• Title/Summary/Keyword: Saturated temperature

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Deposition properties of $Al_{2}O_{3}$ thin films by LP-MOCVD (LP-MOCVD로 제조한 알루미나 박막의 증착 특성)

  • 김종국;박병옥;조상희
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.3
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    • pp.309-317
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    • 1996
  • Al2O3 thin films were deposited on Si-wafer (100) using organo-aluminum compounds at low pressure by chemical vapor deposition (CVD) method. The vapor of the organo-metallic precursor was carried by pure N2 gas. The deposition rate increased and then saturated as Tsub increased with increasing the AIP flow rate. The main contamination didn't found in deposited films except carbon. The H-O(H2O) IR absorption band decreased in intensity as the deposition temperature increased, and completely disappeared through annealing.

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A PROPOSED CORRELATION FOR CRITICAL FLOW RATE OF WATER FLOW

  • KIM, YEON-SIK
    • Nuclear Engineering and Technology
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    • v.47 no.1
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    • pp.135-138
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    • 2015
  • A new correlation predicting the idealized critical mass-flow rates of water for subcooled and saturated liquid water including two-phase water flow was developed for a wide range of upstream stagnation pressures (e.g., 0.5-20.0 MPa). A choking correction factor dependent on the upstream stagnation pressure and subcooled temperature was introduced into a new correlation, and its values were suggested to satisfy the idealized nozzle data within 10% error ranges. The suggested correlation will be instructive and helpful for related studies and/or engineering works.

Hydrogenation and Isomerization of Soybean Oil with Perchloratocarbonylbis-(triphenylphosphine) rhodium (Ⅰ)

  • Jeong, Hyun-Mok;Chin, Chong-Shik
    • Bulletin of the Korean Chemical Society
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    • v.5 no.5
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    • pp.199-201
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    • 1984
  • It has been found that $Rh(ClO_4)(CO)(P(C_6H_5)_3)_2$ catalyzes the hydrogenation and isomerization of soybean oil at room temperature under the atmospheric pressure of hydrogen. The hydrogenation occurs at the olefinic groups to produce saturated groups leaving the ester groups intact, and the isomerization converts $-CH = CH- CH_2-CH = CH-$ units to conjugated dienes and the dienes separated by more than two $-CH_2-$ groups. The rate of the hydrogenation is faster than that of the isomerization.

Preparation and Characteristics of Heterogeneous Cation Exchange Membrane : 2. Characteristics Change on Post-treatment (PE계 불균질 양이온 교환막의 제조와 특성 : 2. 후처리에 따른 특성 변화)

  • Yang, Hyun S.;Cho, Byoung H.;Kim, Woong K.;Lee, Chang S.
    • Applied Chemistry for Engineering
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    • v.8 no.1
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    • pp.67-75
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    • 1997
  • Heterogeneous cation exchange membrane consisting of cation exchange resin particles (diameter of less than $149{\mu}$) which are finely dispersed in a polyethylene matrix, were produced as forms of sheet. The characteristics were measured after treating hot water or saturated sodium chloride. When membranes were treated with hot water or saturated sodium chloride, cation exchange resin particles swell and expand pushing away the polyethylene matrix of membranes. The above treatment results the formation of narrow cavities between a cation exchange resin particles and polyethylene matrix, and the formation of fine micro-cracks on the polyethylene matrix. Thus, we were obtained good physical and electrochemical properties. On the treatment with hot water or saturated sodium chloride, the optimum conditions for good heterogeneous cation exchange membrane were treatment time of 30min and treatment temperature of $90^{\circ}C$.

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I2-Saturated Absorption Spectroscopy for Frequency-Stabilization of He-Ne Laser at 543 nm (543 nm 헬륨네온 레이저의 주파수 안정화를 위한 I2 포화흡수분광)

  • Kim, Kyung-Chan;Eum, Nyeon-Sik;Hong, Joo-Hyun;Seo, Ho-Sung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.3
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    • pp.859-865
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    • 2010
  • We have designed and assembled a saturated absorption-spectroscopy system of $^{127}I_2$ for the frequency stabilization of the 543 nm He-Ne laser. The frequency of a internal-mirror 543 nm He-Ne laser was swept by utilizing the temperature and PZT change of the laser cavity length. Frequency modulation was applied to the output laser mirror with a PZT modulator for the third harmonic signal. A portion of the hyperfine spectrum originated from the R(12)26-0 and R(106)28-0 transitions of the B-X system of $^{127}I_2$ was observed as the third-derivative signal using a saturated absorption spectroscopy. The signal-to-noise ratio of a typical hyperfine spectrum signal was estimated to be 30:1.

Characterization of saturation of CR-39 detector at high alpha-particle fluence

  • Ghazaly, M. El;Hassan, Nabil M.
    • Nuclear Engineering and Technology
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    • v.50 no.3
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    • pp.432-438
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    • 2018
  • The occurrence of saturation in the CR-39 detector reduces and limits its detection dynamic range; nevertheless, this range could be extended using spectroscopic techniques and by measuring the net bulk rate of the saturated CR-39 detector surface. CR-39 detectors were irradiated by 1.5 MeV high alpha-particle fluence varying from $0.06{\times}10^8$ to $7.36{\times}10^8\;alphas/cm^2$ from Am-241 source; thereafter, they were etched in a 6.25N NaOH solution at a temperature of $70^{\circ}C$ for different durations. Net bulk etch rate measurement of the 1.5 MeV alpha-irradiated CR-39 detector surface revealed that rate increases with increasing etching time and reaches its maximum value at the end of the alpha-particle range. It is also correlated with the alpha-particle fluence. The measurements of UV-Visible (UV-Vis) absorbance at 500 and 600 nm reveal that the absorbance is linearly correlated with the fluence of alpha particles at the etching times of 2 and 4 hour. For extended etching times of 6, 10, and 14.5 hour, the absorbance is saturated for fluence values of $4.05{\times}10^8$, $5.30{\times}10^8$, and $7.36{\times}10^8\;alphas/cm^2$. These new methods pave the way to extend the dynamic range of polymer-based solid state nuclear track detectors (SSNTDs) in measurement of high fluence of heavy ions as well as in radiation dosimetry.

Velocity and Temperature Profiles of Steam-Air Mixture on the Film Condensation (막응축 열전달에서 공기-수증기 혼합기체의 속도 및 온도분포)

  • 강희찬;김무환
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.10
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    • pp.2675-2685
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    • 1994
  • A study has been conducted to provide the experimental information for the velocity and temperature profiles of steam-air mixutre and to investigate their roles on the film condensation with wavy interface. Saturated gas mixture of steam-air was made to flow through the nearly horizontal$(4.1^{\circ})$ square duct of 0.1m width and 1.56m length at atmospheric pressure, and was condensated on the bottom cold plate. The air mass fraction in the gas mixture was changed from zero(W =0, pure steam) to one(W =1, pure air), and the bulk velocity was varied from 2 to 4 m/s. Water film was injected concurrently to investigate the effect of wavy interface on the condensation. The velocity and temperature profiles were measured by LDA system and thermocouples along the three parameters ; air mass fraction, mixture velocity and film flow rate. The profiles moved toward the interface with increasing steam mass fraction, mixture velocity and film flow rate. The Prandtl and Schmidt numbers were near one in the present experimental range, however there was no complete similarity between the velocity and temperature profiles of gas mixture. And the heat transfer characteristics and interfacial structure were coupled with each other.

A Numerical Study of the Performance Assessment of Coupled Thermo-Hydro-Mechanical (THM) Processes in Improved Korean Reference Disposal System (KRS+) for High-Level Radioactive Waste (수치해석을 활용한 향상된 한국형 기준 고준위방사성폐기물 처분시스템의 열-수리-역학적 복합거동 성능평가)

  • Kim, Kwang-Il;Lee, Changsoo;Kim, Jin-Seop
    • Tunnel and Underground Space
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    • v.31 no.4
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    • pp.221-242
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    • 2021
  • A numerical study of the performance assesment of coupled thermo-hydro-mechanical (THM) processes in improved Korean reference disposal system (KRS+) for high-level radioactive waste is conducted using TOUGH2-MP/FLAC3D simulator. Decay heat from high-level radioactive waste increases the temperature of the repository, and it decreases as decay heat is reduced. The maximum temperature of the repository is below a maximum temperature criterion of 100℃. Saturation of bentonite buffer adjacent to the canister is initially reduced due to pore water evaporation induced by temperature increase. Bentonite buffer is saturated 250 years after the disposal of high-level radioactive waste by inflow of groundwater from the surrounding rock mass. Initial saturation of rock mass decreases as groundwater in rock mass is moved to bentnonite buffer by suction, but rock mass is saturated after inflow of groundwater from the far-field area. Stress changes at rock mass are compared to the Mohr-Coulomb failure criterion and the spalling strength in order to investigate the potential rock failure by thermal stress and swelling pressure. Additional simulations are conducted with the reduced spacing of deposition holes. The maximum temperature of bentonite buffer exceeds 100℃ as deposition hole spacing is smaller than 5.5 m. However, temperature of about 56.1% volume of bentonite buffer is below 90℃. The methodology of numerical modeling used in this study can be applied to the performance assessment of coupled THM processes for high-level radioactive waste repositories with various input parameters and geological conditions such as site-specific stress models and geothermal gradients.

Modelling of noise-added saturated steam table using the neural networks (신경회로망을 사용한 노이즈가 첨가된 포화증기표의 모델링)

  • Lee, Tae-Hwan;Park, Jin-Hyun
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2008.05a
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    • pp.205-208
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    • 2008
  • In numerical analysis numerical values of thermodynamic properties such as temperature, pressure, specific volume, enthalpy and entropy are required. But most of the thermodynamic properties of the steam table are determined by experiment. Therefore they are supposed to have measurement errors. In order to make noised thermodynamic properties corresponding to errors, random numbers are generated, adjusted to appropriate magnitudes and added to original thermodynamic properties. the neural networks and quadratic spline interpolation method are introduced for function approximation of these modified thermodynamic properties in the saturated water based on pressure. It was proved that the neural networks give smaller percentage error compared with quadratic spline interpolation. From this fact it was confirmed that the neural networks trace the original values of thermodynamic properties better than the quadratic interpolation method.

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