• Title/Summary/Keyword: Sb removal

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Pollutant Removal Efficiency of Sedimentation Basin at Inlet of an Irrigation Reservoir (저수지 내 유입부 침강지의 수질정화 효율)

  • Jang, Jeong-Ryeol;Choi, Sun-Hwa;Kwun, Soon-Kuk
    • Journal of Korean Society on Water Environment
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    • v.20 no.5
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    • pp.473-479
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    • 2004
  • A sedimentation basin (SB) at the inlet of an irrigation reservoir which was constructed using an auxiliary dam was monitored to evaluate its pollutant removal efficiency. Water sampling at three points, i.e., inflow stream, upstream and downstream of the reservoir, were taken 5 times before and after the construction of the SB in 1999 and 2003, respectively. No significant water quality variations in inflow stream were observed during these periods. The COD, T-N, T-P and SS removal efficiencies were 38, 24, 35 and 49%, respectively. The results indicated that those removal efficiencies significantly increased during the rainy season and COD removal efficiency, especially, was higher than others studies. The scale of SB in this study was rational as aspects of pollutant removal efficiency and hydraulic detention time. And it is recommended that SB, at inlet of an reservoir, should be constructed as completely separated structure from reservoir water body and having SAR Index from 0.7% to 1.0%.

Microstructural features of Laser Radiated GeSbTe Intermetallic Compounds (레이저 조사시킨 GeSbTe 금속간 화합물의 미세조직)

  • 박정우;김명룡
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.66-72
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    • 1995
  • Microstructural features of laser irradiated bulk target which consists of GeSbTe interrmertallic compounds were examined by analytical microscopy. It was found that in addition to vaporization, a liquid expulsion due to laer-material interatction is main contribution of materials removal in the sintered GaSbTe targets, The morphological change is qualitatively discussed in the present article.

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A study on the removal of As, Sb, Bi from the copper sulfate solutions by Ion exchange resin containing Aminophosphosphonic acid as a functional group (황산동용액(黃酸銅溶液)에서 Aminophosphosphonic acid 관능기를 가진 이온교환수지에 의한 As, Sb, Bi 제거(除去)에 관한 연구(硏究))

  • Ahn, Jae-Woo;Seo, Jae-Seong
    • Resources Recycling
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    • v.21 no.5
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    • pp.50-57
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    • 2012
  • A comparative study has been carried out on the removal of impurities such As, Sb, Bi from the copper sulfate solution by ion exchange resin containing aminophosphosphonic acid as functional group. The various parameters which affect the removal of impurities; such as the reaction temperature, the reaction time, the amount of ion-exchange resins, the concentration of sulfuric acid in electrolyte, were studied. The basic experimental results showed that about 88% of Sb & 94% of Bi can be adsorbed in these chelate resins and removed from the copper sulfate solutions but As was removed below 10% from the solutions. And the selective elution of Bi and Sb from the adsorbed ion exchange resin also can be achieved by $H_2SO_4$ or HCl solutions. The results also showed that 98.1% of Sb and 96.6% of Bi can be adsorbed from the copper sulfate solutions after 2 Bed-volume of continuous ion exchange column test.

A Study on Distribution Behavior of Ni and Sb in Reduction products of Cu Matte Converting (동 매트제련의 반응생성물중 Ni와 Sb의 분배거동에 관한 연구)

  • 김영진;이광막;김영홍
    • Resources Recycling
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    • v.8 no.5
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    • pp.44-50
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    • 1999
  • The sbdy iwestlgaled ihc propa-ties of Lhe dust\ulcorner rrom fe~~oallomya ~~ufacturTeh. e chemical composition, cornpasitlon material, p d c l e sire md shapes of the bulk dust, sired dust and magnetically separated durl were mvesligaled. As the re\ulcornerulL, we suppose that the dust from &gh Carbon Fenama~~gunesMc anuiact~vingP rocess is not sufiicient as solulce material of Mn because of ale low Mn canlenl (13.5%) and complicaled composition mate~ial. The dust from Bug F!lter or AOD Proccss is mi~inlym ade up of 0.2-2 pm Mn30, (Hausmam~iu)p iutlde in spherical shape and thc Mn content is 63.190.The dust from Cooler of AOD Process is inninly made up of coarse Ca(O1-Or)zM. n,FeyO,, SiO, and fine Mn30d.

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Effect of SO2 on NOx Removal Performance in Low Temperature Region over V2O5-Sb2O3/TiO2 SCR Catalyst Washcoated on the Metal Foam (저온영역에서 메탈폼에 코팅된 V2O5-Sb2O3/TiO2 SCR 촉매의 NOx 저감성능에 미치는 SO2 영향에 관한 연구)

  • Na, Woo-Jin;Park, Young-Jin;Bang, Hyun-Seok;Bang, Jong-Seong;Park, Hea-Kyung
    • Clean Technology
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    • v.22 no.2
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    • pp.132-138
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    • 2016
  • The emission of SO2 is inevitable in case of combustion of most fossil fuels except LNG in commercial power plant which has a bad effect on the durability of SCR catalyst. To develop a low temperature SCR catalyst which has a high NOx removal performance and excellent durability to SO2, V2O5/TiO2 catalysts were prepared by coating on the metal foam substrate with the impregnation amount of Sb2O3 as promotor. This study has evaluated the NOx removal performance and the durability to SO2 on a laboratory scale atmospheric reactor and analyzed the properties of the prepared catalysts by means of porosimeter, BET, SEM (scanning electron microscope), EDX (energy dispersive x-ray spectrometer), XPS (X-ray photoelectron spectroscopy). It was found that the surface area of catalyst increased with the impregnation amount of Sb2O3 and the NOx removal performance showed the highest value at the 2 wt% impregnation of Sb2O3. This results was considered to be due to the optimum active site on the catalyst surface. And also, Sb2O3 impregnated catalysts presented that NOx removal performance was maintained despite the exposure to SO2 for 5 hours. Therefore it was confirmed that metal foam SCR catalyst for low temperature could be manufactured with the optimum control of Sb2O3 impregnation according to the SO2 presence or not.

Electrochemical treatment of cefalexin with Sb-doped SnO2 anode: Anode characterization and parameter effects

  • Ayse, Kurt;Hande, Helvacıoglu;Taner, Yonar
    • Advances in nano research
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    • v.13 no.6
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    • pp.513-525
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    • 2022
  • In this study, it was aimed to evaluate direct oxidation of aqueous solution containing cefalexin antibiotic with new generation Sn/Sb/Ni: 500/8/1 anode. The fact that there is no such a study on treatment of cefalexin with these new anode made this study unique. According to the operating parameters evaluation COD graphs showed clearer results compared to TOC and CLX and thus, it was it was chosen as major parameter. Furthermore, pseudo-first degree kd values were calculated from CLX results to show more accurate and specific results. Experimental results showed that after 60 min of electrochemical oxidation, complete removal of COD and TOC was accomplished with 750 mg L-1 KCl, at pH 7, 50 mA cm-2 current density and 1 cm anode-cathode distance. Also, the stability of the Sn/Sb/Ni anode was evaluated by taking SEM and AFM images and XRD analysis before and after of electrochemical oxidation processes. According to the results, it was not occurred too much change on the anode surface even after 300 h of electrolysis. Thus, it was thought that the anode material was not corroded to a large extent. Furthermore, the removal efficiencies were very high for almost all the time and conditions. According to the results of the study, electrochemical oxidation with new generation Sn/Sb/Ni anodes for the removal of cefalexin antibiotic was found very successful and applicable due to require less reaction time complete mineralization and doesn't require pH adjustment step compared to other studies in literature. In future studies, different antibiotic types should be studied with this anode and maybe with real wastewaters to test applicability of the process in treatment of pharmaceutical wastewaters containing antibiotics, in a better way.

The Selective Removal of Sb and Pb from Molten Bi-Pb-Sb Alloy by Oxidation (용융(熔融) Bi-Pb-Sb계(系) 합급(合金)의 산화(酸化)에 의한 Sb과 Pb 제거(除去))

  • Kim, Se-Jong;Son, In-Joon;Sohn, Ho-Sang
    • Resources Recycling
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    • v.21 no.4
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    • pp.53-59
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    • 2012
  • In this study, behaviors of removing Sb and Pb by oxidation of molten Bi-Pb-Sb alloy which is a by-product of non-ferrous smelting process was investigated. The molten alloy was oxidized at 1173 K by bubbling $N_2+O_2$ gas through a submerged nozzle. The Sb was removed and recovered as mixed phase of $Sb_2O_3$ and metal Sb. In the case of bubbling $N_2+O_2$ gas into molten Bi-Pb alloy at 923 K, Pb was oxidized and removed to slag. But Bi could not be refined due to simultaneous oxidization of Bi with Pb.

Evaluation of dynamic behavior of coagulation-flocculation using hydrous ferric oxide for removal of radioactive nuclides in wastewater

  • Kim, Kwang-Wook;Shon, Woo-Jung;Oh, Maeng-Kyo;Yang, Dasom;Foster, Richard I.;Lee, Keun-Young
    • Nuclear Engineering and Technology
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    • v.51 no.3
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    • pp.738-745
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    • 2019
  • Coprecipitation using hydrous ferric oxide (HFO) has been effectively used for the removal of radionuclides from radioactive wastewater. This work studied the dynamic behavior of HFO floc formation during the neutralization of acidic ferric iron in the presence of several radionuclides by using a photometric dispersion analyzer (PDA). Then the coagulation-flocculation system using HFO-anionic poly acrylamide (PAM) composite floc system was evaluated and compared in seawater and distilled water to find the effective condition to remove the target nuclides (Co-60, Mn-54, Sb-125, and Ru-106) present in wastewater generated in the severe accident of nuclear power plant like Fukushima Daiichi case. A ferric iron dosage of 10 ppm for the formation of HFO was suitable in terms of fast formation of HFO flocs without induction time, and maximum total removal yield of radioactivity from the wastewater. The settling time of HFO flocs was reduced by changing them to HFO-PAM composite floc. The optimal dosage of anionic PAM for HFO-anionic PAM floc system was approximately 1-10 ppm. The total removal yield of Mn-54, Co-60, Sb-125, Ru-106 radionuclides by the HFO-anionic PAM coagulation-flocculation system was higher in distilled water than in seawater and was more than 99%.

The Evaluation of Pollutant Removal Efficiencies by Sedimentation Basin Types constructed at the Inlets of Irrigation Reservoirs (농업용 저수지 내 침강지의 설치유형에 따른 수질정화효율 평가)

  • Jang, Jeong-Ryeol;Choi, Sun-Hwa;Nam, Gui-Sook;Kwun, Soon-Kuk
    • Journal of Korea Water Resources Association
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    • v.38 no.8 s.157
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    • pp.665-674
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    • 2005
  • The aim of this study is to evaluate 3 types of sedimentation basins: dredging, shield skirt and auxiliary dam, constructed at inlets of two irrigation reservoir and to estimate the most beneficial type and fitted size, SAR(surface to area ratio), for pollutant removal efficiency(RE). For this, RE of major water quality items and change of physicochemical properties in sediments before and post construction of sedimentation basin(SB) were investigated. RE depended on SB types, water quality items and survey times with wide range from $-87\%$ to $92\%$. Long term overall removal efficiency by ROC(regression of concentration) method were $18\%$ in dredging, $29\%$ in shield skirt and $42\%$ in auxiliary dam type. There was a change of physicochemical properties in sediments at auxiliary dam type, while a slight change at dredging and shield skirt type. In comparison to RE, SAR and hydraulic retention time at 3 types of SB, auxiliary dam type was the most beneficial one. Thus, it is recommended that SB would be constructed in completely separated structure from water body of a reservoir with SAR ranged from 0.7 to $1.0\%.$

COD Removal of Rhodamine B from Aqueous Solution by Electrochemical Treatment

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.21 no.6
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    • pp.655-659
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    • 2012
  • This study elucidates the COD removal of dye (Rhodamine B) through electrochemical reaction. Effects of current density (7.2 to 43.3 $mA/cm^2$), electrolyte type (NaCl, KCl, $Na_2SO_4$, HCl), electrolyte concentration (0.5 to 2.0 g/L), air flow rate (0 to 4 L/min) and pH (3 to 11) on the COD removal of Rhodamine B were investigated. The observed results showed that the increase of pH decrease the COD removal efficiency. Whereas, the increase of current density;NaCl concentration and air flow rate caused the increase of the COD removal of Rhodamine B.