and Zn) measurements between 20:00 May 23 and 09:30 May 24 when winds blew from between 70 and $85^{\circ}$, in which animal feed processing plant is situated, to determine emission and ambient source contributions rates of $SO_2$ and elements from one animal feed processing plant. Agreement between observed and predicted $SO_2$ concentrations was excellent (R of 0.99; and their ratio, $1.09{\pm}0.35$) when one emission source was used in the model. Average ratios of observed and predicted concentrations for As, Cd, Cr, Pb, and Zn varied from $0.83{\pm}0.26$ for Pb to $1.12{\pm}0.53$ for Cd.

연자성 복합체에서 파우더 크기 분포와 Epoxy Resin에 따른 Packing Density 변화 (The Variation of Packing Density According to Powder Size Distribution and Epoxy Resin in Soft Magnetic Composite)

  • 이창현;오세문;신효순;여동훈;김진호
    • 한국전기전자재료학회논문지
    • /
    • 제30권12호
    • /
    • pp.782-787
    • /
    • 2017
  • There is growing interest in power inductors in which metal soft magnetic powder and epoxy resin are combined. In this field, the process technology for increasing the packing density of magnetic particles in an injection molding process is very important. However, little research has been reported in this regard. In order to improve the packing density, we investigated and compared the sedimentation heights of pastes for three types of soft magnetic alloy powders as a function of the mixing ratios and the type of resin used. Experimental results showed that the packing density was the highest (71.74%) when the mixing ratio was 80 : 16 : 4 (Sendust : Fe-S : CIP) according to the particle size using an SE-4125 resin. In addition, the packing density was found to be inversely related to the layer separation distance. As a result, it was confirmed that the dispersion of solid particles in the paste was important for curing; however, the duration of the curing process can greatly affect the packing density of the final composite.

응집된 Y2O3:Eu Red 형광체의 나노분산 및 나노졸의 형광특성 (Nano Dispersion of Aggregated Y2O3:Eu Red Phosphor and Photoluminescent Properties of Its Nanosol)

  • 이현진;반세민;정경열;최병기;강광중;김대성
    • 한국재료학회지
    • /
    • 제27권2호
    • /
    • pp.100-106
    • /
    • 2017
  • Nanosized and aggregated $Y_2O_3:Eu$ Red phosphors were prepared by template method from metal salt impregnated into crystalline cellulose. The particle size and photoluminescent property of $Y_2O_3:Eu$ red phosphors were controlled by variation of the calcination temperature and time. Dispersed nanosol was also obtained from the aggregated $Y_2O_3:Eu$ Red phosphor under bead mill wet process. The dispersion property of the $Y_2O_3:Eu$ nanosol was optimized by controlling the bead size, bead content ratio and milling time. The median particle size ($D_{50}$) of $Y_2O_3:Eu$ nanosol was found to be around 100 nm, and to be below 90 nm after centrifuging. In spite of the low photoluminescent properties of $Y_2O_3:Eu$ nanosol, it was observed that the photoluminescent property recovered after re-calcination. The dispersion and photoluminescent properties of $Y_2O_3:Eu$ nanosol were investigated using a particle size analyzer, FE-SEM, and a fluorescence spectrometer.

주형법으로 제조된 Gd2O3:Eu3+ 적색 형광체의 나노입자 분산 및 형상제어 (Dispersion and Shape Control on Nanoparticles of Gd2O3:Eu3+ Red Phosphor Prepared by Template Method)

  • 박정민;반세민;정경열;최병기;강광중;김대성
    • 한국재료학회지
    • /
    • 제27권10호
    • /
    • pp.534-543
    • /
    • 2017
  • $Gd_2O_3:Eu^{3+}$ red phosphors were prepared by template method from crystalline cellulose impregnated by metal salt. The crystallite size and photoluminescence(PL) property of $Gd_2O_3:Eu^{3+}$ red phosphors were controlled by varying the calcination temperature and $Eu^{3+}$ mol ratio. The nano dispersion of $Gd_2O_3:Eu^{3+}$ was also conducted with a bead mill wet process. Dependent on the time of bead milling, $Gd_2O_3:Eu^{3+}$ nanosol of around 100 nm (median particle size : $D_{50}$) was produced. As the bead milling process proceeded, the luminescent efficiency decreased due to the low crystallinity of the $Gd_2O_3:Eu^{3+}$ nanoparticles. In spite of the low PL property of $Gd_2O_3:Eu^{3+}$ nanosol, it was observed that the photoluminescent property was recovered after re-calcination. In addition, in the dispersed nanosol treated at $85^{\circ}C$, a self assembly phenomenon between particles appeared, and the particles changed from spherical to rod-shaped. These results indicate that particle growth occurs due to mutual assembly of $Gd(OH)_3$ particles, which is the hydration of $Gd_2O_3$ particles, in aqueous solvent at $85^{\circ}C$.

$Eu^{3+}$ 농도에 따른 $Y_3Al_5O_{12}:Ce^{3+},Eu^{3+}$ 형광체의 광학적 특성 (Photoluminescence Characteristics of $Y_3Al_5O_{12}:Ce^{3+},Eu^{3+}$ Phosphors by $Eu^{3+}$ ions)

  • 곽현호;김세준;박용서;최형욱
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
    • /
    • pp.441-442
    • /
    • 2008
  • For this study, Yttrium aluminum garnet (YAG) particles co-doped with $Ce^{3+}$ and $Eu^{3+}$ were prepared via the combustion process using the 1:1 ratio of metal ions to reagents. The characteristics of the synthesized nano powder were investigated by means of X-ray diffraction (XRD), Scanning Electron Microscope (SEM), and photoluminescence (PL). The various YAG peaks, with the (420) main peak, appeared at all Eu concentrationin XRD patterns. The YAG phase crystallized with results that are in good agreement with the JCPDS diffraction file 33-0040. The SEM image showed that the resulting YAG:Ce,Eu powders had uniform sizes and good homogeneity. The grain size was about 50nm. The photoluminescence spectra of the YAG:Ce,Eu nanoparticles were investigated to determine the energy level of electron transition related to luminescence processes. It was composed a broad band of $Ce^{3+}$ activator into the weak line peak of $Eu^{3+}$ in YAG host. The PL intensity of $Ce^{3+}$ has the wavelengths of 480-650 nm and The PL intensity of $Eu^{3+}$ has main peak at 590nm.

  • PDF

전자코를 사용한 가열처리 야자유의 판별 (Discrimination of the Heated Coconut Oil using the Electronic Nose)

  • 한기영;오세연;김정환;윤예리;노봉수
    • 한국식품과학회지
    • /
    • 제38권1호
    • /
    • pp.16-21
    • /
    • 2006
  • 본 연구는 야자유를 190, $220^{\circ}C$에서 24시간 가열한 후 6개의 MOS로 구성된 전자코로 산패정도를 판별하였다. 주성분분석 결과 제1주성분 값이 열처리 시간에 따라 +0.952에서 0.325로 감소하였다. 가열 온도를 높임에 따라 야자유의 산패정도도 증가하였다. 또 다른 방법에 하나로 GC를 바탕으로 한 SAW센서가 부착된 전자코를 사용한 결과 후각이미지가 뚜렷하게 차이가 나는 것을 보여주었다. 160, $220^{\circ}C$에서 가열한 야자유로부터 휘발 성분에 대한 GC peak의 수와 넓이가 가열온도와 가열 처리 시간에 따라 증가함을 보여주었다. 이러한 방법은 신속하면서도 곧바로 알기 쉽게 데이터를 이미지화함으로써 가열 처리된 야자유의 휘발성분을 전자코로 신속하고 간편하게 분석하여 가열 처리 정도가 예측 가능하였다.

스트레인게이지 타입 회전형 공구동력계 개발과 3축 정적 하중 검증 (Development of Strain-gauge-type Rotational Tool Dynamometer and Verification of 3-axis Static Load)

  • 이동섭;김인수;이세한;왕덕현
    • 한국기계가공학회지
    • /
    • 제18권9호
    • /
    • pp.72-80
    • /
    • 2019
  • In this task, the tool dynamometer design and manufacture, and the Ansys S/W structural analysis program for tool attachment that satisfies the cutting force measurement requirements of the tool dynamometer system are used to determine the cutting force generated by metal cutting using 3-axis static structural analysis and the LabVIEW system. The cutting power in a cutting process using a milling tool for processing metals provides useful information for understanding the processing, optimization, tool status monitoring, and tool design. Thus, various methods of measuring cutting power have been proposed. The device consists of a strain-gauge-based sensor fitted to a new design force sensing element, which is then placed in a force reduction. The force-sensing element is designed as a symmetrical cross beam with four arms of a rectangular parallel line. Furthermore, data duplication is eliminated by the appropriate setting the strain gauge attachment position and the construction of a suitable Wheatstone full-bridge circuit. This device is intended for use with rotating spindles such as milling tools. Verification and machining tests were performed to determine the static and dynamic characteristics of the tool dynamometer. The verification tests were performed by analyzing the difference between strain data measured by weight and that derived by theoretical calculations. Processing test was performed by attaching a tool dynamometer to the MCT to analyze data generated by the measuring equipment during machining. To maintain high productivity and precision, the system monitors and suppresses process disturbances such as chatter vibration, imbalances, overload, collision, forced vibration due to tool failure, and excessive tool wear; additionally, a tool dynamometer with a high signal-to-noise ratio is provided.