• Title/Summary/Keyword: Screen Printing

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Electrochemical Performance of LSCF Cathode with GDC lnterlayer on ScSZ Electrolyte

  • Hwang, Hae-Jin;Moon, Ji-Woong;Lim, Yongho;Lee, Seunghun;Lee, Eun-A
    • Journal of the Korean Ceramic Society
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    • v.42 no.12 s.283
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    • pp.787-792
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    • 2005
  • A symmetrical LSCF $(La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-\delta})\;ScSZ(89ZrO_2-10Sc_2O_3-1CeO_2)/LSCF$ electrochemical cell with a GDC (Gadolinium-Doped Ceria, $90CeO_2-10Gd_2O_3$) interlayer that was inserted between the LSCF cathode and ScSZ electrolyte was fabricated, and the electrochemical performance of these cells was evaluated. The GDC interlayer was deposited on a ScSZ electrolyte using a screen-printing technique. The GDC interlayer prevented the unfavorable solid-state reactions at the LSCF/ScSZ interfaces. The LSCF cathode on the GDC interlayer had excellent electrocatalytic performance even at $650^{\circ}C$. The Area Specific Resistance (ASR) was strongly dependent on the thickness and heat-treatment temperature of the GDC interlayer. The impedance spectra showed that the cell with a $15\~27{\mu}m$ thick GDC interlayer heat-treated at $1200^{\circ}C$ had the lowest ASR.

Fabrication of Photoimageable Silver Paste for Low-Temperature Cofiring Using Acrylic Binder Polymers and Photosensitive Materials

  • Park, Seong-Dae;Yoo, Myong-Jae;Kang, Nam-Kee;Park, Jong-Chul;Lim, Jin-Kyu;Kim, Dong-Kook
    • Macromolecular Research
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    • v.12 no.4
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    • pp.391-398
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    • 2004
  • Thick-film photolithography is a new technology that combines lithography processes, such as exposure and development, with the conventional thick-film process applied to screen-printing. In this study, we developed a low-temperature cofireable silver paste applicable for thick-film processing to form fine lines using photolitho-graphic technologies. The optimum paste composition for forming fine lines was investigated. The effect of processing parameters, such as the exposing dose, had on the fine-line resolution was also investigated. As the result, we found that the type of polymer and monomer, the silver powder loading, and the amount of photoinitiator were the main factors affecting the resolution of the fine lines. The developed photoimageable silver paste was printed on a low-temperature cofireable green sheet, dried, exposed, developed in an aqueous process, laminated, and then fired. Our results demonstrate that thick-film fine lines having widths < 20 $\mu\textrm{m}$ can be obtained after cofiring.

Discharge Characteristics of Xe Plasma Flat Lamp for LCD Backlight According to Operating Voltage Pulse (LCD 백라이트용 Xe계 플라즈마 평판 램프의 구동 전압 Pulse의 조건에 따른 방전 특성 연구)

  • Kwon, Eun-Mi;Kim, Hyuk-Hwan;Lee, Won-Jong
    • Korean Journal of Materials Research
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    • v.13 no.4
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    • pp.271-278
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    • 2003
  • Conventional backlight for liquid crystal display (LCD) uses mercury which leads to environmental pollution. In this study, characteristics of AC coplanar type mercury-free plasma flat lamp have been studied. Pollution-free Xe-He is adopted as a discharge gas system. Since the Xe gas has a lower efficiency in generating vacuum ultraviolet (VUV) than mercury, the improvement of luminance and luminous efficiency in the Xe gas system is very important. The electrode, dielectric, and phosphor layers constituting lamp are formed on the bottom glass by the screen printing method. The effects of pulse shape, on-time, and pulse frequency on the luminance and luminous efficiency have been examined. For Xe(5%)-He gas, the lamp exhibits higher efficiency with sharper pulse shape, higher peak voltage, and shorter pulse on-time (up to 2 $\mu\textrm{s}$). Higher efficiency and lower consumption of power were obtained at 30 kHz than at 60 kHz. The collision of ion to bottom electrodes is a dominant factor to raise the lamp temperature. Therefore the high voltage and low current discharge system is necessary for reduction of the lamp temperature as well as for enhancement of the luminous efficiency.

Characteristics and Preparation of Gas Sensor Using Nano-ZnO Powders (나노 ZnO 분말을 이용한 가스센서 제작 및 특성연구)

  • Yu, Il
    • Korean Journal of Materials Research
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    • v.25 no.6
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    • pp.300-304
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    • 2015
  • Nanorod ZnO and spherical nano ZnO for gas sensors were prepared by hydrothermal reaction method and hydrazine method, respectively. The nano-ZnO gas sensors were fabricated by a screen printing method on alumina substrates. The gas sensing properties were investigated for hydrocarbon gas. The effects of Co concentration on the structural and morphological properties of the nano ZnO:Co were investigated by X-ray diffraction and scanning electron microscope (SEM), respectively. XRD patterns revealed that nanorod and spherical ZnO:Co with a wurtzite structure were grown with (100), (002), (101) peaks. The sensitivity of nanorod and spherical ZnO:Co sensors was measured for 5 ppm $CH_4$ and $CH_3CH_2CH_3$ gas at room temperature by comparing the resistance in air with that in target gases. The highest sensitivity to the $CH_4$ and $CH_3CH_2CH_3$ gas of spherical nano ZnO:Co sensors was observed at Co 6 wt%. The spherical nano ZnO:Co sensor exhibited a higher sensitivity to hydrocarbon gas than nanorod ZnO.

Effect of Surface Morphology and Adhesion Force on the Field Emisson Properties of Carbon Nanotube Based Cathode (탄소나노튜브 캐소드의 전계방출 특성에 대한 표면 형상과 부착력의 영향)

  • Jung, Hyuk;Cho, You-Suk;Kang, Young-Jin;Kim, Do-Jin
    • Korean Journal of Materials Research
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    • v.18 no.5
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    • pp.277-282
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    • 2008
  • The effects of the field emission property in relation to the surface morphology and adhesion force were investigated. The single-wall-nanotube-based cathode was obtained by use of an in-situ arc discharge synthesis method, a screen-printing method and a spray method. The morphologies of the formed emitter layers were very different. The emission stability and uniformity were dramatically improved by employing an in-situ arc discharge synthesis method. In this study, it was confirmed that the current stability and uniformity of the field emission of the cathode depend on the surface morphology and adhesion force of the emitters. The current stability of the field emission device was also studied through an electrical aging process by varying the current and electric field.

Characteristics of Thick Film Gas Sensors Using Nano ZnO:CNT (나노 ZnO:CNT를 이용한 후막 가스센서의 특성연구)

  • Yoon, So-Jin;Yu, Il
    • Korean Journal of Materials Research
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    • v.24 no.8
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    • pp.413-416
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    • 2014
  • The effects of an addition of CNT on the sensing properties of nano ZnO:CNT-based gas sensors were studied for $H_2S$ gas. The nano ZnO sensing materials were grown by a hydrothermal reaction method. The nano ZnO:CNT was prepared by ball-milling method. The weight range of the CNT addition on the ZnO surface was from 0 to 10%. The nano ZnO:CNT gas sensors were fabricated by a screen-printing method on alumina substrates. The structural and morphological properties of the ZnO:CNT sensing materials were investigated by XRD, EDS, and SEM. The XRD patterns revealed that nano ZnO:CNT powders with a wurtzite structure were grown with (1 0 0), (0 0 2), and (1 0 1) dominant peaks. The size of the ZnO was about 210 nm, as confirmed by SEM images. The sensitivity of the nano ZnO:CNT-based sensors was measured for 5 ppm of $H_2S$ gas at room temperature by comparing the resistance in air with that in target gases.

Crystalline Silicon Solar Cell with Selective Emitter Using One-step Diffusion Process (One-step diffusion으로 형성된 선택적 에미터 결정질 실리콘 태양전지에 관한 연구)

  • Jeong, Kyeong-Taek;Yang, O-Bong;Yu, Gwon-Jong;Lee, Jeong-Chul;Song, Hee-Eun
    • 한국태양에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.40-44
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    • 2011
  • Recent studies in crystalline silicon solar cell fabrication have been focused on high efficiency and low cost. However, the rising of the cost results in additional processes to approach high efficiency. The fabrication process also becomes complicated with additional technologies. In this paper, we studied the selective emitter formation with phosphorous paste to improve the conversion efficiency. Selective emitter formations like two-step diffusion or etch-back method require at least one more step compared in the conventional line since heavily and lightly doped area was needed to form separately.However,one-step diffusion process is the method diffusing heavily and lightly doped area at the same time only with additional screen-printing step. This study lays the foundation for the simple way to form the selective emitter.

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Fabrication of Double Textured Selective Emitter Si Solar Cell Usning Electroless Etching Process (이중 텍스쳐 구조를 적용한 선택적 에미터 태양전지의 특성 분석)

  • Kim, Changheon;Lee, Jonghwan;Lim, Sangwoo;Jeong, Chaehwan
    • Current Photovoltaic Research
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    • v.2 no.3
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    • pp.130-134
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    • 2014
  • We have fabricated the selective emitter solar cell using double textured nanowires structure. The $40{\times}40mm2$-sized silicon substrates were textured to form the pyramid-shaped surface and the nanowires were fabricated by metal assisted chemical etching process using Ag nanoparticles, subsequently. The heavily doped and shallow emitters for selectiv eemitter solar cells were prepared through the thermal $POCl_3$ diffusion and chemical etch-back process, respectively. The front and rear electrodes were prepared following conventional screen printing method and the widths of fingers have been optimized. The selective emitter solar cell using double textured nanowires structure achieved a conversion efficiency of 17.9% with improved absorption and short circuit current density.

Effect of SLS Glass for Bulletproof Materials by Ion Exchange Technique (방탄소재 활용을 위한 SLS 유리의 이온교환 효과)

  • Kim, Tae-Yoon;Shim, Gyu-In;Choi, Se-Young
    • Journal of the Korea Institute of Military Science and Technology
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    • v.13 no.1
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    • pp.114-119
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    • 2010
  • There are a number of studies on chemically strengthened glass. Most of them are strengthened in molten salt bath below transformation range of glass. This research is distinguished from the aforementioned studies in that single $KNO_3$ powder was used by employing screen printing technique. In this study soda-lime-silicate(SLS) glasses for bulletproof glass application with various thicknesses were used. The maximum value of the bending strength is 791MPa heat treated at $480^{\circ}C$, which is about 4.3 times higher than the parent glass, which is the highest strength of all soda-lime glasses. In this study, it is also observed that Vickers hardness increased to $657H_v$, which is about 15% higher than the parent glass($568.7H_v$) and fracture toughness was not changed. Depth profiles measured by electron probe micro analyzer(EPMA) showed a correlation between the migrations of $K^+$ ions with bending strength of ion exchanged glasses.

Glass Infiltration법에 의한 $Al_2O_3$/Glass/$Al_2O_3$ 세라믹스의 Ag 전극 matching

  • Jo, Tae-Jin;Yeo, Dong-Hun;Sin, Hyo-Sun;Hong, Yeon-U;Kim, Jong-Hui;Jo, Yong-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.302-302
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    • 2008
  • 다층 세라믹 기판은 내열성, 내마모성 및 우수한 전기적 특성으로 인하여 기존의 PCB의 대체품으로 많이 이용되며 그 수요가 점점 늘어가고 있는 추세이다. 이에 고집적 다층 세라믹 기판을 보다 다기능화, 고밀도화, 고성능화하기 위해서는 세라믹 층간 정밀도가 아주 중요한 요소로 부각되고 있으며, 무수촉 기판 소성기술을 이용한 층간 정밀도를 높이는 연구가 진행되어지고 있다. 그러나 무수축 기판에서 이러한 정밀도를 유지하기 위해서는 전극의 수축률을 기판의 수축율과 같은 0%에 가깝게 제어하여야 하며 이를 위해서 여러 가지 Frit을 이용하여 수축율을 제어를 시도되고 있다. Ag 전극은 낮은 비저항 우수한 접착성 등의 장점을 가지고 있을 뿐 아니라 가격이 저렴하여 전극재료로서 많은 연구가 이루어졌다. 특히 Infiltration법에 의한 무수축소성의 경우 Glass가 Ag paste로 Infiltration되어 Ag paste와 세라믹의 matching성 확보에 많은 문제가 발생하였다. 이에 본 실험에서는 제조된 Ag conductor paste 에 첨가되는 frit이 무수축 기판과의 매칭성에 어떠한 영향이 있는지에 대하여 고찰하였다. 시편의 준비는 frit이 첨가된 Ag paste를 기판에 screen printing 한 후 $900^{\circ}C$에서 소결한 것을 사용하였으며 Ag 전극의 미세구조를 관찰하고 전기적 특성과 미세구조와의 연관성에 관해 고찰하였다.

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