• Title/Summary/Keyword: Saturation concentration

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Magnetic and Magneto-Optical Properties of FeCo/Pd Multilayers (FeCo/Pd 초격자 다층박막의 자기 및 자기광학적 특성)

  • 김진홍;신성철
    • Journal of the Korean Magnetics Society
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    • v.3 no.1
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    • pp.56-60
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    • 1993
  • We have investigated the dependence of the magnetization, anisotropy, coercivity, and Kerr rotation on the Fe concentration in FeCo/Pd multilayer thin films, where the Fe concentration in the FeCo sublayer varied between 0 and 100% with maintaining the same sublayer thickness of $2.5\;{\AA}$ FeCo and $10.5\;{\AA}$A Pd. The maximum saturation magnetization was observed at the Fe concentration of about 48at.% in the FeCo sublayer. Perpendicular magnetic anisotropy and coercivity of the FeCo/Pd multilayer thin film decreased monotonically with increasing the Fe con-centration. The Kerr rotation angle also decreased with increasing the Fe concentration and the amount of vari-ation was remarkably changed with decreasing the light wavelength.

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Halogen Etching of Si(100)-2x1 : Dependence on Vacancy Creation and Surface Concentration

  • Nakayama, Koji
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.146-146
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    • 2000
  • We have studied the etching of Si(100)-2xl by Cl and Br, using scanning tunneling microscopy to obtain morphological information that can be related to reaction and desorption pathways. Clean surfaces were exposed to molecular halogens at room temperature to produce well-defined chemisorption structures for coverages in the range 0.2-1.0 ML. Heating to 750-750 K induced etching by thermal desorpton. Analysis of the halogen concentration before and after heating indicated that the rates of desorption for SICl2 or SiBr2 were greatest for intermediate coverages and that etching was suppressed as saturation was reached. Hence, desorption is not simply proportional to the concentration of species that can form adsorbed precursors SiX2(a). Instead, it is directly coupled to the creation of monomer vacancies adjacent to the SiX2 (a) unit because this increases the lifetime of the excited state and increases the likelihood of its desorption. Increasing the surface concentration of halogens reduces the rate of vacancy formation. We show that these rates are also affected by a re-dimerization process in the high temperature Br-stabilized Si(100)-3xl reconstruction that increases the likelihood of siBr2(a) formation and enhances its desorption. I will also discuss recent result for F etching on Si(100)-2xl.

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Micelle Studies of Dodecyltrimethylammonium Bromide in Water as Probed by Benzene: Effect on Shapes and Sizes of Micelles

  • Yoon Seob Lee;Kyu Whan Woo
    • Bulletin of the Korean Chemical Society
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    • v.14 no.5
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    • pp.599-602
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    • 1993
  • Micellization process of dodecyltrimethylammonium bromide (DTAB) was studied by using the aromatic probe (benzene) which dissolved in aqueous DTAB solutions. Proton NMR chemical shift measurements of DTAB and DTAB-benzene system showed that benzene molecules solubilized near the micelle-water interface and that the solubilization sites within the micelles are different as the DTAB concentration is passing through 32.0 mM (hereafter we refer this concentration as the second CMC). The change of solubilization sites is also confirmed by abrupt changes of the chemical shifts and relaxation rates of benzene protons in DATB-benzene system at this concentration. It was revealed from the electrical conductivity and viscosity measurements that the solubilization of benzene caused the DTAB micelles to swell out and that the micelles prepared after the second CMC had a greater swelling effect than those prepared before the second CMC. The transition point which reflects the saturation of benzene molecules on the solubilization sites of micelles was observed at one benzene/micellized DTAB mole ratio from the electrical conductivity measurements. Along the different concentration of DTAB solution, this transition point is appeared clearly after the second CMC. From these results it is suggested that the shapes and/or sizes of DTAB micelles of the spherical micelle region prepared after the second CMC are different from those prepared before the second CMC.

Effect of Anodizing and Dyeing Treatments on Coloring of Al-Mg (Al-Mg합금의 컬러에 미치는 양극산화 및 착색처리의 영향)

  • Bae, Sung Hwa;Lee, Hyun Woo;Son, Injoon
    • Journal of the Korean institute of surface engineering
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    • v.52 no.1
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    • pp.30-36
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    • 2019
  • In this study, we investigated the effects of anodizing time, dyeing treatment time, and variations in coloring concentration on the color of an AA5052 alloy processed by dye-treated anodizing. The outward color of the anodized film changed to deep red according to increases in anodizing time, dyeing treatment time, and coloring concentration; accordingly, lightness $L^*$ decreased and saturation $a^*$ and $b^*$ increased. The concentration of the dye and the UV-visible absorbance showed a nearly perfect linear relationship, allowing a quantitative analysis of the absorbed dye. Because the quantity of absorbed dye increased as anodizing time, dyeing treatment time, and coloring concentration increased, the outward color of the anodized film deepened. In addition, from the GD-OES depth profile, we found that the dye was preferentially absorbed on the surface of the porous anodized film.

Setting Behavior and Drug Release from Brushite Bone Cement prepared with Granulated Hydroxyapatite and β-Tricalcium Phosphate

  • Son, Yeong-Jun;Lee, In-Cheol;Jo, Hyun-Ho;Chung, Tai-Joo;Oh, Kyung-Sik
    • Journal of the Korean Ceramic Society
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    • v.56 no.1
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    • pp.56-64
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    • 2019
  • Calcium phosphate bone cement was prepared to contain antibiotics for release after setting using granulated ${\beta}$-tricalcium phosphate (${\beta}$-TCP) and hydroxyapatite (HA). Gentamicin sulfate (GS) solution was infiltrated within the interconnected pores of the granule to avoid affecting the setting reaction and for protection of GS during the setting. Consequently, the setting time and the temperature increase were not affected, regardless of the loading of GS. The release of the GS from the cement was estimated by measuring the concentration at regular intervals from the cement dipped solution. The ${\beta}$-TCP granule loaded with GS exhibited the saturation of accumulative concentration at 16 h. In contrast, the HA granule with GS exhibited steady increase in accumulative concentration of over $10{\mu}g/ml$ at 144 h. Thus, the granulated cement could release the GS greater than the minimum inhibitory concentration of staphylococcus during the prescription peroid of the oral antibiotics.

Correlation between Phytoplankton Dynamics and Water Quality in Paldang Reservoir (팔당호에서 식물플랑크톤 군집 동태와 수질과의 상관성)

  • Han, Myung-Soo;Jheong, Weon-Hwa;Park, Jun-Dae;Kim, Jong-Min
    • Korean Journal of Ecology and Environment
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    • v.38 no.2 s.112
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    • pp.217-224
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    • 2005
  • This study was aimed to analyze the long-term fluctuation of water quality and phytoplankton dynamics of Paldang reservoir in Korea and to assess the relationship between algal bloom patterns and hydrological, limnological data. Diatoms in Paldang reservoir occurred continuously through the year. Blue- green algae occurred during the summer season (from June to Sept.), and the highest count was observed in July. Occurrence pattern of green algae was similar to that of blue-green algae. The rest of algae contained a lot of Cryptomonas spp. whose concentration was high from May to Aug. Dominant algal genera (>>7,000 cells $mL^{-1}$) in Paldang reservoir were Aulacoseira, Cyclotella, Microcystis, and Cryptomonas spp. Microcystis and Anabaena occurred during the summer season. Many different green algal genera were found in Paldang reservoir but their abundances were very low. There were some significant correlations (r>0.3, p<0.05) between algal taxa and water quality; diatoms and water temperature, TP:blue-green algae and water temperature, pH, DO saturation, COD, TP; green algae and water temperature, pH, DO saturation, COD, SS, TP. Furthermore, algal genera and water quality was significantly correlated (r>0.3, p<0.05) ; Aulacoseira and TN, TP; Anabaena and water temperature, DO saturation, COD, TP : Microcystisand water temperature, pH, DO saturation, TP; Coelastrum and COD, SS; Scenedesmus and water temperature, COD, TN, TP; Cryptomonas and DO saturation, TN. In Paldang reservoir, the water temperature had relatively big effect on blue-green algal bloom that was also dependant upon its hydrologic condition.

Estimating Saturation-paste Electrical Conductivities of Rose-cultivated Soils from their Diluted Soil Extracts (절화장미 재배토양에서 희석된 토양 침출용액으로부터 포화반죽 전기전도도 추정)

  • Lee, In-Bog;Ro, Hee-Myong;Lim, Jae-Hyun;Yiem, Myoung-Soon
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.6
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    • pp.398-404
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    • 2000
  • We examined the effect of soil:water ratio on the equivalent concentration of individual electrolyte species and the electrical conductivities (EC) of the diluted extracts of 24 soil samples (loam or silt loam) collected from rose-cultivated plastic houses to estimate the EC of saturated soil-paste extracts (ECe) from diluted soil extracts. With increasing volume ratio of water (higher dilution), the equivalent concentrations of each electrolyte species and their sum increased. The relative contribution to the EC, however, was highest for $NO_3{^-}$, irrespective of soil:water ratio. The measured ECe was 6.36 for loam and $8.09dS\;m^{-1}$ for silt loam soils and the corresponding soil:water ratio was 0.38 and 0.50, respectively. The EC_e estimated from the EC of diluted extracts at 1:1, 1:2, or 1:5 soil:water ratios using their corresponding uniform diluted factors was lower than the measured EC_e and this difference was greater with higher dilution and EC values. Therefore, the alternative diluted factors (y) for each soil: water ratio were obtained following the definition of diluted factor and were correlated significantly with volume ratios of added water (x): y=1.55x+0.5 for loam and y=1.21x+0.48 for silt loam soils. On the other hand, correlation analyses of the EC of soil extracts (y) to the volume ratio of added water (x) on log-log scale yielded linear models: logy = -0.805logx + logb, SD of slope=0.05, b=sample specific constant, n=24). With known saturation percentage of a sample representing a group and and the EC of diluted extract of a given soil, the EC_e could be predicted using the proposed logarithmic equation.

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THE REMINERALIZATION ASPECT OF ENAMEL ACCORDING TO CHANGE OF THE DEGREE OF SATURATION OF THE ORGANIC ACID BUFFERING SOLUTION IN pH 5.5 (pH 5.5에서 유기산 완충용액의 포화도 변화에 따른 법랑질의 재광화 양상)

  • Park, Jin-Sung;Park, Sung-Ho;Park, Jeong-Won;Lee, Chan-Young
    • Restorative Dentistry and Endodontics
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    • v.35 no.2
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    • pp.96-105
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    • 2010
  • The purpose of this study is to observe and compare the remineralization tendencies of artificial enamel caries lesion by remineralization solutions of different degree of saturations at pH 5.5, using a polarizing microscope and computer programs (Photoshop, Image pro plus, Scion Image, Excel). For this study, 48 sound permanent teeth with no signs of demineralization, cracks, or dental restorations were used. The specimens were immersed in lactic acid demineralization solution for 2 days in order to produce artificial dental caries that consist of surface and subsurface lesions. Each of 9 or 10 specimens was immersed in pH 5.5 lactic acid buffering remineralization solution of four different degrees of saturation (0.507, 0.394, 0.301, and 0.251) for 12 days. After the demineralization and remineralization, images were taken by a polarizing microscope (${\times}100$). The results were obtained by observing images of the specimens, and using computer programs, the density of caries lesions were est mated. While the group with the lowest degree of saturation (0.251) showed total remineralization feature from the surface to the subsurface of the lesion, the group with the highest degree of saturation (0.507) showed demineralization mainly on the surface of the lesion at the constant organic acid concentration 0.01 M and pH 5.5.

High Cell Density Cultivation of Pseudomonas putida BM01 Using Glucose

  • Kim, Guk Jin;In Young Lee;Dae Keon Choi;Sung Chul Yoon;Young Hoon Park
    • Journal of Microbiology and Biotechnology
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    • v.6 no.3
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    • pp.221-224
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    • 1996
  • Pseudomonas putida BM01 was grown efficiently on glucose as the sole carbon source with a supply of a nitrogen source in pH-stat mode using a low setpoint limit. A final cell concentration of 100 g/l was obtained in 30 h of fed-batch cultivation by controlling glucose concentration within the range of 5-20 g/l and maintaining dissolved oxygen tension above 10$%$ saturation using pure oxygen. This high cell density culture technique is believed highly useful for the production of poly(3-hydroxyalkanoates) by this strain.

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$CO_2$ Sensing Characteristics of PLD NASICON Thin Films (PLD법에 의해 제작된 NASICON 박막의 $CO_2$ 감지특성)

  • Min, Nam-Ki;Jin, Joon-Hyung;Lee, Sang-Yeol;Hong, Suk-In
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1657-1659
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    • 1999
  • Our $CO_2$ sensor is based on an electrochemical reaction involving NASICON, Ba-Stabilized $Na_2CO_3$, two Pt electrodes, $O_2$, and $CO_2$.. NASICON thin films were deposited by pulsed laser deposition(PLD). The sensitive electrode made of Ba-stabilized sodium carbonate was magnetron sputtered. An emf between two Pt electrodes was proportional to the logarism of the concentration of $CO_2$ in the ambient. This sensor has a sensitivity of 3.82mV/decade and does not show any saturation for $CO_2$ concentration as high as 200,000 ppm.

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