• Title/Summary/Keyword: Salts

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Evaluation of the Chemical Compositions of Solar Salts Produced in Korea (국내 시판 천일염의 성분 조사)

  • Seo, Ji-Hyun;Kim, Hyun-Jeong;Lee, Sam-Pin
    • Food Science and Preservation
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    • v.19 no.4
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    • pp.554-559
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    • 2012
  • To evaluate the effect of aging on solar salts produced in Korea, the chemical compositions of the solar salts, including their heavy metal contents, were analyzed after they were aged for one-year (OA) and for three years (TA). The average contents of the components were: sodium chloride; 81.4% (OA) and 90.9% (TA), chloride; 57.7% (OA) and 65.0% (TA), moisture content; 4.7% (TA) and 12.0% (OA), insoluble solids; 0.03% (OA) and 0.04% (TA), and $SO_4$ ions; and 0.57% (TA) and 0.85% (OA). No significant difference was found, however, in the heavy metal contents. Heavy metals such as As, Pb, and Hg were detected with values far below the maximum permissible limit, and Cd was not detected in the salts. The TA solar salts showed higher values of sodium chloride, chloride, and insoluble solids than the OA solar salts, but the TA solar salts had lower moisture and $SO_4$ values. These results clearly indicate that the levels of heavy metals in the OA and TA solar salts that are produced in Korea are safe.

Flame Retardancy of Veneers Treated by Ammonium Salts (암모늄염으로 처리한 베니어의 난연성)

  • Chung, Yeong-Jin
    • Applied Chemistry for Engineering
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    • v.18 no.3
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    • pp.251-254
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    • 2007
  • Veneer plate was painted by the treatment with ammonium salts such as ammonium chloride (AMCR), ammonium sulfate (AMSF), monoammonium phosphate (MAPP), and diammonium phosphate (DAPP) at room temperature. The flame retardancy of painted veneer plate was investigated. The painted veneer plate shows an increased $CO/CO_2$ over virgin veneer and it was supposed to affect the toxicity to different extents. But when the ammonium salts were used as the retardant for veneer, the flame retardancy was improved due to the painted ammonium salts in the veneers. Also, the veneer plates with ammonium sulfate and ammonium chloride showed both the lower total smoke release (TSR) and lower total smoke production (TSP) than that of virgin veneer.

Principles of Physiology of Lipid Digestion

  • Bauer, E.;Jakob, S.;Mosenthin, R.
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.2
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    • pp.282-295
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    • 2005
  • The processing of dietary lipids can be distinguished in several sequential steps, including their emulsification, hydrolysis and micellization, before they are absorbed by the enterocytes. Emulsification of lipids starts in the stomach and is mediated by physical forces and favoured by the partial lipolysis of the dietary lipids due to the activity of gastric lipase. The process of lipid digestion continues in the duodenum where pancreatic triacylglycerol lipase (PTL) releases 50 to 70% of dietary fatty acids. Bile salts at low concentrations stimulate PTL activity, but higher concentrations inhibit PTL activity. Pancreatic triacylglycerol lipase activity is regulated by colipase, that interacts with bile salts and PTL and can release bile salt mediated PTL inhibition. Without colipase, PTL is unable to hydrolyse fatty acids from dietary triacylglycerols, resulting in fat malabsorption with severe consequences on bioavailability of dietary lipids and fat-soluble vitamins. Furthermore, carboxyl ester lipase, a pancreatic enzyme that is bile salt-stimulated and displays wide substrate reactivities, is involved in lipid digestion. The products of lipolysis are removed from the water-oil interface by incorporation into mixed micelles that are formed spontaneously by the interaction of bile salts. Monoacylglycerols and phospholipids enhance the ability of bile salts to form mixed micelles. Formation of mixed micelles is necessary to move the non-polar lipids across the unstirred water layer adjacent to the mucosal cells, thereby facilitating absorption.

Thermally Induced Cationic Polymerization of Glycidyl Phenyl Ether Using Novel Xanthenyl Phosphonium Salts

  • Gupta, Mukesh Kumar;Singh, Raj Pal
    • Macromolecular Research
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    • v.17 no.4
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    • pp.221-226
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    • 2009
  • The present study firstly describes the synthesis of novel, thermo-latent initiators based on xanthenyl phosphonium salts with different counter anions and phosphine moieties and secondly examines their efficiency in the bulk polymerization of glycidyl phenyl ether(GPE). The polymerization was performed with phosphonium salt initiators($I_{SbF6}$, $I_{PF6}$, $I_{AsF6}$ and $I_{BF4}$) at ambient temperature to $200^{\circ}C$ for 1 h. The order of initiator activity was $I_{SbF6}>I_{PF6}>I_{AsF6}>I_{BF4}$. To examine the effect of the phosphine moiety on the initiator activity, polymerization was carried out with $I_{SbF6}(Ph_{3}P)$ and $II_{SbF6}(Bu_{3}P)$ at ambient temperature to $170^{\circ}C$ for 1 h. The order of reactivity was $I_{SbF6}>II_{SbF6}$. In general, the conversion percentage increased with increasing polymerization temperature. The thermal stability of these salts was measured by thermo gravimetric analysis(TGA). The solubility of phosphonium salts in various organic solvents and epoxy monomers was also investigated.

Quality of Yukwa base and Popped rice for Salyeotgangjung popped with salt (소금으로 팽화시킨 유과바탕 및 쌀엿강정용 팽화쌀의 품질)

  • 임경려;강순아;이경희
    • Korean journal of food and cookery science
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    • v.19 no.6
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    • pp.729-736
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    • 2003
  • This study was performed to improve the quality and extend the shelf life of Yukwa and Salyeotgangjung, traditional Korean cookies, by using fine hot salt instead of oil as the popping medium. Yukwa and Salyeotgangjung were popped with fine salt, and the size, sensory evaluation, color values and textural properties were then compared with those popped in oil. The results showed that the Yukwa base with salt was popped the most at 140C and the rice was popped at 240C. The Yukwa base in salts was smaller in size and larger in density than in oil but the popped rice in salts had a similar size and a smaller density than that popped in oil. In the sensory test, the Yukwa base and popped rice expanded in the salts were preferred to those popped in oil but there was little difference in only popped rice. In terms of color, there was a difference between those popped in salt and in oil. In terms of texture, only popped rice expanded in the salts was harder than in oil, and the Yukwa popped in oil was more cohesive than in the salts. In brittleness, there were no differences between in salt and in oil.

Effects of Salts on the Conformation and Catalytic Properties of D-Amino Acid Aminotransferase

  • Ro, Hyeon-Su
    • BMB Reports
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    • v.35 no.3
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    • pp.306-312
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    • 2002
  • The effects of salts on the biochemical properties of D-amino acid aminotransferase from Bacillus sp. YM-1 have been studied to elucidate both the inhibitory effects of salts on the activity and the protective effects of salts on the substrate-induced inactivation. The results from UV-visible spectroscopy studies on the reaction of the enzyme with D-serine revealed that salt significantly reduced the rate of the formation of the quinonoid intermediate and its accumulation. The kinetic and spectroscopy studies of the reaction with $\alpha$-[$^2H$]-DL-serine in different concentrations of NaCl provided evidence that the rate-limiting step was changed from the deprotonation of the external aldimine to another step(s), presumably to the hydrolysis of the ketimine. Gel filtration chromatography data in the presence of NaCl showed that the enzyme volume was reduced sharply with the increasing NaCl concentration, up to 100 mM. An additional increase of the NaCl concentration did not affect the elution volume, which suggests that the enzyme has a limited number of salt-binding groups. These results provide detailed mechanistic evidence for the way salts inhibit the catalytic activity of D-amino acid aminotransferase.

Alkaline Hydrolysis of Polyester/Acetate Union Fabric (폴리에스테르/아세테이트 혼용직물의 알칼리 가수분해)

  • Ju, Young Min;Kim, Myung Kyoon;Ahn, Kyoung Ryoul;Lee, Jeong Min
    • Textile Coloration and Finishing
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    • v.8 no.4
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    • pp.42-51
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    • 1996
  • Alkaline hydrolysis to improve the hand of PET/acetate union fabric was studied in relation to skin saponification and retarding effect of salts on the alkaline hydrolysis of cellulose acetate fiber, accelerating effect of salts on the alkaline hydrolysis of PET fiber, and changes of total hand value(T.H.V) of PET/acetate union fabric treated with alkali/salt solution. It was found that the rate of saponification of acetate was delayed by the addition of salts such as LiCl, NaCl and CH$_{3}$COONa into NaOH solution below 10 minutes. The rate of shrinkage of acetate fabric treated with 5g/l NaOH solution at 9$0^{\circ}C$ and 60 minutes showed 20 % but it was decreased 8% by. the addition of 120g/l Concentration of inorganic salts. We could know that the rate of alkaline hydrolysis of filament yarn treated with alkali solution at 9$0^{\circ}C$ and 60 minutes was delayed about 3 % using 2,000T/M of hard twist yarn, especially acetate filament treated with alkali solution at 9$0^{\circ}C$ and 10 minutes was delayed about 10%. T.H.V. of PET/acetate union fabric was increased from 2.77 to 3.04~3.18 by the addition of salts into alkali solution.

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Proteomic Analysis of Proteins of Weissella confusa 31 Affected by Bile Salts

  • Lee, Kang Wook;Lee, Seung-Gyu;Han, Nam Soo;Kim, Jeong-Hwan
    • Journal of Microbiology and Biotechnology
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    • v.22 no.10
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    • pp.1432-1440
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    • 2012
  • Weissella confusa 31, an isolate from human feces, possesses desirable properties as a probiotic strain, including bile salt resistance. W. confusa 31 is not inhibited by bile salts up to 0.3% concentration. Proteins affected by bile salts (0.05%) were examined by 2-D gel electrophoresis. Our proteomic analyses revealed that the intensities of 29 spots were changed, where 17 increased (including 2 spots observed only under the bile salts stress conditions) and 12 decreased. Proteins were identified by MALDI-TOF mass spectrometry. Proteins increased in the band intensities included adenylate kinase (12.75-fold increase), Clp-like ATP-dependent protease (11.91-fold), 6-phosphogluconate dehydrogenase (10.35-fold), and HSP 70 (5.07-fold). Some of the increased or decreased proteins are also known to be involved in other types of stress responses.

Determination of Chemical Compositions and Oxidation States for Corrosion Products in LiCl Molten Salts

  • Park, Yong-Joon;Pyo, Hyung-Ryul;Kim, Do-Yang;Jee, Kwang-Yong;Kim, Won-Ho
    • Nuclear Engineering and Technology
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    • v.32 no.5
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    • pp.514-520
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    • 2000
  • The mechanism of corrosion behavior has to be understood clearly to select an optimum material for handling molten salts to be used in the oxide reduction process of PWR spent fuel. In this study, the oxidation states of corrosion products on the surface of Inconel 600 and 800H as well as their chemical compositions and structural informations were determined by using XPS, ICP-AES, AAS, EPMA and XRD after the corrosion experiment with lithium molten salts at 75$0^{\circ}C$ for 25 hours. Nickel and oxygen were detected from the corrosion products on the surface of Inconel plates and chromium was found to be dissolved out into lithium molten salts leaving cracks on the surface. The corrosion products were identified as metal oxides such as Fe$_2$O$_3$, Cr$_2$O$_3$, NiO, NiFe$_2$O$_4$and MnO by using XPS and XRD.

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Enhance degradation of insecticide chlorpyrifos by iron salts and potassium persulfate during zerovalent iron treatment in aqueous solution

  • Rahman, M. Mokhlesur;Hwang, Jung-In;Kwak, Se-Yeon;Kim, Jang-Eok
    • Journal of Applied Biological Chemistry
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    • v.61 no.4
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    • pp.383-389
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    • 2018
  • Degradation of the insecticide O,O-diethyl O-3,5,6-trichloro-2-pyridyl phosphorothioate (chlorpyrifos) in aqueous solution was investigated using iron salts and potassium persulfate during ZVI treatment through a series of batch experiments. The degradation rate of chlorpyrifos increased with increases in the concentrations of iron salts and potassium persulfate in the aqueous system. Ferric chloride was found to be the most effective iron salt for the ZVI-mediated degradation of chlorpyrifos in aqueous solution. Further, the iron salts tested could be arranged in the following order in terms of their effectiveness: $FeCl_3$> $Fe_2(SO_4)_3$> $Fe(NO_3)_3$. The persulfate-ZVI system could significantly degrade chlorpyrifos present in the aqueous medium. This revealed that chlorpyrifos degradation by treatment with $Fe^0$ was promoted on adding ferric chloride and potassium persulfate. The kinetics of the degradation of chlorpyrifos by persulfate-amended $Fe^0$ was higher than that for iron-salt-amended $Fe^0$. This suggests that using a sequential $Fe^0$ reduction-ferric chloride or $Fe^0$ reduction-persulfate process may be an effective strategy to enhance the removal of chlorpyrifos in contaminated water.