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A simulation study on synthesis gas process optimization for FT(Fischer-Tropsh) synthesis (FT(Fischer-Tropsh) 합성유 제조를 위한 합성가스 공정 최적화 연구)

  • Kim, Yong-Heon;Lee, Won-Su;Lee, Heoung-Yeoun;Koo, Kee-Young;Song, In-Kyu
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.888-888
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    • 2009
  • A simulation study on SCR (Steam Carbon dioxide Reforming) process in gas-to-liquid (natural gas to Fischer-Tropsch synthetic fuel) process was carried out in order to find optimum reaction conditions for GTL (gas-to-liquid) process reaction. Optimum SCR operating conditions for synthesis gas to FT (Fischer-Tropsch) process were determined by changing reaction variables such as feed temperature and pressure. During the simulation, overall synthesis process was assumed to proceed under steady-state conditions. It was also assumed that physical properties of reaction medium were governed by RKS (Redlich-Kwong-Soave) equation. SCR process was considered as reaction models for synthesis gas in GTL proess. The effect of temperature and pressure on SCR process $H_2$/CO ratio and the effect of reaction pressure on SCR reaction were mainly examined. Simulation results were also compared to experimental results to confirm the reliability of simulation model. Simulation results were reasonably well matched with experimental results.

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Experimental studies on the diesel engine urea-SCR system using a double NOx sensor system

  • Tang, Wei;Cai, Yixi;Wang, Jun
    • Environmental Engineering Research
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    • v.20 no.4
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    • pp.397-402
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    • 2015
  • SCR has been popularly approved as one of the most effective means for NOx emission control in heavy-duty and medium-duty vehicles currently. However, high urea dosing would lead to ammonia slip. And $NH_3$ sensor for vehicle emission applications has not been popularly used in real applications. This paper presents experimental studies on the diesel engine urea-SCR system by using a double NOx sensor system that is arranged in the downstream of the SCR catalyst based on ammonia cross-sensitivity. It was shown that the NOx conversion efficiency rised as $NH_3/NOx$ increases and the ammonia slip started from the $NH_3/NOx$ equal to 1.4. The increase of temperature caused high improvement of the SCR reaction rate while the space velocity had no obvious change. The ammonia slip was in advance as catalyst temperature or space velocity increase and the ammonia storage reduced as catalyst temperature or space velocity increase. The NOx real-time conversion efficiency rised as the ammonia accumulative storage increase and reached the maximum value gradually.

선박용 SCR 시스템 상용화 (운항 선박 실증 테스트 및 적합성 인증)

  • Yang, Hui-Seong;Park, Jae-Hyeon;Park, Chan-Do;Lee, Seong-Yeong;Go, Jun-Ho;Song, Seok-Yong;Lee, Jae-U;Ryu, Seung-Ho;An, Gwang-Heon
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2011.10a
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    • pp.41-41
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    • 2011
  • 국제해사기구(IMO)에서2016년에 건조되는 선박부터 Tier III 규제를 예고하고 있다. 이 규 제를 만족하기 위하여 엔진 전처리 기술 및 후처리 기술 개발과 실증 연구가 활발히 진행되고 있다. 이중 SCR(Selective Catalytic Reduction) 반응을 이용한 질소산화물 저감기술이 80% 이상의 Tier III NOx 규제치를 만족할 수 있는 유일한 기술이다. 육상 플랜트에서 실증과 검증이 확보된 SCR 기술의 선박 엔진에 대한 적용을 위해서는 선박의 급격한 운전조건 변화와 엔진에 의한 저주파 진동에 대한 촉매 내구성 확보가 중요하다. 본 연구에서 기공 분포면에서 마이크로 기공보다는 메죠 및 매크로 기공쪽으로 구조를 개선함으로써 촉매 사용시 우려되는 배기가스중의 Soot 또는 2차 합성물질에 의한 촉매기공 막힘을 최대한 방지한 상용 SCR 촉매를 개발하였다. 또한 촉매에 대한 내구성 실증을 위하여 현재 운항 선박(한진피츠버그호)에 장착하여 실증 실험을 수행하였다. 기존 corrugate 타입의 촉매보다 40% 정도의 부피 감소와 차압 감소를 달성하였고 이로 인하여 선박내 제한된 공간에 효율적으로 SCR 시스템 설치가 가능할 것으로 생각된다. 그리고 본 연구에서는 가이드 베인 설치 없이 유동 균일화를 달성하여 반응기 전체의 크기 축소가 가능하다. 이는 추가적인 비용 및 압력 손실 저감, 유지 보수 공간 확보 등의 장점이 있다.

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A Study on the Characteristics of NOx Reduction by Urea-SCR System for a Light-Duty Diesel Engine (Urea-SCR 시스템에 의한 소형 디젤엔진의 NOx 저감 특성에 관한 연구)

  • Nam, Jeong-Gil;Lee, Don-Chool;Choi, Joo-Yol;Choi, Jae-Sung
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.06a
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    • pp.521-527
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    • 2005
  • The effects of an urae injection at the exhaust pipe for a 4-cylinder DI(Direct Injection) diesel engine are investigated experimentally. The urea quantity was controlled by NOx quantity and MAF(Manifold Air Flow). The urea injection must be precisely metered and then I used the urea syringe pump. I have tested 4 kinds of items that were with the EGR base engine and without the EGR engine. Then I tested each urea-SCR(Selective Catalytic Reduction) system. As the results, I can caculate the SUF(Stoichiometric Urea Flow) and visualize the NOx results by variation of engine speed and engine load. Also, I can make the NOx map. Therfore, I knew that NOx reduction effects of the urea-SCR system without the EGR engine were better than the with EGR base engine except of low load and low speed.

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Effect of NH3 Uniformity Index on SCR System According to Urea Spray Characteristics (요소수 분무특성이 SCR시스템 내 분무균일도에 미치는 영향)

  • Kim, Se Hun;Ko, Jin Seok;Ko, Jae Yu;Cho, Young Jun;Lee, Dong Ryu
    • Journal of ILASS-Korea
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    • v.24 no.4
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    • pp.178-184
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    • 2019
  • Diesel engines have the advantages of higher thermal efficiency and lower CO2 emissions than gasoline engines, but have the disadvantages that particulate matter (PM) and nitrogen oxides (NOx) emissions are greater than those of gasoline engines. In particular, nitrogen oxides (NOx) emitted from diesel engines generates secondary ultrafine dust (PM2.5) through photochemical reactions in the atmosphere, which is fatal to humans. In order to reduce nitrogen oxides (NOx), pre-treatment systems such as EGR, post-treatment systems such as LNT and Urea SCR have been actively studied. The Urea SCR consists of an injection device injecting urea agent and a catalytic device for reducing nitrogen oxides (NOx). The nitrogen oxide (NOx) reduction performance varies greatly depending on the urea uniformity in the exhaust pipe. In this study, spray characteristics according to the spray hole structure were confirmed, and the influence of spray uniformity on spray characteristics was studied through engine evaluation.

A Study on the PCD Plasma System as an After Treatment Apparatus in Diesel Engine (디젤엔진의 후처리장치로서 PCD 플라즈마 시스템에 관한 연구)

  • Ryu, Kyung-Hyun
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.2
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    • pp.70-77
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    • 2012
  • The selective catalytic reduction(SCR) system used to reduce NOx in diesel engines requires an NO/$NO_2$ ratio of about 1 in exhaust emissions to realize the fast SCR mode at temperatures lower than $300^{\circ}C$. This study investigated the characteristics of a plasma system as a pre-active apparatus for the fast SCR reaction mode of an SCR system. Plasma was generated by the pulse corona discharge(PCD) method with a four-channel wire-cylinder reactor. This study showed that plasma was easily generated in the exhaust gas by the PCD system, and the peak voltage of the normal state condition for plasma generation was generally 12 kV. The PCD system easily converted NO into $NO_2$ at lower temperatures and the NO/$NO_2$ conversion ratio increased with the discharge current for plasma generation. But the PCD system could not convert NO into $NO_2$ at higher engine speeds and higher engine loads due to the lack of oxygen in exhaust gas. The PCD system also activated the diesel oxidation catalysts(DOC) system to reduce CO emissions.

Development of Digital controlled SCR type CO2 Welding System for Implementation Pulse Output (펄스 출력 구현이 가능한 디지털 제어의 SCR형 CO2 용접시스템의 개발)

  • Eun, Jong-Mok;Choe, Gyu-Ha
    • Journal of Welding and Joining
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    • v.32 no.1
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    • pp.102-107
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    • 2014
  • SCR(Thyristor) type $CO_2$ welders have widely used for the welding process of heavy industries such as shipbuilding and plant. Since the industrial fields of shipbuilding and plant are usually exposed to severe welding condition with lots of dust, extreme temperature, high humidity and vibration, it is not recommended to use inverter type welder despite its state-of-the-art technology. Many sophisticated functions in the inverter welder may not work due to malfunction of its sensitive components. Hence this study focused on digitalization of SCR $CO_2$ welder by making use of microprocessor for SCR phase control. By this application, fine control of output of the $CO_2$ welding systems is achieved. Also pulse output mode of operation is realized and its verification is carried out with aluminum sample welding. The experimental results showed sound weld bead. The front operation panel provide user with numerical parameter settings and monitors. It will help precise weld process monitoring and control with digital value.

Emission Characteristics of Hazardous Air Pollutants from Diesel Heavy duty Trucks for Euro 5 (Euro 5 경유 대형트럭의 유해대기오염물질 배출특성)

  • Hong, Heekyoung;Mun, Sunhee;Seo, Seokjun;Kim, Jounghwa;Jung, Sungwoon;Chung, Taekho;Hong, Youdeog;Sung, Kijae;Kim, Sunmoon
    • Journal of ILASS-Korea
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    • v.23 no.2
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    • pp.74-80
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    • 2018
  • Emission characteristics of regulated pollutants (CO, NOx, HC and PM) and hazardous air pollutants (HAPs) from diesel heavy duty trucks equipped with EGR+pDPF and SCR for Euro 5 emission standards were investigated using a chassis dynamometer. In the case of regulated pollutants, diesel heavy duty trucks with EGR+pDPF emitted 79% less CO than those with SCR. Also, those with the SCR emitted 36% less NOx than those with the EGR+pDPF. The results of VOCs have show that alkanes emissions for heavy duty trucks with the EGR+pDPF and the SCR have been higher than alkenes, cycloalkanes and aromatics. In the case of individual VOCs, the highest of propene emissions for 11.3~16.1% occupied. For aromatics group, benzene emissions are the highest percentage for 4.4~15.5%. In the future, the results of present study will provide basic data to set up HAPs emissions inventory for mobile source.

A Study on the Efficiency when replacing SSR Dimmer with IGBT SINEWAVE Dimmer in Concert Halls (공연장에서 사용하고 있는 SSR조광기를 새로운 IGBT 싸인웨이브 조광기로 교체시 효율성에 관한 연구)

  • Lee, Jang-Weon;Kwon, Hyeok-Hwan
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.15 no.3
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    • pp.219-224
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    • 2015
  • Today, High Social demand for Energy Saving. This have been Studied for the purpose, Having an Efficiency of much it, in IGBT DIMMER SYSTEM compared to the existing SSR,SCR Dimmer System. The Method Two, The First is Dimming in Dimmer System How much Power loss Appears of A Comparison Experiment According to the output a SINEWAVE Strain, Comparative Measurements Experimental were Conducted with Oscilloscope. Second, When Dimming the sound has equipment by measuring the relative Size Decibel Experiment was conducted in Decibel Meter about the Equipment Noise. Results Thus Confirm SSR, SCR Dimmer IGBT SINEWAVE Dimmer more Efficiently.

Optimal Operation Condition of Pressurized Methanol Fuel Processor for Underwater Environment (수중환경용 가압형 메탄올 연료프로세서의 최적운전 연구)

  • JI, HYUNJIN;CHOI, EUNYEONG;LEE, JUNGHUN
    • Journal of Hydrogen and New Energy
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    • v.27 no.5
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    • pp.485-493
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    • 2016
  • Recently submarine and unmanned underwater vehicle (UUV) are equipped with a fuel cell system as an air independent propulsion system. Methanol fuel processor can efficiently supply the hydrogen to the fuel cell system to improve the ability to dive. This study investigated the optimal conditions of the methanol fuel processor that may be used in the closed environment. For this purpose, the numerical model based on Gibbs minimization equation was established for steam reformer and three exhaust gas burners. After simulating the characteristics of steam reformer according to the steam-to-carbon ratio (SCR) and the pressure change, the SCR condition was able to narrow down to 1.1 to 1.5. Considering water consumption and the amount of heat recovered from three burners, the optimum condition of the SCR can be determined to be 1.5. Nevertheless, the additional heat supply is required to satisfy the heat balance of the methanol fuel processor in the SCR=1.5. In other to obtain additional amount of heat, the combustion of methanol is better than the increased of SCR in terms of system design.