• 제목/요약/키워드: Saturated temperature

검색결과 613건 처리시간 0.028초

요소 착물형성에 의한 포화지방산 고함유 팜유 및 우지 유래 바이오디젤의 저온유동성 개선효과 연구 (Improvement of Low Temperature Property of Biodiesel from Palm Oil and Beef Tallow Via Urea Complexation)

  • 이영화;신정아;장화;이기택;김광수;장영석;박광근
    • 신재생에너지
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    • 제8권4호
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    • pp.38-43
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    • 2012
  • Biodiesel is non-petroleum based fuel produced from vegetable oils or animal fats through transesterification. The compositions of saturated and unsaturated fatty acids in the feedstocks are important factors for biodiesel quality in terms of low-temperature fluidity and oxidative stability. The goal of this study is to improve the cold flow property of biodiesel from vegetable and animal origin containing highly saturated methyl esters (approx. 50%). In this purpose poly-saturated methyl esters in palm and tallow biodiesel were removed via urea-based fractionation and then the recovered fractions (enriched unsaturated fatty acid methyl esters) were supplemented with cold flow improvers. The highest concentration of unsaturated fatty acid methyl esters (93.8%) was obtained using a urea/fatty acid ratio of 3:1 at the crystallization temperature of $0^{\circ}C$ for 17 hours in incubation, with recovery of 71% and the addition of cold flow improver (Flozol$^{(R)}$ 515, 3,000 ppm) to the enriched poly-unsaturated fatty acid methyl esters reduced the CFPP(cold filter plugging point) of palm biodiesel from $12^{\circ}C$ to $-42^{\circ}C$. In tallow biodiesel both the enrichment of unsaturated fatty acid methyl esters (93.71%) and the addition of cold flow improver (Infineum R408, 3,000ppm) reduced the CFPP from $10^{\circ}C$ to $-32^{\circ}C$.

GENERATION OF MAGNETIC FIELDS BY TEMPERATURE GRADIENTS

  • OKABE NOBUHIRO;HATTORI MAKOTO
    • 천문학회지
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    • 제37권5호
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    • pp.547-551
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    • 2004
  • We showed that magnetic fields are generated in the plasma which have the temperature inhomogeneities. The mechanism is the same as the Weibel instability because the velocity distribution functions are at non-equilibrium and anisotropic under the temperature gradients. The growth timescale is much shorter than the dynamical time of structure formation. The coherence length of magnetic fields at the saturated time is much shorter than kpc scale and then, at nonlinear phase, become longer by inverse-cascade process. We report the application of our results to clusters of galaxies, not including hydrodynamic effects.

연제품류의 열확산도 추정에 관한 연구 3. 가열매체의 열확산도에 대한 영향 (Prediction of Thermal Diffusivities of Fish Meat Paste Products 3. Influence of Heating Medium on the Thermal Diffusivities)

  • 한봉호;최수일;김종철;배태진;조현덕
    • 한국수산과학회지
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    • 제21권5호
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    • pp.277-287
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    • 1988
  • In this paper, the influence of heating medium on the thermal diffusivities of fish meat paste products was studied. Model products were heated in boiling water, saturated steam and soybean oil. The differences in temperature raise of the products were interpreted with Biot number of the products. Because of the large overall heat transfer coefficient of heating medium, the temperature raise of the products in boiling water and saturated steam was fast and the Biot number of the products could be recognized as infinite. But the temperature raise of the products in soybean oil was slow and the Biot number of the products was less than 50.

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Experimental study on the consolidation of saturated silty clay subjected to cyclic thermal loading

  • Bai, Bing;Shi, Xiaoying
    • Geomechanics and Engineering
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    • 제12권4호
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    • pp.707-721
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    • 2017
  • The objective of this paper is to experimentally study the consolidation of saturated silty clay subjected to repeated heating-cooling cycles using a modified temperature-controlled triaxial apparatus. Focus is placed on the influence of the water content, confining pressure, and magnitudes and number of thermal loading cycles. The experimental results show that the thermally induced pore pressure increases with increasing water content and magnitude of thermal loading in undrained conditions. After isothermal consolidation at an elevated temperature, the pore pressure continues to decrease and gradually falls below zero during undrained cooling, and the maximum negative pore pressure increases as the water content decreases or the magnitude of thermal loading increases. During isothermal consolidation at ambient temperature after one heating-cooling cycle, the pore pressure begins to rise due to water absorption and finally stabilizes at approximately zero. As the number of thermal loading cycles increases, the thermally induced pore pressure shows a degrading trend, which seems to be more apparent under a higher confining pressure. Overall, the specimens tested show an obvious volume reduction at the completion of a series of heating-cooling cycles, indicating a notable irreversible thermal consolidation deformation.

초음파 진동에 의한 대류 및 비등 열전달 촉진 원리에 관한 연구 (Mechanisms of Convective and Boiling Heat Transfer Enhancement via Ultrasonic Vibration)

  • 김이구;김호영;강승민;강병하;이진호
    • 대한기계학회논문집B
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    • 제27권5호
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    • pp.612-619
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    • 2003
  • This work experimentally studies the fundamental mechanisms by which the ultrasonic vibration enhances convection and pool boiling heat transfer. A thin platinum wire is used as both a heat source and a temperature sensor. A high speed video imaging system is employed to observe the behavior of cavitation and thermal bubbles. It is found that when the liquid temperature is below its boiling point, cavitation takes place due to ultrasonic vibration while cavitation disappears when the liquid reaches the boiling point. Moreover, when the gas dissolved in liquid is removed by pre-degassing, the cavitation arises only locally. Depending on the liquid temperature, heat transfer rates in convection, subcooled boiling and saturated boiling regimes are examined. In convection heat transfer regime, fully agitated cavitation is the most efficient heat transfer enhancement mechanism. Subcooled boiling is most enhanced when tile local cavitation is induced after degassing. In saturated boiling regime, acoustic pressure is shown to be a dominant heat transfer enhancement mechanism.

하천수율원이용 2단압축 열펌프시스템 냉방성능평가 (Cooling Performance Test of 2-stage Heat Pump System Using River Water as a Heat Source)

  • 김종률;이영수;장기창;라호상
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 춘계학술대회
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    • pp.2129-2134
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    • 2004
  • The present study has been conducted to develop a heat pump system using river water of temperature energy which not only belongs to unutilized energy but is a kind of good heat source due to maintain its temperature in a certain degree regardless of seasonal variation. The system did not meet the proposed performance after setup. In this paper, the system performance affected by refrigerant Oil, by pressure drop, or by other factors has been discussed. The followings were obtained : (1) Refrigerant Oil mixture rate was 2.5 in weight percentage, (2) Pressure drop through evaporator was 29.1kPa($3.1^{\circ}C$ in saturated tempearture) (3) Pressure drop from the end of evaporator to compressor inlet was 39.8kPa($4.0^{\circ}C$ in saturated tempearture). (4) The system performance can to be improved by modifying a part of pipe line to compressor, and reducing pressure drop through heat exchangers.

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Characterization of Copper Saturated-$Ge_xTe_{1-x}$ Solid Electrolyte Films Incoperated by Nitrogen for Programmable Metalization Cell Memory Device

  • Lee, Soo-Jin;Yoon, Soon-Gil;Yoon, Sung-Min;Yu, Byoung-Gon
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.174-175
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    • 2007
  • A programmable metallization cell (PMC) memory structure with copper-saturated GeTe solid electrolyte films doped by nitrogen was prepared on a TiW bottom electrode by a co-sputtering technique at room temperature. The $Ge_{45}Te_{55}$ solid electrolyte films deposited with various $N_2$/Ar flow ratios showed an increase of crystallization temperature and especially, the electrolyte films deposited at $N_2$/Ar ratios above 30% showed a crystallization temperature above $400^{\circ}C$, resulting in surviving in a back-end process in semiconductor memory devices. The device with a 200 nm thick $Cu_{1-x}(Ge_{45}Te_{55})_x$ electrolyte switches at 1 V from an "off " state resistance, $R_{off}$, close to $10^5$ to an "on" resistance state, Ron, more than 20rders of magnitude lower for this programming current.

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Enzymatic reaction model for the production of symmetrical lipid molecules using the response surface methodology

  • Hong, Joon-Sun;Shin, Jung-Ah;Lee, Ki-Teak
    • 농업과학연구
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    • 제45권2호
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    • pp.265-282
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    • 2018
  • The purpose of this research was to produce symmetric (Saturated-Unsaturated-Saturated, SUS) triacylglycerol (TAG) using palm stearin fraction oil (PSFO) and high oleic sunflower oil (HOSO) as substrates to replace cocoa butter. PSFO was blended with HOSO (1 : 2 weight ratio), and $lipozyme^{(R)}$ TLIM (20 weight % of the substrate) was added. Interesterification was carried out in a shaking water bath at $55^{\circ}C$ at 220 rpm for 6 hours. The response surface methodology (RSM) through the central composite face design was employed to observe the optimized SUS-TAG. The independent factors were the reaction temperature ($X_1$: 65, 75 and $85^{\circ}C$), reaction time ($X_2$: 1, 3 and 5 hours) and ratio of TLIM ($X_3$: 10, 15 and 20 weight %). The dependent variables were $Y_1$ = Saturated-Unsaturated-Unsaturated (SUU, area %), $Y_2=SUS$ (area %), $Y_3$ = Saturated-Saturated-Unsaturated (SSU, area %), $Y_4$ = Unsaturated-Unsaturated-Unsaturated (UUU, area %), and $Y_5=sn-2$ unsaturated fatty acid (area %). The optimal conditions from the central composite face design minimized acyl migration while maximizing the presence of unsaturated fatty acid at the sn-2 position (73.43 area %). The optimal conditions were $X_1=65^{\circ}C$, $X_2=1hour$, and $X_3=20weight%$. As a result of the response surface analysis, the lack of fits was found as $Y_1=0.622$, $Y_2=0.438$, $Y_3=0.264$, $Y_4=0.526$, and $Y_5=0.215$, and their $R^2$ were 0.897, 0.944, 0.826, 0.857, and 0.867, respectively.

서로 다른 수분율을 갖도록 염수환경에 노출된 복합재 접착체결부의 강도 (Strength of Composit Single-lap Bonded Joints with Different Saltwater Moisture Contents)

  • 양현정;정문규;권진회;최진호
    • Composites Research
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    • 제24권4호
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    • pp.48-54
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    • 2011
  • 본 연구에서는 탄소/에폭시 복합재 단일겹침 접착체결부의 염수 수분율이 체결부의 강도 및 파손모드에 미치는 영향을 연구하였다. 시편은 이차접착 방식으로 제작하였고, $71^{\circ}C$, 3.5% 염수환경에서 수분율 0, 0.2, 0.5, 1.0, 2.0%(포화상태)를 갖도록 노출시켰다. 수분율별 시편은 각 8개씩이고, 두 종류의 시험환경을 고려하여 총 80개의 시편에 대한 시험을 수행하였다. 시험결과 복합재 체결부의 강도는 수분율이 2%(포화상태)에 도달하면 감소하지만 그 이전 과도상태(약 1% 근처까지)에서는 오히려 증가하는 것으로 나타났다. 또한 수분율 1%까지는 고온 환경에서의 강도가 상온 강도보다 2~5% 가량 높게 나타났다. 그러나 수분 포화된 고온 환경 체결부의 강도는 상온 강도 대비 약 5% 가량 저하되는 것으로 나타났다.

고온에서 스피넬의 올리빈으로 역상변이 연구 (A Study of Back Transformation of Spinel to Olivine at High Temperature)

  • 김영호
    • 한국광물학회지
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    • 제18권4호통권46호
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    • pp.237-248
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    • 2005
  • [ $Mg_{2}SiO_{4}{-}$ ]스피넬에서 올리빈으로의 역상변이에 대한 고온 X-선 회절실험 결과, 진공상태에서 가열하였을 때 상변이가 일어나며, 일정한 온도에서 스피넬상으로부터 올리빈상이 시간이 경과하면서 성장하는 것으로 보아 상변이 메커니즘은 '핵생성 및 성장' 형태인 것으로 판단된다. 스피넬 상으로부터 올리빈 상으로 역상변이 할 때의 활성화 에너지를 구하기 위해 $Mg_{2}SiO_{4}{-}$스피넬 시료에 대한 상변이 실험을 진공 및 고온($1023\∼1116\;k$)에서 시행하였다. 올리빈 상에 대해 '주어진 시간에 따른 비분율법'을 이용하여 활성화 에너지 값을 결정하였다. 아브라미 방정식을 이용하여 계산한 결과, n값은 대체로 온도가 증가함에 따라 매우 넓은 영역에서 동반 상승하는데, 이러한 현상은 '핵생성 및 성장' 메커니즘이 아마도 온도에 종속적이지 않느냐 하는 것을 제시해주고 있다. 상대적으로 낮은 온도에서는 $Mg_{2}SiO_{4}{-}$스피넬은 핵이 생성된 자리가 포화된 후, 새로운 결정상이 표면에서 성장을 시작하고 시간이 지남에 따라 내부 쪽으로 옮아가는 것으로 판단된다. 그러나 고온에서, 성장은 핵이 생성된 자리가 포화되고 난 후 표면뿐만 아니라, 내부에서도 동시에 시작되는 것으로 보인다.